4-Bromo-1,2-(methylenedioxy)benzene 4-溴-1,2-亚甲二氧基苯

CAS 2635-13-4 MFCD00005821

化学结构图

2635-13-4
SMILES: Brc1ccc2c(c1)OCO2

化学属性

Mol. FormulaC7H5BrO2
Mol. Weight201.02
Refractive index1.5820 to 1.5850
Boiling Point268.6°C at 760 mmHg
Density1.669
Flash Point113°C
TSCANo
Stability对光线敏感
Melting PointN/A

别名和识别编码

Chemical Name4-Bromo-1,2-(methylenedioxy)benzene, 97%
Synonym 5-Bromo-1,3-benzodioxole {LY} 5-Bromo-1,3-benzodioxole {} {LY} 5-Bromo-1,3-benzodioxole {} {} {LY} 5-Bromo-1,3-benzodioxole {} {} {} {LY} 5-Bromo-1,3-benzodioxole {} {} {} {} {LY} 5-Bromo-1,3-benzodioxole {} {} {} {} {} {LY} 5-Bromo-1,3-benzodioxole {} {} {} {} {} {} {LY} 5-Bromo-1,3-benzodioxole {} {} {} {} {} {} {} {LY} 5-Bromo-1,3-benzodioxole {} {} {} {} {} {} {} {} {LY} 5-Bromo-1,3-benzodioxole {} {} {} {} {} {} {} {} {} {LY} 5-Bromo-1,3-benzodioxole {} {} {} {} {} {} {} {} {} {} {LY} 5-Bromo-1,3-benzodioxole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Bromo-1,3-benzodioxole {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Bromo-1,3-benzodioxole {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Bromo-1,3-benzodioxole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Bromo-1,3-benzodioxole {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 5-Bromo-1,3-ben
CAS Number2635-13-4
PubChem Substance ID75831
EC Number220-123-5
Beilstein Registry Number127407
MDL NumberMFCD00005821
Reaxys-RN127407
Chemical Name Translation4-溴-1,2-亚甲二氧基苯
InChIKeyFBOYMIDCHINJKC-UHFFFAOYSA-N
LabNetwork Molecule IDLN00219922
InChIInChI=1S/C7H5BrO2/c8-5-1-2-6-7(3-5)10-4-9-6/h1-3H,4H2
Canonical SMILESBrC1=CC=C(OCO2)C2=C1
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Protected Alcohols/Phenols
  • Building Blocks, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Protected Alcohols/Phenols

相关文献及参考

  • Beilstein: 19,V,1,435
  • Lithiation can be effected at the 3-position using LDA or LTMP at 78oC: J. Org. Chem., 64, 8004 (1999).

安全信息

GHS Symbol
WGK Germany3
Hazard Codes Xi
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C {LY} 2-8°C Store at room temperature {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°

其他信息

  • MOL 文件:2635-13-4.mol
  • Sigma Aldrich:2635-13-4(sigmaaldrich)
  • Acros Organics:1,2-亚甲基二氧基-4-溴苯 4-Bromo-1,2-(methylenedioxy)benzene, 97%(2635-13-4)
  • 4-溴-1,2-亚甲二氧基苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B1230 4-溴-1,2-亚甲基二氧基苯 4-Bromo-1,2-methylenedioxybenzene 25G 1040元 2010/06/21 307680250 4-溴-1,2-亚甲二氧基苯 4-Bromo-1,2-(methylenedioxy)benzene 97% 25 GR 1107元 2010/06/21 307681000 4-溴-1,2-亚甲二氧基苯 4-Bromo-1,2-(methylenedioxy)benzene 97% 100 GR 3134元
  • 下游产品:3，4-亚甲基苯硼酸
  • MSDS 信息:4-Bromo-1,2-(methylenedioxy)benzene(2635-13-4).msds
  • Hazard Note:Irritant
  • 图谱信息:4-溴-1,2-亚甲二氧基苯(2635-13-4)质谱(MS) 4-溴-1,2-亚甲二氧基苯(2635-13-4)红外图谱(IR1) 4-溴-1,2-亚甲二氧基苯(2635-13-4)核磁图( 1 HNMR) 4-溴-1,2-亚甲二氧基苯(2635-13-4)Raman光谱 4-溴-1,2-亚甲二氧基苯(2635-13-4)核磁图( 13 CNMR)
  • Alfa Aesar:4-溴-1,2-亚甲基二氧苯,98% 4-Bromo-1,2-(methylenedioxy)benzene, 98%(2635-13-4)
  • TCI Shanghai:4-溴-1,2-亚甲基二氧基苯 4-Bromo-1,2-methylenedioxybenzene,>;98.0%(GC)(2635-13-4)
  • 用途一:用作日用化学品中间体

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Arenes 芳烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Protected Alcohols/Phenols - Oxygen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Polyols

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