Hydrazine hydrochloride 盐酸肼

CAS 2644-70-4 MFCD00044368

化学结构图

2644-70-4
SMILES: Cl.NN

化学属性

Mol. FormulaClH5N2
Mol. Weight68.51
Melting Point89°C
Density1.422
Solubility370 G/L (20 ºC)
Boiling Point240 °C at 760 mmHg
Stability对湿度和空气敏感

别名和识别编码

Chemical NameHydrazine Hydrochloride
MDL NumberMFCD00044368
PubChem Substance ID115031
CAS Number2644-70-4
EC Number220-154-4
Reaxys-RN15709173
Synonym Hydrazine monohydrochloride {LY} Hydrazine monohydrochloride {} {LY} Hydrazine monohydrochloride {} {} {LY} Hydrazine monohydrochloride {} {} {} {LY} Hydrazine monohydrochloride {} {} {} {} {LY} Hydrazine monohydrochloride {} {} {} {} {} {LY} Hydrazine monohydrochloride {} {} {} {} {} {} {LY} Hydrazine monohydrochloride {} {} {} {} {} {} {} {LY} Hydrazine monohydrochloride {} {} {} {} {} {} {} {} {LY} Hydrazine monohydrochloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Hydrazine monohydrochloride {} {} {} {} {} {} {} {} {} {} {LY} Hydrazine monohydrochloride {} {} {} {} {} {} {} {} {} {} {} {LY} Hydrazine monohydrochloride {} {} {} {} {} {} {} {} {} {} {} {} {LY} Hydrazine monohydrochloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Hydrazine monohydrochloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Hydrazine monohydrochloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Hydrazine monohydroch
Beilstein Registry Number15709173
Chemical Name Translation盐酸肼
InChIKeyLIAWOTKNAVAKCX-UHFFFAOYSA-N
Wiswesser Line NotationZZ &GH
LabNetwork Molecule IDLN00002505
InChIInChI=1S/ClH.H4N2/c;1-2/h1H;1-2H2
Canonical SMILESNN.[H]Cl
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分类

  • Building Blocks, Chemical Synthesis, Hydrazines, Nitrogen Compounds, Organic Building Blocks
  • {uni_hamburg} no charge; 2fragments; ionic
  • {SA} Building Blocks, Chemical Synthesis, Hydrazines, Nitrogen Compounds, Organic Building Blocks
  • {SNA} Building Blocks, Chemical Synthesis, Hydrazines, Nitrogen Compounds, Organic Building Blocks

产品应用

  • Has been used as catalyst in the synthesis of titanium oxide polymers

相关文献及参考

  • Aldrich MSDS 1 , 1046:A / Corp MSDS 1 (1), 1890:A / RegBook 1 (3), 3201:G / Sax 6 , 1541 / Structure Index 1 , 509:D:3
  • Short: III/20a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cl Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20a Year: 1988 Keyword: NQR ISBN: 3-540-18161-X ISBN: 978-3-540-18161-3 Internet Resource: DOI:10.1007/b31153 RefComment: IX,677 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
  • Short: III/31a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cu Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/31a Year: 1993 Keyword: NQR ISBN: 3-540-55146-8 ISBN: 978-3-540-55146-1 Internet Resource: DOI:10.1007/b43999 RefComment: VIII, 437 pages. Hardcover Abstract: Volume III/31 continues the compilation of nuclear quadrupole resonance spectroscopy data of solid substances which started in with volume III/20 in 1987 covering the literature from the beginning of nuclear quadrupole resonance spectroscopy in 1951 to 1982 and containing the data for 8000 substances in the solid state, distributed among three subvolumes III/20 a, b, and c. Volume III/31 covers the literature published in the period from the end of 1982 through the end of 1989. Included are the data for substances studied for the first time, as well as data for substances already present in the previous volume III/20 if the data published there could be comp

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P203
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P310
  • P301+P316
  • P301+P330+P331
  • P301+P330+P331+P310
  • P302+P350
  • P302+P352
  • P302+P361+P354
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P310
  • P305+P354+P338
  • P308+P313
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P316
  • P318
  • P320 Specific treatment is urgent (see … on this label). 紧急具体治疗（见本标签上的）。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P333+P313
  • P333+P317
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P361+P364
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H301 Toxic if swallowed 吞食有毒
  • H310 Fatal in contact with skin 皮肤接触致命
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H330 Fatal if inhaled 吸入致命
  • H331 Toxic if inhaled 吸入中毒
  • H341 Suspected of causing genetic defects 怀疑导致遗传性缺陷
  • H350 May cause cancer 可能致癌
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Hazard Codes 8 T,N
RTECSMV4625000
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Signal word Danger
UN Number 2923 UN 2923 8/PG 2
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Risk Statements
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R45 May cause cancer 可能致癌
  • R50/53
Packing GroupII
Hazard Class6.1/8
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 118 mg/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
REFERENCE :
   AMIHAB AMA Archives of Industrial Health.  (Chicago, IL)  V.11-21, 1955-60.
   For publisher information, see AEHLAU.  Volume(issue)/page/year: 13,34,1956

