Methyl Phenylsulfonylacetate 苯磺酰乙酸甲酯

CAS 34097-60-4 MFCD00007555

化学结构图

34097-60-4
SMILES: COC(=O)CS(=O)(=O)C1C=CC=CC=1

化学属性

Mol. FormulaC9H10O4S
Mol. Weight214
Boiling Point165
Density1.305
Refractive index1.5310 to 1.5340
Flash Point78°C(lit.)
TSCANo
Melting Pointca 30°

别名和识别编码

Chemical NameMethyl Phenylsulfonylacetate
CAS Number34097-60-4
Alfabeta NameMETHYLPHENYLSULFONYLACETATE ALPHA()-
MDL NumberMFCD00007555
Synonym Phenylsulphonylacetic acid methyl ester 苯磺酰基乙酸甲酯 Methyl phenylsulphonylacetate Benzenesulfonyl-acetic acid methyl ester methyl (phenylsulfonyl)acetate Methyl benzenesulfonylacetate
PubChem Substance ID87575439
Beilstein Registry Number2051463
Reaxys-RN2051463
Chemical Name Translation苯磺酰乙酸甲酯
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; ester; sulfone; 1fragment
  • {SNA} Bioactive Small Molecules, Building Blocks, Cell Biology, Chemical Synthesis, M, Organic Building Blocks, Sulfones, Sulfur Compounds
  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfones, Sulfur Compounds

相关文献及参考

  • Active methylene compound used by Trost in Pd-catalyzed additions to allylic systems, providing, after desulfonation, methoxycarbonylmethyl derivatives under neutral conditions; see, e.g.: J. Am. Chem. Soc., 100, 3435 (1978); 103, 5969 (1981):
  • See also: Tetrahedron Lett., 33, 1831 (1992). Desulfonation has been effected with Na amalgam: Tetrahedron Lett., 3477 (1976), Ca in liquid ammonia: J. Am. Chem. Soc., 100, 3435 (1978); or Mg in methanol: J. Org. Chem., 50, 1749 (1985).
  • Short: III/35C1

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter Eyeshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US)
Signal word
Hazard statements
  • H227 Combustible liquid 可燃液体
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P370+P378
  • P403+P235
GHS Symbol
Safety Statements
Risk Statements

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfones - Sulfur Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Sulfones - Sulfur Compounds

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