9-Borabicyclo[3.3.1]nonane 9-硼双环[3.3.1]壬烷

CAS 280-64-8 MFCD00074742

化学结构图

280-64-8
SMILES: B1C2CCCC1CCC2

化学属性

Mol. FormulaC8H15B
Mol. Weight122.02
Density0.894
Boiling Point68-70 °C
Flash Point-19°(-2°F)
Solubility起反应
TSCANo
Stability对空气和水分敏感
Danger-Level甲类
pH:A

别名和识别编码

Chemical Name9-Borabicyclo[3.3.1]nonane
CAS Number280-64-8
EC Number206-000-9
Beilstein Registry Number605509
MDL NumberMFCD00074742
Synonym 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal {} {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal {} {} {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal {} {} {} {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal {} {} {} {} {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal {} {} {} {} {} {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal {} {} {} {} {} {} {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal {} {} {} {} {} {} {} {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal {} {} {} {} {} {} {} {} {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal {} {} {} {} {} {} {} {} {} {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal {} {} {} {} {} {} {} {} {} {} {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} 9-Borabicyclo[3.3.1]nonane,0.5M in THF,Safeseal {} {} {} {} {} {} {} {} {} {
PubChem Substance ID6327450
Chemical Name Translation9-硼双环[3.3.1]壬烷
InChIKeyFEJUGLKDZJDVFY-UHFFFAOYSA-N
LabNetwork Molecule IDLN00222630
InChIInChI=1S/C8H14B/c1-3-7-5-2-6-8(4-1)9-7/h7-8H,1-6H2
Canonical SMILESC1(B2)CCCC2CCC1
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分类

  • {SNA} 25mL Sure/Seal Reagents, Boranes, Chemical Synthesis, Organometallic Reagents, Reduction, Synthetic Reagents
  • {SNA} Boranes, Chemical Synthesis, Reduction, Synthetic Reagents

产品应用

  • 使用 9-BBN 对相应环状缩醛进行还原以鉴别对称二醇。
  • 选择性硼氢化还原试剂。
  • Reactant for:
  • • Linear SPPS synthesis of ubiquitin derivatives
  • • Copper-catalyzed cross-coupling reactions of organoboron compounds with primary alkyl halides and pseudohalides
  • • Intramolecular insertion of alkenes into palladium-nitrogen bonds
  • • Preparation of (phosphonoacetyl)ornithine to study effect on arginine biosynthetic genes in yeast
  • • Hetero-Diels-Alder reaction for synthesis of spirocyclic alkaloids

安全信息

Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S30 Never add water to this product 切勿将水加入该产品中；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
  • S7/8 Keep container tightly closed and dry 保存在严格密闭容器中，保持干燥；
Risk Statements
  • R11 Highly flammable 非常易燃
  • R14 Reacts violently with water 遇水会猛烈反应
  • R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应，释放出高度可燃气体
  • R15 Contact with water liberates extremely flammable gases 遇水会释放出极端易燃的气体
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R38 Irritating to skin 刺激皮肤
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R48/20
  • R51/53
  • R62 Possible risk of impaired fertility 有削弱生殖能力的危险
  • R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P222 Do not allow contact with air. 不要与空气接触。
  • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能，因为会剧烈反应可能产生闪火。
  • P231+P232
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P330+P331
  • P302+P334
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P331 Do NOT induce vomiting.. 不要催吐。
  • P335+P334
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P402+P404
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P422 Store contents under… 存储目录在…之下。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
  • H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体，可自燃。
  • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H351 Suspected of causing cancer 怀疑致癌
  • H361 Suspected of damaging fertility or the unborn child 怀疑对生育能力或未出生婴儿造成伤害
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 4.3 F,Xn F,Xn,N F,Xn,Xi,N F;Xi
UN Number 3399
Packing GroupI
Storage condition 2-8°C {LY} 2-8°C Flammables area {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°

其他信息

  • HazardClass:4.1
  • 9-硼双环[3.3.1]壬烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 165818000 9-硼双环[3.3.1]壬烷 9-Borabicyclo[3.3.1]nonane , 0.5M solution in THF, AcroSeal® 800 ML 2077元 2010/06/21 165811000 9-硼双环[3.3.1]壬烷 9-Borabicyclo[3.3.1]nonane , 0.5M solution in THF, AcroSeal® 100 ML 523元
  • MOL 文件:280-64-8.mol
  • PackingGroup:III
  • F:1-10-34

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Aromatic alcohols 芳香醇

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