Potassium sodium tartrate solution L-酒石酸钾钠

CAS 304-59-6 MFCD00065391

化学结构图

304-59-6
SMILES: O=C([O-])[C@H](O)[C@@H](O)C(=O)[O-].[K+].[Na+]

化学属性

Mol. FormulaC4H4KNaO6
Mol. Weight210.16
Appearance 酒石酸钾钠(304-59-6)为白色结晶颗或无色透明。相对密度1.79,熔点70-80℃。在热空气中稍有风化性。60℃开始失去部分结晶水,热至100℃时失去3个水分子,215℃变成无水盐。易溶于水,溶液呈微碱性。
Boiling Point100 °C at 760 mmHg
Melting Point70-80 °C
Solubility溶于0.9份水中,几乎不溶于乙醇。
Density1.24

别名和识别编码

Chemical NamePotassium sodium tartrate solution
Synonym Potassium sodium tartrate {LY} Potassium sodium tartrate {} {LY} Potassium sodium tartrate {} {} {LY} Potassium sodium tartrate {} {} {} {LY} Potassium sodium tartrate {} {} {} {} {LY} Potassium sodium tartrate {} {} {} {} {} {LY} Potassium sodium tartrate {} {} {} {} {} {} {LY} Potassium sodium tartrate {} {} {} {} {} {} {} {LY} Potassium sodium tartrate {} {} {} {} {} {} {} {} {LY} Potassium sodium tartrate {} {} {} {} {} {} {} {} {} {LY} Potassium sodium tartrate {} {} {} {} {} {} {} {} {} {} {LY} Potassium sodium tartrate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Potassium sodium tartrate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Potassium sodium tartrate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Potassium sodium tartrate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Potassium sodium tartrate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Potassi
MDL NumberMFCD00065391
CAS Number304-59-6
EC Number231-791-2
PubChem Substance ID9357
Chemical Name TranslationL-酒石酸钾钠
InChIKeyLJCNRYVRMXRIQR-OLXYHTOASA-L
LabNetwork Molecule IDLN01303159
InChIInChI=1S/C4H6O6.K.Na/c5-1(3(7)8)2(6)4(9)10;;/h1-2,5-6H,(H,7,8)(H,9,10);;/q;2*+1/p-2/t1-,2-;;/m1../s1
Canonical SMILES[C@@H]([C@H](C(O)=O)O)(C(O)=O)O.[K].[Na]
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分类

  • {SNA} Alphabetical, BioUltra Buffers, Biochemicals and Reagents, Buffer Solutions, Chelators, Optimization Reagents, Protein Structural Analysis, X-Ray Crystallography, 分子生物学, 生物缓冲液, 蛋白质组学
  • {SNA} Alphabetical, BioUltra Buffers,

相关文献及参考

  • Short: III/20a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cl Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20a Year: 1988 Keyword: NQR ISBN: 3-540-18161-X ISBN: 978-3-540-18161-3 Internet Resource: DOI:10.1007/b31153 RefComment: IX,677 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
  • Short: IV/1a Title: Densities of Liquid Systems: Nonaqueous Systems and Ternary Aqueous Systems Author: Lacmann, R.; Synowietz, C. Editor: Schäfer, Kl. Source: Landolt-Börnstein, New Series Volume: IV/1a Year: 1974 ISBN: 3-540-06269-6 ISBN: 978-3-540-06269-1 Internet Resource: DOI:10.1007/b20003 RefComment: X, 716 pages. Hardcover Abstract: Volume IV/1 contains information on the densities of liquid systems. It may be considered as a supplement to volume II/1 of the 6th Edition, which contains only a few data on nonaqueous systems. Data are not listed for all systems but primarily for those of greater interest where data for a larger range of concentrations were available.
  • Short: IV/1b Title: Densities of Liquid Systems: Densities of Binary Aqueous Systems and Heat Capacities of Liquid Systems Author: D'Ans, J.; Surawski, H.; Synowietz, C. Editor: Schäfer, Kl. Source: Landolt-Börnstein, New Series Volume: IV/1b Year: 1977 ISBN: 3-540-08272-7 ISBN: 978-3-540-08272-9 Internet Resource: DOI:10.1007/b20004 RefComment: 62 figs., VII, 335 pages. Hardcover Abstract: Volume IV/1 contains information on the densities of liquid systems. It may be considered as

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves
UN Number UN 1824 8/PG 2
Hazard Codes C
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R35 Causes severe burns 会导致严重灼伤
Storage condition 2-8°C, sealed storage, away from moisture {LY} 2-8°C, sealed storage, away from moisture {} {LY} 2-8°C, sealed storage, away from moisture {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {}

