Tetrabutylammonium iodide 四丁基碘化铵

CAS 311-28-4 MFCD00011636

化学结构图

311-28-4
SMILES: CCCC[N+](CCCC)(CCCC)CCCC.[I-]

化学属性

Mol. FormulaC16H36IN
Mol. Weight369.37
Melting Point141-143°C
TSCAYes
Density1.2
Stability对光敏感
Solubilityacetonitrile: 0.1 g/mL, clear, colorless
Boiling Point145.3 °C at 760 mmHg

别名和识别编码

Chemical NameTetrabutylammonium iodide
Synonym Tetrabutylammonium (iodide) {LY} Tetrabutylammonium (iodide) {} {LY} Tetrabutylammonium (iodide) {} {} {LY} Tetrabutylammonium (iodide) {} {} {} {LY} Tetrabutylammonium (iodide) {} {} {} {} {LY} Tetrabutylammonium (iodide) {} {} {} {} {} {LY} Tetrabutylammonium (iodide) {} {} {} {} {} {} {LY} Tetrabutylammonium (iodide) {} {} {} {} {} {} {} {LY} Tetrabutylammonium (iodide) {} {} {} {} {} {} {} {} {LY} Tetrabutylammonium (iodide) {} {} {} {} {} {} {} {} {} {LY} Tetrabutylammonium (iodide) {} {} {} {} {} {} {} {} {} {} {LY} Tetrabutylammonium (iodide) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetrabutylammonium (iodide) {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetrabutylammonium (iodide) {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetrabutylammonium (iodide) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetrabutylammonium (iodide) {} {} {} {} {} {} {}
CAS Number311-28-4
PubChem Substance ID67553
Beilstein Registry Number3916152
MDL NumberMFCD00011636
EC Number206-220-5
Reaxys-RN3916152
Chemical Name Translation四丁基碘化铵
InChIKeyDPKBAXPHAYBPRL-UHFFFAOYSA-M
Wiswesser Line Notation4K4&4&4 &I
LabNetwork Molecule IDLN00008641
InChIInChI=1S/C16H36N.HI/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;/h5-16H2,1-4H3;1H/q+1;/p-1
Canonical SMILESCCCC[N+](CCCC)(CCCC)CCCC.[I-]
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分类

  • {SNA} Ammonium Salts, Chemical Synthesis, Phase Transfer Catalysts, Synthetic Reagents
  • {SNA} Ammonium Salts, Chemical Synthesis, Electrochemistry, Phase Transfer Catalysts, Supporting Electrolytes for Electrochemistry, Synthetic Reagents, 分析/色谱, 分析试
  • {SNA} Acidic Ion Pair Reagents (Anionic), Buffers & Reagents, Chromatography Reagents & Solvents, HPLC, Ion Pair Reagents, Ion Pair Reagents - Anionic, 分析/色谱, 分析试剂
  • {SNA} Ammonium Salts, Analytical Reagents, Analytical/Chromatography, Chemical Synthesis, Electrochemistry,
  • Acidic Ion Pair Reagents (Anionic), Analytical Reagents,

产品应用

  • 离子对色谱试剂，相转移催化剂，极谱分析试剂。有机合成。

相关文献及参考

  • Aliphatic and aromatic sulfonic acids are reduced to thiols in the presence of trifluoroacetic anhydride, followed by hydrolysis of the resulting trifluoroacetates: Tetrahedron Lett., 21, 1235 (1980).
  • Catalyst for the high-yield methylation of alcohols with dimethyl sulfate: Angew. Chem., 85, 868; Angew. Chem. Int. Ed., 12, 846 (1973), or the benzylation of alcohols with benzyl bromide in organic solvents: Org. Synth. Coll., 8, 34 (1993); 9, 52 (1998).
  • Useful source of I- for nucleophilic displacements, e.g. in the formation of neopentyl iodides from the triflates: J. Org. Chem., 45, 4387 (1980).
  • Short: III/31a
  • Beilstein:4(4)558
  • In combination with Boron trifluoride diethyl­ etherate, A15275, has been used in a mild, versatile cleavage of ethers: Synthesis, 274 (1985).

