Tetraphenylphosphonium bromide 四苯基溴化膦

CAS 2751-90-8 MFCD00011915

化学结构图

2751-90-8
SMILES: [Br-].c1ccc([P+](c2ccccc2)(c2ccccc2)c2ccccc2)cc1

化学属性

Mol. FormulaC24H20BrP
Mol. Weight419.30
Density1.422
Melting Point295-300°C
TSCAYes
Stability易吸潮
Flash Point260 °C
Appearance 白色针状结晶,熔点294-296℃,微溶于冷水,可溶于热水、乙醇、乙醚、苯、四氢呋喃等有机溶剂。

别名和识别编码

Chemical NameTetraphenylphosphonium bromide
CAS Number2751-90-8
EC Number220-393-4
Beilstein Registry Number3922383
MDL NumberMFCD00011915
PubChem Substance ID2724163
Merck Number14,9237
Synonym Tetraphenylphosphonium bromide {LY} Tetraphenylphosphonium bromide {} {LY} Tetraphenylphosphonium bromide {} {} {LY} Tetraphenylphosphonium bromide {} {} {} {LY} Tetraphenylphosphonium bromide {} {} {} {} {LY} Tetraphenylphosphonium bromide {} {} {} {} {} {LY} Tetraphenylphosphonium bromide {} {} {} {} {} {} {LY} Tetraphenylphosphonium bromide {} {} {} {} {} {} {} {LY} Tetraphenylphosphonium bromide {} {} {} {} {} {} {} {} {LY} Tetraphenylphosphonium bromide {} {} {} {} {} {} {} {} {} {LY} Tetraphenylphosphonium bromide {} {} {} {} {} {} {} {} {} {} {LY} Tetraphenylphosphonium bromide {} {} {} {} {} {} {} {} {} {} {} {LY} Tetraphenylphosphonium bromide {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetraphenylphosphonium bromide {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetraphenylphosphonium bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetraphenylphosphonium bromide {} {} {} {
Reaxys-RN3922383
Chemical Name Translation四苯基溴化膦
InChIKeyBRKFQVAOMSWFDU-UHFFFAOYSA-M
LabNetwork Molecule IDLN00189977
InChIInChI=1S/C24H20P.BrH/c1-5-13-21(14-6-1)25(22-15-7-2-8-16-22,23-17-9-3-10-18-23)24-19-11-4-12-20-24;/h1-20H;1H/q+1;/p-1
Canonical SMILESC1([P+](C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4)=CC=CC=C1.[Br-]
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分类

  • {SNA} Chemical Synthesis, Phase Transfer Catalysts, Phosphonium Salts, Synthetic Reagents

产品应用

  • 用于电还原富勒烯的支持电解质。

相关文献及参考

  • Thermally stable phase-transfer catalyst (see Appendix 2): in combination with o-phthaloyl chloride (nitrite trap), facilitates the otherwise difficult displacement by F- of a nitro-group meta to an activating group: Chem. Lett., 2213 (1989):
  • This salt, or the more water-soluble chloride (next entry), has been used to extract heavy metals from aqueous solution as ion-association complexes: J. Organomet. Chem., 160, 17 (1978), Z. Naturforsch. B, 33B(5), 533 (1978); Microchem. J., 22, 275 (1977).
  • For a similar reaction, see 4-Chlorobenzaldehyde, A12757.
  • Beilstein:16(2)373

安全信息

Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S37 Wear suitable gloves 戴适当手套;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Codes Xi

其他信息

  • 下游产品:
  • 海关编码:29310095
  • TCI Shanghai:四苯基溴化磷 Tetraphenylphosphonium Bromide,>;98.0%(T)(2751-90-8)
  • Sigma Aldrich:2751-90-8(sigmaaldrich)
  • MSDS 信息:Tetraphenylphosphonium bromide (2751-90-8).msds
  • Acros Organics:四苯基溴化膦 Tetraphenylphosphonium bromide, 99%(2751-90-8)
  • 敏感性:Hygroscopic
  • F:10
  • Alfa Aesar:四苯基溴化膦,98+% Tetraphenylphosphonium bromide, 98+%(2751-90-8)
  • MOL 文件:2751-90-8.mol
  • 四苯基溴化价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw060024 四苯基溴化鏻 100g 300元 2011/04/16 T1069 四苯基溴化磷 Tetraphenylphosphonium Bromide 25G 515元 2011/04/16 T1069 四苯基溴化磷 Tetraphenylphosphonium Bromide 500G 4320元
  • 图谱信息:四苯基溴化(2751-90-8)红外图谱(IR2) 四苯基溴化(2751-90-8)质谱(MS) 四苯基溴化(2751-90-8)核磁图( 13 CNMR) 四苯基溴化(2751-90-8)核磁图( 1 HNMR) 四苯基溴化(2751-90-8)红外图谱(IR1)
  • 用途一:用作相转移催化剂

系列性分类


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