Methyl Dichlorophosphite 二氯亚磷酸甲酯

CAS 3279-26-3 MFCD00000524

化学结构图

3279-26-3
SMILES: COP(Cl)Cl

化学属性

Mol. FormulaCH3Cl2OP
Mol. Weight133
Refractive indexn20/D 1.474(lit.)
Boiling Point92°C
Density1.376 g/mL at 20 °C(lit.)
Melting Point-91 °C(lit.)
Flash Point40°C(lit.)
TSCANo

别名和识别编码

Chemical NameMethyl Dichlorophosphite
CAS Number3279-26-3
Synonym DICHLORO METHYL PHOSPHITE DICHLOROMETHOXY PHOSPHINE Dichloridophosphorous acid methyl ester Dichloromethoxyphosphine Dichlorphosphorigsäuremonomethylester METHYL DICHLOROPHOSPHITE METHYL DICHLOROPHOSPHITE, TECHNICAL GRADE METHYL PHOSPHORODICHLORIDITE Methoxydichlorophosphine Methoxyphosphonous Dichloride Methyl Dichlorophosphite Methyl Dichlorophosphite [Phosphitylating Agent] Methyl Phosphorodichloridite Methyl dichloridophosphite Methyl dichlorophosphite Methyl-dichlorphosphit Methyl-phosphordichloridit Methyldichlorphosphit O-Methyl Phosphorodichloridit O-Methyl Phosphorodichloridite Phosphorigsäure-monomethylester-dichlorid Phosphorodichloridous acid methyl ester Phosphorodichloridous acid,
MDL NumberMFCD00000524
PubChem Substance ID76768
EC Number221-915-3
Beilstein Registry Number1697452
Reaxys-RN1697452
Chemical Name Translation二氯亚磷酸甲酯
InChIKeyHCSDJECSMANTCX-UHFFFAOYSA-N
LabNetwork Molecule IDLN01269835
InChIInChI=1S/CH3Cl2OP/c1-4-5(2)3/h1H3
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • Aliphatics
  • Phosphorylating and Phosphitylating Agents
  • {uni_hamburg} no charge; 1fragment
  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Phosphorus Compounds, Phosphorus Halides

相关文献及参考

  • Short: III/20a
  • Short: II/25B
  • Key reagent for the phosphite coupling method of oligonucleotide synthesis: Tetrahedron Lett., 1859 (1981).
  • Short: III/38A

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P302+P361+P354
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P316
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Packing GroupII
UN Number 2920 UN 2920 8/PG 2 UN2920
Risk Statements
  • R10 Flammable 易燃
  • R37 Irritating to respiratory system 刺激呼吸道
  • R14 Reacts violently with water 遇水会猛烈反应
  • R34 Causes burns 会导致灼伤
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Storage condition -20°C 0-10 0-10°C Moisture Sensitive
Hazard Codes C
Hazard Class8/3

其他信息

  • 图谱信息:二氯亚磷酸甲酯(3279-26-3)红外图谱(IR1) 二氯亚磷酸甲酯(3279-26-3)质谱(MS)
  • Alfa Aesar:偶磷二氯甲酯,98% Methyl phosphorodichloridite, 98%(3279-26-3)
  • MOL 文件:3279-26-3.mol
  • F:10-13-23
  • Sigma Aldrich:3279-26-3(sigmaaldrich)
  • 二氯亚磷酸甲酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M0905 二氯亚磷酸甲酯[亚磷酸化剂] Methyl Dichlorophosphite [Phosphitylating Agent] 10G 698元 2010/06/21 216080050 二氯亚磷酸甲酯 Methyl dichlorophosphite 98% 5 ML 678元 2010/06/21 216080250 二氯亚磷酸甲酯 Methyl dichlorophosphite 98% 25 ML 2899元
  • Acros Organics:Methyl dichlorophosphite, 98%(3279-26-3)
  • 敏感性:Moisture Sensitive
  • TCI Shanghai:二氯亚磷酸甲酯[亚磷酸化剂] Methyl Dichlorophosphite [Phosphitylating Agent],>;95.0%(T)(3279-26-3)

系列性分类

  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Nucleosides, Nucleotides, Oligonucleotides - Biochemicals and Reagents
  4. Nucleoside Analogs - Nucleosides, Nucleotides, Oligonucleotides
  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Nucleosides, Nucleotides, Oligonucleotides - Biochemicals and Reagents
  4. Nucleosides - Nucleosides, Nucleotides, Oligonucleotides
  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Nucleosides, Nucleotides, Oligonucleotides - Biochemicals and Reagents
  4. Nucleotide Analogs - Nucleosides, Nucleotides, Oligonucleotides
  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Nucleosides, Nucleotides, Oligonucleotides - Biochemicals and Reagents
  4. Nucleotides - Nucleosides, Nucleotides, Oligonucleotides
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  5. Phosphorus Halides - Phosphorus Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  5. Phosphorus Halides - Phosphorus Compounds
  1. Life Science 生命科学
  2. Biochemistry / Glyco-Chemistry
  3. DNA / RNA Synthesis

相关产品推荐