Triethyltin Bromide 三乙基溴化锡

CAS 2767-54-6 MFCD00000052

化学结构图

2767-54-6
SMILES: CC[Sn](Br)(CC)CC

化学属性

Mol. FormulaC6H15BrSn
Mol. Weight285.80
Refractive indexn20/D 1.526(lit.)
Boiling Point222-224 °C(lit.)
Density1.63 g/mL at 25 °C(lit.)
Flash Point99°(210°F)
TSCAYes
Melting Point-13.5°

别名和识别编码

Chemical NameTriethyltin Bromide
MDL NumberMFCD00000052
CAS Number2767-54-6
Synonym Bromotriethylstannane {LY} Bromotriethylstannane {} {LY} Bromotriethylstannane {} {} {LY} Bromotriethylstannane {} {} {} {LY} Bromotriethylstannane {} {} {} {} {LY} Bromotriethylstannane {} {} {} {} {} {LY} Bromotriethylstannane {} {} {} {} {} {} {LY} Bromotriethylstannane {} {} {} {} {} {} {} {LY} Bromotriethylstannane {} {} {} {} {} {} {} {} {LY} Bromotriethylstannane {} {} {} {} {} {} {} {} {} {LY} Bromotriethylstannane {} {} {} {} {} {} {} {} {} {} {LY} Bromotriethylstannane {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} Bromotriethylstannane {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bromotriethylstannane {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bromotriethylstannane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bromotriethylstannane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bromotriethylstannane {} {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID17701
EC Number220-443-5
Chemical Name Translation三乙基溴化锡
Wiswesser Line NotationE-SN-2&2&2
LabNetwork Molecule IDLN02145030
InChIInChI=1S/3C2H5.BrH.Sn/c3*1-2;;/h3*1H2,2H3;1H;/q;;;;+1/p-1
Canonical SMILESCC[Sn](CC)(CC)Br
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分类

  • {uni_hamburg} no charge; metal-organic; 1fragment
  • Chemical Synthesis, Organometallic Reagents, Organotin, Organotin Halides
  • {SNA} Chemical Synthesis, Organometallic Reagents, Organotin, Organotin Halides

相关文献及参考

  • Beil. 4 ,633
  • Corp MSDS 1 (2), 3437:C / FT-IR 2 (3), 4483:A / FT-NMR 1 (3), 741:A / RegBook 1 (2), 3049:I / Structure Index 1 , 482:B:8 / Vapor Phase 3 , 1685:D
  • Short: III/20b Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei Cl ... Rb Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20b Year: 1988 Keyword: NQR ISBN: 3-540-18483-X ISBN: 978-3-540-18483-6 Internet Resource: DOI:10.1007/b86664 RefComment: IX,717 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
  • Short: III/35D5 Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Carbon-13, Part 5: Organometallic Compounds Author: Mikhova, Bozhana Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35D5 Year: 2008 Keyword: Carbon-13; chemical shift; magnetic properties of nuclei; nuclear magnetic resonance data ISBN: 978-3-540-74188-6 (print) ISBN: 978-3-540-74189-3 (electronic) Internet Resource: DOI:10.1007/978-3-540-74189-3 RefComment: VIII, 241 p., Hardcover RefComment: Written for Scientists and engineers in the fields of physics, chemistry and physical chemistry who intend to use NMR to study the structure and the binding of molecules Abstract: Nuclear Magnetic Resonance (NMR) is based on the fact that certain nuclei exhibit a magnetic moment, oriented by a magnetic field, and absorb characteristic frequencies in the radiofrequency part of the spectrum. The spectral lines of the nuclei are highly influenced by t

安全信息

GHS Symbol
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S27/28
WGK Germany2
Hazard Codes T+,N
Hazard statements
  • H330 Fatal if inhaled 吸入致命
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H310 Fatal in contact with skin 皮肤接触致命
  • H300 Fatal if swallowed 吞食致命
  • H300+H310+H330
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Risk Statements
  • R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有剧毒
  • R50/53
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P301+P310
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
Signal word Danger
Packing GroupII
UN Number UN2788
Storage condition Moisture Sensitive
RTECSWH6740000 
TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1640 mg/m3/10M
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - lacrimation
   Behavioral - convulsions or effect on seizure threshold
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   NDRC** National Defense Research Committee, Office of Scientific Research
   and Development, Progress Report.  Volume(issue)/page/year:
   NDCrc-132,FEB1942

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 6 mg/kg
SEX/DURATION            : lactating female 1 day(s) post-birth
TOXIC EFFECTS :
   Reproductive - Effects on Newborn - behavioral
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   72,557,1984

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organotin 有机锡
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organotin 有机锡
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organotin 有机锡
  4. Organotin Halides - Organotin

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