(4-Nitrobenzyl)Triphenylphosphonium Bromide (4-硝基苄基)三苯基溴化鏻

CAS 2767-70-6 MFCD00032108

化学结构图

2767-70-6
SMILES: O=[N+]([O-])c1ccc(C[P+](c2ccccc2)(c2ccccc2)c2ccccc2)cc1.[Br-]

化学属性

Mol. FormulaC25H21BrNO2P
Mol. Weight478.32
Melting Point275 °C
TSCANo

别名和识别编码

Chemical Name(4-Nitrobenzyl)Triphenylphosphonium Bromide
Synonym (4-Nitrobenzyl)triphenylphosphonium bromide {LY} (4-Nitrobenzyl)triphenylphosphonium bromide {} {LY} (4-Nitrobenzyl)triphenylphosphonium bromide {} {} {LY} (4-Nitrobenzyl)triphenylphosphonium bromide {} {} {} {LY} (4-Nitrobenzyl)triphenylphosphonium bromide {} {} {} {} {LY} (4-Nitrobenzyl)triphenylphosphonium bromide {} {} {} {} {} {LY} (4-Nitrobenzyl)triphenylphosphonium bromide {} {} {} {} {} {} {LY} (4-Nitrobenzyl)triphenylphosphonium bromide {} {} {} {} {} {} {} {LY} (4-Nitrobenzyl)triphenylphosphonium bromide {} {} {} {} {} {} {} {} {LY} (4-Nitrobenzyl)triphenylphosphonium bromide {} {} {} {} {} {} {} {} {} {LY} (4-Nitrobenzyl)triphenylphosphonium bromide {} {} {} {} {} {} {} {} {} {} {LY} (4-Nitrobenzyl)triphenylphosphonium bromide {} {} {} {} {} {} {} {} {} {} {} {LY} (4-Nitrobenzyl)triphenylphosphonium bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (4-Nitrobenzyl)triphenylphosphonium bromide {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00032108
PubChem Substance ID197008
CAS Number2767-70-6
EC Number220-444-0
Reaxys-RN3834220
Beilstein Registry Number3834220
Chemical Name Translation(4-硝基苄基)三苯基溴化鏻
InChIKeyIPJPTPFIJLFWLP-UHFFFAOYSA-M
Wiswesser Line NotationWNR D1PR&R&R &E
LabNetwork Molecule IDLN00246579
InChIInChI=1S/C25H21NO2P.BrH/c27-26(28)22-18-16-21(17-19-22)20-29(23-10-4-1-5-11-23,24-12-6-2-7-13-24)25-14-8-3-9-15-25;/h1-19H,20H2;1H/q+1;/p-1
Canonical SMILESO=[N+](C1=CC=C(C[P+](C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4)C=C1)[O-].[Br-]
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分类

  • {SA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents
  • {SNA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents

相关文献及参考

  • 1. K. Motoshima, et al., Bioorg. Med. Chem. 19 , 3156-3172, (2011)
  • 2. A. M. Costero, et al., Chem. Asian J. 5 , 1573-1585, (2010)
  • 3. Q. Xu, et al., J. Macromol. Sci., Pure Appl. Chem. 47 , 343-349, (2010)
  • 4. I. Skoric, et al., J. Photochem. Photobiol., A 211 , 152-161, (2010)
  • 5. F. O. Silverio, et al., Pest Mgmt Sci. 65 , 900-905, (2009)
  • 6. T. Rodrigues, et al., Bioorg. Med. Chem. Lett. 19 , 3476-3480, (2009)
  • Beil. 16 ,III,854
  • FT-IR 2 (2), 3336:C / Structure Index 1 , 356:C:7

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P405 Store locked up. 上锁保管。
  • P501a
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
RTECSTA2390000
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 18 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#00884

Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • Alfa Aesar:（4－硝基苄基）三苯基溴化膦,98% (4-Nitrobenzyl)triphenylphosphonium bromide, 98%(2767-70-6)
  • 4-硝基苄基三苯基溴蓊盐价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 N0701 (4-硝基苄基)三苯基溴化膦 (4-Nitrobenzyl)triphenylphosphonium Bromide 25G 837元 2010/05/25 A15288 （4－硝基苄基）三苯基溴化膦, 98% (4-Nitrobenzyl)triphenylphosphonium bromide, 98% 5g 253元 2010/05/25 A15288 （4－硝基苄基）三苯基溴化膦, 98% (4-Nitrobenzyl)triphenylphosphonium bromide, 98% 25g 997元
  • Acros Organics:4-硝基苄基三苯基溴蓊盐 4-Nitrobenzyl triphenylphosphonium bromide, 97%(2767-70-6)
  • TCI Shanghai:(4-硝基苄基)三苯基溴化膦 (4-Nitrobenzyl)triphenylphosphonium Bromide,>;98.0%(T)(2767-70-6)
  • MOL 文件:2767-70-6.mol
  • Sigma Aldrich:2767-70-6(sigmaaldrich)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Wittig Reagents - Olefination
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Wittig Reagents - Olefination
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Others - Olefination
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Wittig & Horner-Emmons Reaction
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Phosphonium Compounds

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