Dibenzoyl-L-tartaric acid 二苯甲酰基-L-酒石酸

CAS 2743-38-6 MFCD00003074

化学结构图

2743-38-6
SMILES: O=C(O[C@@H](C(=O)O)[C@@H](OC(=O)c1ccccc1)C(=O)O)c1ccccc1

化学属性

Mol. FormulaC18H14O8
Mol. Weight358.30
Melting Point152-155°C
TSCAYes
Density1.438
Appearance 白色至类白色结晶粉末，熔点 151-154℃
Boiling Point606.6°C at 760 mmHg
Refractive index-116 ° (C=1, EtOH)

别名和识别编码

Chemical NameDibenzoyl-L-tartaric acid
MDL NumberMFCD00003074
CAS Number2743-38-6
EC Number241-097-1
Synonym L-(-)-Dibenzoyltartaric acid {LY} L-(-)-Dibenzoyltartaric acid SNC 86 SNC-86 SNC86 d-2,3-dibenzoyltartaric acid dibenzoyltartaric acid {} {LY} L-(-)-Dibenzoyltartaric acid {} {} {LY} L-(-)-Dibenzoyltartaric acid {} {} {} {LY} L-(-)-Dibenzoyltartaric acid {} {} {} {} {LY} L-(-)-Dibenzoyltartaric acid {} {} {} {} {} {LY} L-(-)-Dibenzoyltartaric acid {} {} {} {} {} {} {LY} L-(-)-Dibenzoyltartaric acid {} {} {} {} {} {} {} {LY} L-(-)-Dibenzoyltartaric acid {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {LY} L-(-)-Dibenzoyltartaric acid {} {} {} {} {} {} {} {} {} {LY} L-(-)-Dibenzoyltartaric acid {} {} {} {} {} {} {} {} {} {} {LY} L-(-)-Dibenzoyltartaric acid {} {} {} {} {} {} {} {} {} {} {} {LY} L-(-)-Dibenzoyltartaric acid {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} L-(-)-Dibenzoyltartaric acid {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} L-(-)-Dibenzoyltartaric acid {} {} {
PubChem Substance ID75969
Beilstein Registry Number709854
Chemical Name Translation二苯甲酰基-L-酒石酸
Reaxys-RN709854
LabNetwork Molecule IDLN00188287
InChIInChI=1S/C18H14O8/c19-15(20)13(25-17(23)11-7-3-1-4-8-11)14(16(21)22)26-18(24)12-9-5-2-6-10-12/h1-10,13-14H,(H,19,20)(H,21,22)/t13-,14-/m1/s1
Canonical SMILESO=C(O)[C@H](OC(C1=CC=CC=C1)=O)[C@@H](OC(C2=CC=CC=C2)=O)C(O)=O
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分类

  • {SNA} Asymmetric Synthesis, Carboxylic Acids, Chemical Synthesis, Chiral Building Blocks, Chiral Resolution Reagents, Chiral Resolving Reagents, Organic Building Blocks

相关文献及参考

  • Beilstein:9(3)870

安全信息

RTECSWW8070000
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Risk Statements
  • R36 Irritating to eyes 刺激眼睛
WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P302+P352
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P317
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P333+P313
  • P333+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H318 Causes serious eye damage 严重伤害眼睛
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Warning
Hazard Codes Xi
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 图谱信息:L-(-)-二苯甲酰酒石酸(2743-38-6)核磁图( 13 CNMR) L-(-)-二苯甲酰酒石酸(2743-38-6)核磁图( 1 HNMR) L-(-)-二苯甲酰酒石酸(2743-38-6)Raman光谱 L-(-)-二苯甲酰酒石酸(2743-38-6)红外图谱(IR1) L-(-)-二苯甲酰酒石酸(2743-38-6)红外图谱(IR2) L-(-)-二苯甲酰酒石酸(2743-38-6)质谱(MS)
  • 用途一:广泛用于手性拆分胺类化合物
  • Alfa Aesar:无水(-)-二苯甲酰-L-酒石酸,99% (-)-Dibenzoyl-L-tartaric acid, anhydrous, 99%(2743-38-6)
  • MOL 文件:2743-38-6.mol
  • Sigma Aldrich:2743-38-6(sigmaaldrich)
  • MSDS 信息:L(-)-Dibenzoyl-L-tartaric acid(2743-38-6).msds
  • F:3-9
  • TCI Shanghai:L-(-)-二苯甲酰酒石酸 (-)-Dibenzoyl-L-tartaric Acid,>;98.0%(LC)(T)(2743-38-6)
  • L-(-)-二苯甲酰酒石酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D3492 (-)-联苯甲酰-L-酒石酸 (-)-Dibenzoyl-L-tartaric Acid 25G 253元 2014/06/02 D3492 (-)-联苯甲酰-L-酒石酸 (-)-Dibenzoyl-L-tartaric Acid 250G 1300元 2010/05/25 A16181 无水(-)-二苯甲酰-L-酒石酸,99% (-)-Dibenzoyl-L-tartaric acid, anhydrous, 99% 25g 307元

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Resolution Reagents - Asymmetric Synthesis
  4. Chiral Resolving Reagents - Chiral Resolution Reagents
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Carboxylic Acids - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Carboxylic Acids - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块

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