Allyldiphenylphosphine 烯丙基二苯基膦

CAS 2741-38-0 MFCD00014954

化学结构图

2741-38-0
SMILES: C=CCP(c1ccccc1)c1ccccc1

化学属性

Mol. FormulaC15H15P
Mol. Weight226.26
Density1.049 g/mL at 25 °C(lit.)
Boiling Point340.6 °C at 760 mmHg
Refractive indexn20/D 1.619(lit.)
Flash Point>110°(230°F)
TSCANo
Stability对空气敏感

别名和识别编码

Chemical NameAllyldiphenylphosphine
MDL NumberMFCD00014954
CAS Number2741-38-0
Synonym Allyldiphenylphosphine {LY} Allyldiphenylphosphine {} {LY} Allyldiphenylphosphine {} {} {LY} Allyldiphenylphosphine {} {} {} {LY} Allyldiphenylphosphine {} {} {} {} {LY} Allyldiphenylphosphine {} {} {} {} {} {LY} Allyldiphenylphosphine {} {} {} {} {} {} {LY} Allyldiphenylphosphine {} {} {} {} {} {} {} {LY} Allyldiphenylphosphine {} {} {} {} {} {} {} {} {LY} Allyldiphenylphosphine {} {} {} {} {} {} {} {} {} {LY} Allyldiphenylphosphine {} {} {} {} {} {} {} {} {} {} {LY} Allyldiphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {LY} Allyldiphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {LY} Allyldiphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Allyldiphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Allyldiphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Allyldiphenylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Allyldiphenylphosphine {} {} {} {} {} {} {} {} {} {
PubChem Substance ID137699
Chemical Name Translation烯丙基二苯基膦
InChIKeyPDDYFPPQDKRJTK-UHFFFAOYSA-N
LabNetwork Molecule IDLN00200716
InChIInChI=1S/C15H15P/c1-2-13-16(14-9-5-3-6-10-14)15-11-7-4-8-12-15/h2-12H,1,13H2
Canonical SMILESC=CCP(C1=CC=CC=C1)C2=CC=CC=C2
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphine Ligands

产品应用

  • · Cocatalyst in palladium catalyzed hydrocarboxylation reactions
  • · Cocatalyst in Palladium catalyzed cross-coupling reactions
  • · Ligand for hydroformylation catalysts
  • · Ligand for the rhenium phosphinoborane pendant Lewis acid-assisted reductive coupling reactions
  • · Catalyst precursor for alkene hydroboration

安全信息

WGK Germany3
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
GHS Symbol
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Packing GroupIII
UN Number UN3278
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R25 Toxic if swallowed 吞咽有毒
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服;
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S20 When using do not eat or drink 使用时,不得进食,饮水;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Air Sensitive {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from lig
Hazard Codes Xi

系列性分类


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