Bis(2-dimethylaminoethyl) ether 双二甲胺基乙基醚

CAS 3033-62-3 MFCD00059199

化学结构图

3033-62-3
SMILES: CN(C)CCOCCN(C)C

化学属性

Mol. FormulaC8H20N2O
Mol. Weight160.26
Density0.841
Refractive index1.4270 to 1.4320
Flash Point66.11°C
TSCAYes
Boiling Point189 °C at 760 mmHg
Appearance 无色或浅黄色透明液体, ; 溶于水,醇及醚类溶剂, 沸程 186-190℃
pH:A

别名和识别编码

Chemical NameBis[2-​(dimethylamino)​ethyl] ether
CAS Number3033-62-3
Synonym 2,2'-Oxybis(N,N-dimethylethanamine) {LY} 2,2'-Oxybis(N,N-dimethylethanamine) 2,2'-oxybis(N,N-dimethylethylamine) DMAEE bis(2-(dimethylamino)ethyl) ether {} {LY} 2,2'-Oxybis(N,N-dimethylethanamine) {} {} {LY} 2,2'-Oxybis(N,N-dimethylethanamine) {} {} {} {LY} 2,2'-Oxybis(N,N-dimethylethanamine) {} {} {} {} {LY} 2,2'-Oxybis(N,N-dimethylethanamine) {} {} {} {} {} {LY} 2,2'-Oxybis(N,N-dimethylethanamine) {} {} {} {} {} {} {LY} 2,2'-Oxybis(N,N-dimethylethanamine) {} {} {} {} {} {} {} {LY} 2,2'-Oxybis(N,N-dimethylethanamine) {} {} {} {} {} {} {} {} {LY} 2,2'-Oxybis(N,N-dimethylethanamine) {} {} {} {} {} {} {} {} {} {LY} 2,2'-Oxybis(N,N-dimethylethanamine) {} {} {} {} {} {} {} {} {} {} {LY} 2,2'-Oxybis(N,N-dimethylethanamine) {} {} {} {} {} {} {} {} {} {} {} {LY} 2,2'-Oxybis(N,N-dimethylethanamine) {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,2'-Oxybis(N,N-dimethylethanamine) {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,2'-Oxybis(N,N-dimethy
MDL NumberMFCD00059199
EC Number221-220-5
Beilstein Registry Number1739668
PubChem Substance ID18204
Reaxys-RN1739668
Chemical Name Translation双二甲胺基乙基醚
Wiswesser Line Notation1N1&2 2O
LabNetwork Molecule IDLN00223421
InChIInChI=1S/C8H20N2O/c1-9(2)5-7-11-8-6-10(3)4/h5-8H2,1-4H3
Canonical SMILESCN(C)CCOCCN(C)C
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Polyamines
  • Intermediates
  • Aliphatics
  • Amines

产品应用

  • Bis(2-dimethylaminoethyl) Ether is used in the manufacturing of flexible polyurethane foams.

安全信息

RTECSKR9460000
Packing GroupII
UN Number 2927 2929 UN 2927 6.1/PG 2 UN2922
Risk Statements
  • R20 Harmful by inhalation 吸入有害
  • R22 Harmful if swallowed 吞咽有害
  • R23/24 Toxic by inhalation and in contact with skin 吸入及皮肤接触都有毒
  • R24 Toxic in contact with skin 与皮肤接触有毒
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
GHS Symbol
Hazard Codes 6.1 T
WGK Germany2
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H331 Toxic if inhaled 吸入中毒
  • H332 Harmful if inhaled 吸入有害
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛,皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P312
  • P301+P317
  • P301+P330+P331
  • P301+P330+P331+P310
  • P302+P352
  • P302+P361+P354
  • P303+P361+P353
  • P304+P312
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P316
  • P317
  • P320 Specific treatment is urgent (see … on this label). 紧急具体治疗(见本标签上的)。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P361+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P403 Store in a well-ventilated place. 储存在通风良好的地方。
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Hazard Class6.1/3
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 280 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   30,470,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1070 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JTOTDO Journal of Toxicology, Cutaneous and Ocular Toxicology.  (Marcel
   Dekker, 270 Madison Ave., New York, NY 10016)  V.1-    1982-
   Volume(issue)/page/year: 5,3,1986

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 117 ppm/6H
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - corneal damage
   Lungs, Thorax, or Respiration - other changes
   Gastrointestinal - other changes
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0536387

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE                    : 650 mg/kg
SEX/DURATION            : female 6-18 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   JTOTDO Journal of Toxicology, Cutaneous and Ocular Toxicology.  (Marcel
   Dekker, 270 Madison Ave., New York, NY 10016)  V.1-    1982-
   Volume(issue)/page/year: 5,263,1986

Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 职业标准:TWA 0.05 PPM; STEL 0.33 PPM
  • 刺激数据:皮肤-兔子 100 毫克/24小时 重度; 眼睛-兔子 0.25毫克/24小时 重度
  • 可燃性危险特性:可燃; 燃烧产生有毒氮氧化物烟雾
  • 毒性分级:高毒
  • Alfa Aesar:双(2-二甲基氨乙基)醚,98% Bis(2-dimethylaminoethyl) ether, 98%(3033-62-3)
  • 图谱信息:双二甲胺基乙基醚(3033-62-3)Raman光谱 双二甲胺基乙基醚(3033-62-3)质谱(MS) 双二甲胺基乙基醚(3033-62-3)红外图谱(IR1)
  • 用途一:作为高效叔胺催化剂,几乎适用于所有泡沫塑料制品的生产,主要用于软质泡沫制品,特别适合高回弹制品
  • TCI Shanghai:双二甲氨基乙基醚 Bis(2-dimethylaminoethyl) Ether,>;98.0%(GC)(3033-62-3)
  • MSDS 信息:Bis(2-dimethylaminoethyl) ether(3033-62-3).msds
  • 储运特性:库房通风低温干燥; 与食品原料分开存放
  • 下游产品:6-氨基青霉烷酸 --> 二嗪农 --> 2-异丙基-6-甲基-4-吡啶醇 --> 聚氧丙烯聚氧乙烯多惭烯多胺醚硅氧烷共聚物 --> 2-(甲氧基羰基)苯硼酸 --> 3-甲氧基羰基苯硼酸
  • 急性毒性:口服-大鼠 LD50; 1070毫克/公斤; 皮肤-兔子 LD50: 280 毫升/公斤
  • Sigma Aldrich:3033-62-3(sigmaaldrich)
  • 灭火剂:干粉,泡沫,沙土,二氧化碳, 雾状水
  • 双二甲胺基乙基醚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B1291 双(2-二甲氨基乙基)醚 Bis(2-dimethylaminoethyl) Ether 500ML 1890元 2014/06/02 B1291 双(2-二甲氨基乙基)醚 Bis(2-dimethylaminoethyl) Ether 25ML 252元 2010/05/25 L09884 双(2-二甲基氨乙基)醚, 98% Bis(2-dimethylaminoethyl) ether, 98% 50g 1946元
  • MOL 文件:3033-62-3.mol
  • 类别:有毒物品

系列性分类


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