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 126 mg/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
REFERENCE :
   AMIHAB AMA Archives of Industrial Health.  (Chicago, IL)  V.11-21, 1955-60.
   For publisher information, see AEHLAU.  Volume(issue)/page/year: 13,34,1956

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 133 mg/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
REFERENCE :
   AMIHAB AMA Archives of Industrial Health.  (Chicago, IL)  V.11-21, 1955-60.
   For publisher information, see AEHLAU.  Volume(issue)/page/year: 13,34,1956

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 122 mg/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
REFERENCE :
   AMIHAB AMA Archives of Industrial Health.  (Chicago, IL)  V.11-21, 1955-60.
   For publisher information, see AEHLAU.  Volume(issue)/page/year: 13,34,1956

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Mammal - dog
DOSE/DURATION           : 53 mg/kg
TOXIC EFFECTS :
   Behavioral - convu

TYPE OF TEST            : Micronucleus test
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 200 mg/kg/96H (Intermittent)
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 389,3,1997

TYPE OF TEST            : Specific locus test
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 80 mg/kg
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 191,111,1987

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 500 umol/L
REFERENCE :
   HUGEDQ Human Genetics.  (Springer-Verlag New York, Inc., Service Center, 44
   Hartz Way, Secaucus, NJ 07094)  V.31-    1976-  Volume(issue)/page/year:
   54,155,1980

其他信息

  • MSDS 信息:Hydrazine monohydrochloride(2644-70-4).msds
  • TCI Shanghai:肼单盐酸盐 Hydrazine Monohydrochloride,>;98.0%(T)(2644-70-4)
  • Acros Organics:肼单盐酸盐 Hydrazine monohydrochloride, 98+%(2644-70-4)
  • 用途一:用作还原剂，也用于有机合成
  • 下游产品:哒螨灵 --> 1-苯基-3-三氟甲基-1H-吡唑-4-腈 --> 1-苯基-3-三氟甲基-1H-吡唑-4-酰胺 --> 1-苯基-3-三氟甲基-1H-吡唑-4-醛 --> (1-苯基-3-三氟甲基-1H-吡唑-4-基)甲胺 --> (1-苯基-3-三氟甲基-1H-吡唑-4-基)甲醇 --> 1-苯基-3-三氟甲基-1H-吡唑-4-胺 --> 1-苯基-3-三氟甲基-1H-吡唑-4-羧酸乙酯 --> 1-苯基-3-三氟甲基-1H-吡唑-4-羧酸 --> 1-苯基-3-三氟甲基-1H-吡唑-5-羧酸 --> 1-苯基-3-三氟甲基-4-溴-1H-吡唑 --> 2-(4-溴苯基)-5-(1-萘基)-1,3,4-恶二唑 --> 1-苯基-3-三氟甲基吡唑 --> 2-(4'-叔丁苯基)-5-(4'-联苯基)-1,3,4-恶二唑 --> 卡铂 --> 2,5-二苯基-1,3,4-恶二唑 --> 2,5-二萘基-1,3,4-恶二唑 --> 2,5-双(3-甲氧基苯基)-1,3,4-二唑 --> 4-苄氨基-7-硝基苯并-2-氧杂-1,3-二唑 --> 2-萘肼 --> 对叔丁基苯甲酰肼 --> 3-甲基吡唑-5-甲酸乙酯 --> 3-(三氟甲基)吡唑
  • 图谱信息:盐酸肼(2644-70-4)红外图谱(IR1) 盐酸肼(2644-70-4)红外图谱(IR2)
  • Hydrazine monohydrochloride has been used as catalyst in the synthesis of titanium oxide polymers via catalytic sol-gel process and in preparation of ethyl 3-ethoxy-1H-pyrazole-4-carboxylate
  • 盐酸肼价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 H0174 肼单盐酸盐 Hydrazine Monohydrochloride 25G 347元 2014/06/02 H0174 肼单盐酸盐 Hydrazine Monohydrochloride 500G 874元 2010/06/21 201992500 盐酸肼 Hydrazine monohydrochloride 98+% 250 GR 725元
  • MOL 文件:2644-70-4.mol
  • Sigma Aldrich:2644-70-4(sigmaaldrich)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Reduction - Synthetic Reagents
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Hydrazines - Nitrogen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Hydrazines - Nitrogen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Guanidines

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