Thiocyanic acid, chloromethyl ester 硫氰酸氯甲酯

CAS 3268-79-9 MFCD00001831

化学结构图

3268-79-9
SMILES: N#CSCCl

化学属性

Mol. FormulaC2H2ClNS
Mol. Weight107.56
Density1.37 g/mL at 25 °C(lit.)
Refractive index1.5160 to 1.5180
Flash Point83°C(lit.)
TSCANo
Boiling Point186.227±13.00 °C at 760mmHg

别名和识别编码

Chemical NameThiocyanic Acid Chloromethyl Ester
Synonym Chloro(thiocyanato)methane {LY} Chloro(thiocyanato)methane {} {LY} Chloro(thiocyanato)methane {} {} {LY} Chloro(thiocyanato)methane {} {} {} {LY} Chloro(thiocyanato)methane {} {} {} {} {LY} Chloro(thiocyanato)methane {} {} {} {} {} {LY} Chloro(thiocyanato)methane {} {} {} {} {} {} {LY} Chloro(thiocyanato)methane {} {} {} {} {} {} {} {LY} Chloro(thiocyanato)methane {} {} {} {} {} {} {} {} {LY} Chloro(thiocyanato)methane {} {} {} {} {} {} {} {} {} {LY} Chloro(thiocyanato)methane {} {} {} {} {} {} {} {} {} {} {LY} Chloro(thiocyanato)methane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Chloro(thiocyanato)methane {} {} {} {} {} {} {} {} {} {} {} {} {LY} Chloro(thiocyanato)methane {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Chloro(thiocyanato)methane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Chloro(thiocyanato)methane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Chloro(thiocyanato)methane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
MDL NumberMFCD00001831
CAS Number3268-79-9
EC Number221-883-0
Beilstein Registry Number3(2)124
PubChem Substance ID76755
Reaxys-RN1098487
Chemical Name Translation硫氰酸氯甲酯
Wiswesser Line NotationNCS1G
InChIKeyUXUCVNXUWOLPRU-UHFFFAOYSA-N
LabNetwork Molecule IDLN00881711
InChIInChI=1S/C2H2ClNS/c3-1-5-2-4/h1H2
Canonical SMILESC(Cl)SC#N
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfur Compounds, Thiocyanates/Isothiocyanates
  • {uni_hamburg} no charge; 1fragment

相关文献及参考

  • Short: III/38B Title: Refractive Indices of Organic Liquids Author: Wohlfarth, Ch.; Wohlfarth, B. Editor: Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/38B Year: 1996 Keyword: organic compounds; refractive index; liquids ISBN: 3-540-60596-7 ISBN: 978-3-540-60596-6 Internet Resource: DOI:10.1007/b85533 RefComment: VII, 4210 pages, Hardcover Abstract: Volume III/38 Optical Constants provides critically evaluated data on refractive indices of inorganic and organic liquids and their wavelength dependence (dispension). Part A contains the inorganic, organometallic, and organononmetallic liquids, and the binary liquid mixtures (about 900 pure substances and their mixtures). Part B contains data of more than 7600 organic liquids.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

RTECSXK8800000
Packing GroupIII
UN Number UN2810 2810 UN 2810 6.1/PG 2
Risk Statements
  • R32 Contact with acids liberates very toxic gas 与酸接触释放出毒性很高的气体
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
Safety Statements
  • S13 Keep away from food, drink and animal foodstuffs 远离食品、饮料和动物饲料保存；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Storage condition Moisture Sensitive
GHS Symbol
WGK Germany3
Hazard statements
  • H227 Combustible liquid 可燃液体
  • H301 Toxic if swallowed 吞食有毒
  • H302 Harmful if swallowed 吞食有害
  • H302+H312+H332
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H312 Harmful in contact with skin 皮肤接触有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H330 Fatal if inhaled 吸入致命
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P310
  • P301+P310+P330
  • P301+P312
  • P301+P316
  • P301+P317
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P312
  • P304+P340
  • P304+P340+P311
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P316
  • P317
  • P319
  • P320 Specific treatment is urgent (see … on this label). 紧急具体治疗（见本标签上的）。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P361+P364
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Hazard Codes Xn
Hazard Class6.1 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 9572 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PCBPBS Pesticide Biochemistry and Physiology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802)  V.1-    1971-  Volume(issue)/page/year:
   2,95,1972

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 5600 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#03775

其他信息

  • TCI Shanghai:硫氰酸氯甲酯 Chloromethyl Thiocyanate,>;97.0%(GC)(3268-79-9)
  • Sigma Aldrich:3268-79-9(sigmaaldrich)
  • Alfa Aesar:硫氰酸氯甲酯,97% Chloromethyl thiocyanate, 97%(3268-79-9)
  • 硫氰酸氯甲酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1179 硫氰酸氯甲酯 Chloromethyl Thiocyanate 5G 252元 2014/06/02 T1179 硫氰酸氯甲酯 Chloromethyl Thiocyanate 25G 782元 2010/06/21 147470100 硫氰酸氯甲酯 Chloromethyl thiocyanate 97% 10 ML 393元
  • MOL 文件:3268-79-9.mol
  • 图谱信息:硫氰酸氯甲酯(3268-79-9)红外图谱(IR1) 硫氰酸氯甲酯(3268-79-9)质谱(MS)
  • 敏感性:Moisture Sensitive
  • Acros Organics:Chloromethyl thiocyanate, 97%(3268-79-9)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Thiocyanates/Isothiocyanates - Sulfur Compounds
  1. Functional Group 官能团索引
  2. thiocyanate

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