其他信息

  • 参考质量指标:【 美国食品化学法典(III) 】 项 目 指 标 含量%≥ 99.0-102.0 碱度 合格 砷(以As计)%≤ 0.0003 重金属(以Pb计)%≤ 0.001 水分% 21-26 【企业标准 浙Q/HG079-81(电镀级) 】 项 目 指 标 酒石酸钾钠含量%≥ 98.0 氯化物(Cl)%≤ 0.005 重金属(以Pb计)%≤ 0.001 硫酸盐(SO4)%≤ 0.03 铁(Fe)%≤ 0.002 砷(以As计)%≤ 0.0002 水溶液反应 合格 水不溶物%≤ 0.01
  • 使用限量:FDA,§184.1804.(2000):以GMP为限。
  • 含量分析:按GT-2方法测定。每Ml 0.5mol/L硫酸相当于酒石酸钾钠(C4H4KNaO6?4H2O)70.56mg。
  • Sigma Aldrich:304-59-6(sigmaaldrich)
  • 参考质量标准:FCC,1996 含量 99.0%~102.0% 碱度 5%水溶液对石蕊呈碱性,在10ml该溶液中添加0.2ml的0.1mol/L硫酸后,再添1滴酚酞试剂,无桃红色出现 重金属(以Pb十,GT-16-2,试样2g) ≤10mg/kg 水分 21.0%~26.0%
  • 用途二:食品工业中用作焙粉,印刷业中用于制版、制镜
  • 上游原料:氢氧化钠 --> 碳酸钾 --> 碳酸钠 --> 氢氧化钾 --> 过氧化氢 --> 马来酸酐 --> 碳酸氢钾 --> DL-酒石酸
  • 毒性:无毒。GRAS(FDA,§184.1804,2000)。 ADI 0~30mg/kg(FAO/WHO,2001)。
  • MOL 文件:304-59-6.mol
  • 概述:酒石酸钾钠(分子式KNaC4H4O6·4H2O)也称酒石酸钠钾、罗氏盐、罗谢尔盐,是酒石酸钠与酒石酸钾形成的复盐。它是无色至蓝白色正交晶系晶体,可溶于水,微溶于醇,味咸而凉,水溶液呈微碱性。比重1.79,PH值为6.8-8,熔点70-80°C,在热空气中稍有风化性。60°C开始失去部分结晶水,100°C时失去3个水分子,215°C时失去全部结晶水变成无水盐,酒石酸钾钠分D型和DL型两种,D型为无色透明结晶体,在水中的溶解度30℃时100 ml为138.3g。不溶于醇。具有络合性,能与铜、铁、铅、铬、锦等金属离子在碱性溶液中形成可溶性络合物。DL型为白色细粒结晶体,密度1.783g/cm3。熔点100℃。在热空气中有风化性,60℃失去部分结晶水,215℃失去全部结晶水。在水中的溶解度30℃时l00ml为117.62g不溶于醇。具有络合性。 两摩尔的酒石酸氢钾溶于水加热,加入一摩尔碳酸钠,趁热过滤,不溶物干燥结晶,即得到酒石酸钾钠。 可用作缓泻剂、食品添加剂、压电元件,也可作化学试剂,用于配制菲林试剂、双缩脲试剂以及作为制镜时的还原剂。
  • 用途一:用于费林溶液、斑氏溶液的配制,还用作压电元件
  • 酒石酸钾钠的作用与用途:用于配制斐林氏溶液、双缩脲试剂,掩蔽剂、还原剂测定,食品添加剂,血清蛋白的生化检验。还用于印刷工业制版、制镜;热水瓶工业作还原剂;电镀工业作络合剂;医药上作缓泻剂;电讯工业上用以制晶体喇叭及话筒;化肥工业ADA脱硫剂等。
  • 制备方法与生产工艺:将原料酒石酸放入缸内,加入二倍量的水,用蒸汽加热煮沸后,在不断搅拌下,慢慢加入干态的碳酸钠中和,直至不产生气泡为止。这时溶液用石蕊试纸试验呈中性。趁热用布袋过滤。滤液应透明或接近透明。将滤液移入搪瓷桶内,加热蒸发浓至溶液浓度为38-42波美度,取出置于浅盘内(厚度以15-20厘米为宜),在室温下静置24小时即自然结晶。分出母液,取出结晶,用冷水洗涤一次(洗水与母液合并回收),即得酒石酸钾钠粗制品。将粗制品加适量水(1-2倍)加热溶解,加入活性炭脱色(活性炭加入量为样品量的5-15%)搅拌10分钟后,过滤(滤液用粗结晶的处理办法,进行再
  • MSDS 信息:Potassium sodium tartrate(304-59-6).msds
  • 下游产品:氨 --> 硫磺 --> 硫代硫酸钠 --> 硫磺 --> 硫氰酸钠 --> 硫代硫酸钠

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