4-Fluorophthalic Anhydride 4-氟邻苯二甲酸酐

CAS 319-03-9 MFCD00191363

化学结构图

319-03-9
SMILES: O=C1OC(=O)c2cc(F)ccc21

化学属性

Mol. FormulaC8H3FO3
Mol. Weight166.11
Melting Point74-79°C
Density1.5
TSCAYes
Boiling Point147-149 °C at 20 mmHg
Flash Point>93°C
Appearance 白色不定形粉末
Stability易吸潮

别名和识别编码

Chemical Name4-Fluorophthalic Anhydride
CAS Number319-03-9
Alfabeta NameFLUOROPHTHALICANHYDRIDE 4-
MDL NumberMFCD00191363
Synonym 4-Fluorophthalic anhydride {LY} 4-Fluorophthalic anhydride {} {LY} 4-Fluorophthalic anhydride {} {} {LY} 4-Fluorophthalic anhydride {} {} {} {LY} 4-Fluorophthalic anhydride {} {} {} {} {LY} 4-Fluorophthalic anhydride {} {} {} {} {} {LY} 4-Fluorophthalic anhydride {} {} {} {} {} {} {LY} 4-Fluorophthalic anhydride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Fluorophthalic anhydride {} {} {} {} {} {} {} {} {LY} 4-Fluorophthalic anhydride {} {} {} {} {} {} {} {} {} {LY} 4-Fluorophthalic anhydride {} {} {} {} {} {} {} {} {} {} {LY} 4-Fluorophthalic anhydride {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Fluorophthalic anhydride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Fluorophthalic anhydride {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Fluorophthalic anhydride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Fluorophthalic anhydride {} {} {} {} {}
Beilstein Registry Number17(5)11,259
PubChem Substance ID87570096
Reaxys-RN131281
Chemical Name Translation4-氟邻苯二甲酸酐
InChIKeyXVMKZAAFVWXIII-UHFFFAOYSA-N
LabNetwork Molecule IDLN00009498
InChIInChI=1S/C8H3FO3/c9-4-1-2-5-6(3-4)8(11)12-7(5)10/h1-3H
Canonical SMILESO=C1OC(C2=C1C=CC(F)=C2)=O
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分类

  • {SNA} Building Blocks, Carbonyl Compounds, Carboxylic Acid Anhydrides, Chemical Synthesis, Fluorinated Building Blocks, Heterocyclic Fluorinated Building Blocks, Organic Building Blocks, Other Fluorinated Heterocycles, Others
  • {uni_hamburg} no charge; oxygen heterocycle; carbocycle; aromatic; large ring; fused rings; 5ring; 6ring; 9ring; carbo-anhydride; 1fragment

相关文献及参考

  • Short: III/35B Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Fluorine-19 and Nitrogen-15 Author: Balasubramanian, M.; Gupta, R.R.; Jain, M.; Perumal, S. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35B Year: 1998 ISBN: 3-540-63275-1 ISBN: 978-3-540-63275-7 Internet Resource: DOI:10.1007/b55685 RefComment: VII, 242 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CO-ROM's.

安全信息

Warnings MOISTURE SENSITIVE, TOXIC
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
Storage condition -20°C {LY} -20°C Moisture Sensitive {} {LY} -20°C {} {} {LY} -20°C {} {} {} {LY} -20°C {} {} {} {} {LY} -20°C {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
WGK Germany2
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P332+P313
  • P301+P310
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P302+P350
  • P337+P313
  • P302+P352+P332+P313+P362+P364
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H301 Toxic if swallowed 吞食有毒
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H303 May be harmfully swallowed 吞食可能有害
Signal word
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Hazard Codes Xn Xn,Xi
UN Number UN 2811 6.1/PG 3
Packing GroupIII

其他信息

  • 图谱信息:4-氟邻苯二甲酸酐(319-03-9)红外图谱(IR1) 4-氟邻苯二甲酸酐(319-03-9)红外图谱(IR2) 4-氟邻苯二甲酸酐(319-03-9)核磁图( 13 CNMR) 4-氟邻苯二甲酸酐(319-03-9)质谱(MS) 4-氟邻苯二甲酸酐(319-03-9)核磁图( 1 HNMR)
  • MSDS 信息:5-Fluoro-1,3-isobenzofurandione(319-03-9).msds
  • 4-氟邻苯二甲酸酐价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 F0322 4-氟邻苯二甲酸酐 4-Fluorophthalic Anhydride 5G 865元 2010/06/21 330880050 4-氟邻苯二甲酸酐 4-Fluorophthalic anhydride 99% 5 GR 1095元 2010/06/21 330880250 4-氟邻苯二甲酸酐 4-Fluorophthalic anhydride 99% 25 GR 3511元
  • Sigma Aldrich:319-03-9(sigmaaldrich)
  • 敏感性:Moisture Sensitive
  • Acros Organics:4-氟邻苯二甲酸酐 4-Fluorophthalic anhydride, 99%(319-03-9)
  • Alfa Aesar:4-氟邻苯二甲酸酐,98% 4-Fluorophthalic anhydride, 98%(319-03-9)
  • Hazard Note:Irritant
  • MOL 文件:319-03-9.mol
  • TCI Shanghai:4-氟邻苯二甲酸酐 4-Fluorophthalic Anhydride,>;98.0%(GC)(319-03-9)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Carboxylic Acid Anhydrides 羧酸酐
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Carboxylic Acid Anhydrides 羧酸酐
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Carbonates
  1. Functional Group 官能团索引
  2. carboxylic acid anhydride