Allylmagnesium chloride solution 烯丙基氯化镁

CAS 2622-05-1 MFCD00000473

化学结构图

2622-05-1
SMILES: C=CC[Mg]Cl

化学属性

Mol. FormulaC3H5ClMg
Flash Point-17 ºC
Melting Point-21°C
Boiling Point66°C
Solubility剧烈反应
TSCAYes
Density1.01
Mol. Weight100.83
pH-:A
Danger-Level-
Redox-

别名和识别编码

Chemical NameAllylmagnesium chloride solution
CAS Number2622-05-1
EC Number250-023-7
Beilstein Registry Number3587316
MDL NumberMFCD00000473
PubChem Substance ID75804
Synonym chloro-2-propenyl-magnesiu Allylchloromagnesium Allylmagnesium chloride, 1.7M solution in THF 烯丙基氯化镁 溶液 ALLYLMAGNESIUM CHLORIDE Allylmagnesium Chloride 1.5 M in Tetrahydrofuran 氯丙烯镁 烯丙基氯化镁(订作2周) 烯丙基氯化镁 Chloroallylmagnesium Allylmagnesium chloride solution Allylmagnesium chloride1.7M solution in THFAcroSeal§3 丙烯基氯化镁 Magnesium, chloro-2-propenyl- 氯丙烯镁; 丙烯基氯化镁 ALLYLMAGNESIUM CHLORIDE, 2.0M SOLUTION I N TETRAHYDROFURAN 2-Propenylmagnesium chloride ALLYLMAGNESIUM CHLORIDE, 2.0M SOLUTION I Allylmagnesium Chloride (10% in Tetrahydrofuran, ca. 1mol/L) Allylmagnesiumchlorid ALLYLMAGNESIUM CHLORIDE SOLUTION, ~2.0 M IN THF 烯丙基氯化镁(10%的四氢呋喃溶液,约1MOL/L) solutionpurum,2mintetrahydrofuran Allylmagnesium Chloride 1.0 M In Tetrahydrofuran
Reaxys-RN3693919
Chemical Name Translation烯丙基氯化镁
InChIKeyPLYLAFITHJUEGX-UHFFFAOYSA-M
LabNetwork Molecule IDLN01314288
InChIInChI=1S/C3H5.ClH.Mg/c1-3-2;;/h3H,1-2H2;1H;/q-1;;+2/p-1
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分类

  • {SNA} Alkyl, Chemical Synthesis, Grignard Reagents, Organometallic Reagents

产品应用

  • Grignard 试剂

相关文献及参考

  • Beilstein:4(3)1995

安全信息

Signal word Danger
GHS Symbol
WGK Germany1
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S6 Keep under ... (inert gas to be specified by the manufacturer) 将该物质保存在生产厂家指定的惰性气体中；
  • S7/8 Keep container tightly closed and dry 保存在严格密闭容器中，保持干燥；
Risk Statements
  • R11 Highly flammable 非常易燃
  • R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应，释放出高度可燃气体
  • R34 Causes burns 会导致灼伤
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P222 Do not allow contact with air. 不要与空气接触。
  • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能，因为会剧烈反应可能产生闪火。
  • P231+P232
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P305+P351+P338
  • P305+P351+P338+P310
  • P370+P378
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P422 Store contents under… 存储目录在…之下。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体，可自燃。
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
  • H351 Suspected of causing cancer 怀疑致癌
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 4.3 F,C
UN Number 3399
Packing GroupI
Storage condition water-free area Air & Moisture Sensitive
Hazard Class4.3/3
Restrict 危险品

其他信息

  • EPA化学物质信息:Magnesium, chloro-2-propenyl-(2622-05-1)
  • 和水剧烈反应。
  • HazardClass:4.2
  • MOL 文件:2622-05-1.mol
  • F:1-3-10
  • 氯丙烯镁价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 XW26220511 烯丙基氯化镁 100ml 298元 2011/08/23 XW26220512 烯丙基氯化镁 500ml 698元 2011/04/16 A1554 烯丙基氯化镁(约9%的四氢呋喃溶液，约0.8mol/L) Allylmagnesium Chloride (ca. 9% in Tetrahydrofuran, ca. 0.8mol/L) 100G 691元
  • PackingGroup:I

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  4. Alkyl - Grignard Reagents
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  4. Alkyl - Grignard Reagents
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Grignard Reagents & Alkyl Metals
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metal Compounds 金属化合物
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  4. Alkenyl
  1. Functional Group 官能团索引
  2. organomagnesium compound

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