Methoxycarbonylsulfenyl Chloride 甲氧羰基磺酰氯

CAS 26555-40-8 MFCD00013648

化学结构图

26555-40-8
SMILES: COC(=O)SCl

化学属性

Mol. FormulaC2H3ClO2S
Mol. Weight126.55
Refractive index1.4770 to 1.4880
Boiling Point69°C/75mmHg(lit.)
Density1.399 g/mL at 25 °C(lit.)
Flash Point54°C(lit.)
TSCANo

别名和识别编码

Chemical NameMethoxycarbonylsulfenyl Chloride
Synonym Methoxycarbonyl-sulfensäurechlorid thiocarbonic acid, anhydrosulfide with methyl thiohypochlorite 甲氧基羰基磺酰氯 Carbonothioic acid anhydrosulfide with thiohypochlorus acid, O-methyl ester Carbonothioic acid, anhydrosulfide with thiohypochlorous acid, methyl ester (methoxycarbonyl)sulfenyl chloride S-氯 O-硫代碳酸甲酯 Methoxycarbonylsulfenyl chloride Methoxycarbonyl-sulfenylchlorid Methoxycarbonylsulphenyl chloride thiocarbonic acid, anhydrosulphide with methyl thiohypochlorite Thiohypochlorous acid anhydrosulfide with O-methyl thiocarbonate
CAS Number26555-40-8
PubChem Substance ID87572957
EC Number247-801-3
Beilstein Registry Number1849908
MDL NumberMFCD00013648
Reaxys-RN1849908
Chemical Name Translation甲氧羰基磺酰氯
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分类

  • {SA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfenyl Halides, Sulfur Compounds

相关文献及参考

  • Beil. 3 ,IV,279
  • FT-IR 2 (1), 977:D / FT-NMR 1 (1), 931:A / RegBook 1 (1), 695:K / Structure Index 1 , 105:B:7
  • Short: II/2 Title: Magnetic Properties of Coordination and Organometallic Transition Metal Compounds Author: König, E. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/2 Year: 1966 ISBN: 3-540-03593-1 ISBN: 978-3-540-03593-0 Internet Resource: DOI:10.1007/b19948 RefComment: 170 figs., XII, 578 pages. Hardcover Abstract: The data compiled refer to susceptibility measurements (susceptibility, Curie-constants, magnetic moments, transition temperatures) and ESR-measurements (g-factors and other parameters of the applied spin Hamiltonian). In volume II/2 the literature from 1899 up to 1964 has been considered. Volume II/8 supplements volume II/2, taking into account the data on magnetic susceptibilities and ESR parameters published in the p eriod 1964 to 1968. The following subvolumes II/10,II/11, II/12 supplement data up to 1974.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
  • Reacts with arenes under Friedel-Crafts conditions to give S-aryl thiocarbonates, thus providing a method for the introduction of the thiol group into an aromatic ring: Z. Chem., 17, 411 (1977).
  • Reagent for the preparation of unsymmetrical disulfides, by successive reaction with different thiols: Helv. Chim. Acta, 56, 1370 (1973):
  • Reaction of the same intermediate with KO-t-Bu provides a route to trisulfides. Cyclic trisulfides can also be prepared: J. Org. Chem., 44, 4144 (1979).

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H226 Flammable liquid and vapour 易燃液体和蒸气
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes C
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P370+P378
  • P304+P340
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P304+P340+P310
  • P403+P235
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P301+P330+P331
  • P241+P242+P243
  • P305+P351+P338
  • P303+P361+P353+P310+P363
Signal word Danger
UN Number 2920 UN2920
Risk Statements
  • R10 Flammable 易燃
  • R34 Causes burns 会导致灼伤
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Storage condition Moisture Sensitive
Packing GroupII
Hazard Class8/3

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Protection and Derivatization - Synthetic Reagents
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfonyl Halides - Sulfur Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfenyl Halides - Sulfur Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfenyl Halides - Sulfur Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Others
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfur Compounds for Organic Synthesis 有机合成硫化物
  1. Functional Group 官能团索引
  2. thiocarbonic acid derivative
  1. Functional Group 官能团索引
  2. thiocarbonic acid monoester

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