2-Fluoro-5-(TRIFluoroMETHYL)Phenylboronic Acid 2-氟-5-三氟甲基苯硼酸

CAS 352535-96-7 MFCD03701538

化学结构图

352535-96-7
SMILES: OB(O)C1=CC(=CC=C1F)C(F)(F)F

化学属性

Mol. FormulaC7H5BF4O2
Mol. Weight207.92
Melting Point104-109
TSCANo

别名和识别编码

Chemical Name2-Fluoro-5-(TRIFluoroMETHYL)Phenylboronic Acid
CAS Number352535-96-7
Alfabeta NameFLUOROTRIFLUOROMETHYLPHENYLBORONICACID 25()---
MDL NumberMFCD03701538
Synonym 2-Fluoro-5-(trifluoromethyl)phenylboronic acid 2-氟-5-(三氟甲基)苯硼酸
PubChem Substance ID125307918
Reaxys-RN11224038
Chemical Name Translation2-氟-5-三氟甲基苯硼酸
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分类

  • Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Disubstituted Aryl Boronic Acids, Organometallic Reagents
  • {SNA} Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Disubstituted Aryl Boronic Acids, Organometallic Reagents

相关文献及参考

  • 1. Durka, K.; et al., Functionalization of Dihalophenylboronic Acids by Deprotonation of Their N-Butyldiethanolamine Esters Eur. J. Org. Chem. , 4325-4332, (2009)
  • 2. Zigterman, J. L.; et al., Highly Selective Rhodium-Catalyzed Conjugate Addition Reactions of 4-Oxobutenamides J. Org. Chem. 72 , 8870-8876, (2007)
  • 3. Roecker, A. J.; et al., Kinesin spindle protein (KSP) inhibitors. Part 8: Design and synthesis of 1,4-diaryl-4,5-dihydropyrazoles as potent inhibitors of the mitotic kinesin KSP Bioorg. Med. Chem. Lett. 17 , 5677-5682, (2007)
  • Tsoung, J.; et al., Diastereoselective Friedel-Crafts alkylation of hydronaphthalenes J. Org. Chem. 76 , 9031-9045, (2011)

安全信息

Warnings IRRITANT, KEEP COLD
WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Signal word
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P332+P313
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
  • P305+P351+P338+P337+P313
Safety Statements
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
GHS Symbol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  5. Aryl Boronic Acids - Boronic Acids
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  5. Aryl Boronic Acids - Boronic Acids
  6. Disubstituted Aryl Boronic Acids - Aryl Boronic Acids

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