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xn
RTECSBS5450000
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P312+P330
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害
Storage condition RT, sealed storage, away from moisture and light {LY} RT, sealed storage, away from moisture and light {} {LY} RT, sealed storage, away from moisture and light {} {} {LY} RT, sealed storage, away from moisture and light {} {} {} {LY} RT, sealed storage, away from moisture and light {} {} {} {} {LY} RT, sealed storage, away from moisture and light {} {} {} {} {} {LY} RT, sealed storage, away from moisture and light {} {} {} {} {} {} {LY} RT, sealed storage, away from moisture and light {} {} {} {} {} {} {} {LY} RT, sealed storage, away from moisture and light {} {} {} {} {} {} {} {} {LY} RT, sealed storage, away from moisture and light {} {} {} {} {} {} {} {} {} {LY} RT, sealed storage, away from moisture and light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, sealed storage, away from moisture and light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, sealed storage, away from moisture and light {} {} {} {} {} {} {} 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1990 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J.,
   Prague, Czechoslovakia, Avicenum, 1986  Volume(issue)/page/year: -,489,1986

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1600 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPMSAE Journal of Pharmaceutical Sciences.  (American Pharmaceutical Assoc.,
   2215 Constitution Ave., NW, Washington, DC 20037)  V.50-    1961-
   Volume(issue)/page/year: 69,327,1980

其他信息

  • Alfa Aesar:四正丁基碘化铵,98% Tetra-n-butylammonium iodide, 98%(311-28-4)
  • Acros Organics:四丁基碘化铵 Tetrabutylammonium iodide, 98%(311-28-4)
  • 图谱信息:四丁基碘化铵(311-28-4)核磁图( 13 CNMR) 四丁基碘化铵(311-28-4)质谱(MS) 四丁基碘化铵(311-28-4)红外图谱(IR1) 四丁基碘化铵(311-28-4)核磁图( 1 HNMR) 四丁基碘化铵(311-28-4)红外图谱(IR2)
  • 海关编码:29239000
  • F:8
  • 检测方法:T,NMR,TITR
  • MSDS 信息:Tetrabutylammonium iodide(311-28-4).msds
  • 易吸湿。溶于水和乙醇，微溶于氯仿。有刺激性。水中溶解度<5%。
  • 外观性质:白色或微黄色结晶。易吸湿。溶于水和乙醇，微溶于氯仿。有刺激性。水中溶解度<5%。熔点:145-148℃
  • TCI Shanghai:四丁基碘化铵 Tetrabutylammonium Iodide,>;98.0%(T)(311-28-4)
  • 用途二:离子对色谱试剂，相转移催化剂，极谱分析试剂。有机合成。
  • MOL 文件:311-28-4.mol
  • 敏感性:Light Sensitive & Hygroscopic
  • Sigma Aldrich:311-28-4(sigmaaldrich)
  • 四丁基碘化铵价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30174014 四正丁基碘化铵 25g 58元 2011/04/16 T0057 四丁基碘化铵 Tetrabutylammonium Iodide 25G 280元 2011/04/16 T0057 四丁基碘化铵 Tetrabutylammonium Iodide 500G 1900元
  • 存储注意事项:光敏感
  • 用途一:用作极谱分析试剂
  • 下游产品:N,N-二甲基乙二胺 --> S-甲基-S-苄基 亚磺酰亚胺 --> 3-(甲氧基甲基)苯硼酸 --> 苯并-15-冠醚-5 --> 4-哌嗪基苯甲腈

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Phase Transfer Catalysts 相转移催化剂
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Phase Transfer Catalysts 相转移催化剂
  4. Ammonium Salts - Phase Transfer Catalysts
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Amine Salts - Nitrogen Compounds
  1. Analytical & Chromatography 分析化学与色谱
  2. HPLC
  3. Buffers &amp; Reagents - HPLC
  4. Ion Pair Reagents 离子对试剂
  5. Ion Pair Reagents - Anionic - Ion Pair Reagents
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Chromatography Reagents &amp; Solvents - Analytical Reagents
  4. Ion Pair Reagents - Chromatography Reagents &amp; Solvents
  5. Acidic Ion Pair Reagents (Anionic) - Ion Pair Reagents
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Quaternary Ammonium Compounds 季铵化合物
  1. Analytical & Chromatography 分析化学与色谱
  2. Chromatography/CE Reagents
  3. Ion Pair
  1. Functional Group 官能团索引
  2. quaternary ammonium salt