Vinylmagnesium chloride 乙烯基氯化镁

CAS 3536-96-7 MFCD00013594

化学结构图

3536-96-7
SMILES: [CH-]=C.[Cl-].[Mg+2]

化学属性

Mol. FormulaC2H3ClMg
Mol. Weight86.80
Density0.98
Flash Point-17 ºC
Boiling Point66°C
Solubility剧烈反应
Appearance 淡黄色透明液体， 密度 （ 20°C ） d= 四氢呋喃溶液 0.97 g /ml ， 沸点 66 °C ， 凝点 ; - 17 °C 。
Stability对湿度敏感
Danger-Level-
pH-:-
Redox-

别名和识别编码

Chemical NameVinylmagnesium Chloride
Synonym Vinyl magnesium chloride,2.0M solution in THF,Safeseal {LY} Vinyl magnesium chloride,2.0M solution in THF,Safeseal Vinyl-magnesium chloride Vinylchloromagnesium Vinylmagnesium Vinylmagnesium chloride Vinylmagnesium chloride solution Vinylmagnesium chloride, 15 WT% solution in tetrahydrofuran, acroseal(TM) Vinylmagnesium chloride, 15 wt% solution in tetrahydrofuran Vinylmagnesium chloride15 wt% solution in tetrahydrofuranAcroSeal§3 {} {LY} Vinyl magnesium chloride,2.0M solution in THF,Safeseal {} {} {LY} Vinyl magnesium chloride,2.0M solution in THF,Safeseal {} {} {} {LY} Vinyl magnesium chloride,2.0M solution in THF,Safeseal {} {} {} {} {LY} Vinyl magnesium chloride,2.0M solution in THF,Safeseal {} {} {} {} {} {LY} Vinyl magnesium chloride,2.0M solution in THF,Safeseal {} {} {} {} {} {} { {} {} {} {} {} {} {LY} Vinyl magnesium chloride,2.0M soluti
MDL NumberMFCD00013594
CAS Number3536-96-7
PubChem Substance ID77075
Beilstein Registry Number3535268
EC Number222-575-9
Chemical Name Translation乙烯基氯化镁
InChIKeyNAFZXKWEUWVSAW-UHFFFAOYSA-M
LabNetwork Molecule IDLN00226441
InChIInChI=1S/C2H3.ClH.Mg/c1-2;;/h1H,2H2;1H;/q-1;;+2/p-1
Canonical SMILESC=C[Mg]Cl
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分类

  • {uni_hamburg} no charge; metal-organic; 1fragment
  • {SNA} Alkenyl, Chemical Synthesis, Grignard Reagents, Organometallic Reagents

产品应用

  • 与戊二烯酸酯铁络合物共同用于合成二乙烯基环丙烷。

相关文献及参考

  • Short: III/35C4 Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Hydrogen-1, Part 4: Inorganic and Organometallic Compounds Author: Gupta, R.R.; Platzer, N. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35C4 Year: 2001 Keyword: Hydrogen 1; Nuclear Magnetic Resonance ISBN: 3-540-41059-7 ISBN: 978-3-540-41059-1 Internet Resource: DOI:10.1007/b76570 RefComment: VII, 299 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CD-ROM's.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

GHS Symbol
WGK Germany1
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体，可自燃。
  • H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H351 Suspected of causing cancer 怀疑致癌
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能，因为会剧烈反应可能产生闪火。
  • P231+P232
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P302+P335+P334
  • P302+P361+P354
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P316
  • P317
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P335+P334
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P402+P404
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P422 Store contents under… 存储目录在…之下。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
Hazard Codes F,C
Safety Statements
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
  • S7/8 Keep container tightly closed and dry 保存在严格密闭容器中，保持干燥；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S30 Never add water to this product 切勿将水加入该产品中；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
Packing GroupI
UN Number
Storage condition -20°C, stored under nitrogen {LY} -20°C, stored under nitrogen {} {LY} -20°C, stored under nitrogen {} {} {LY} -20°C, stored under nitrogen {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Restrict -

其他信息

  • 图谱信息:乙烯基氯化镁(3536-96-7)核磁图( 1 HNMR)
  • Sigma Aldrich:3536-96-7(sigmaaldrich)
  • MOL 文件:3536-96-7.mol
  • 乙烯基氯化镁价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 252598000 乙烯基氯化镁 Vinylmagnesium chloride , 15 wt% solution in THF, AcroSeal® 800 ML 2168元 2010/06/21 252591000 乙烯基氯化镁 Vinylmagnesium chloride , 15 wt% solution in THF, AcroSeal® 100 ML 507元
  • 用途一:是有机合成中常用的一种格利雅试剂。
  • F:1-3-10
  • Acros Organics:乙烯基氯化镁 Vinylmagnesium chloride, 15 wt% solution in tetrahydrofuran, AcroSeal?(3536-96-7)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  4. Alkenyl Grignard Reagents 烯烃格氏试剂
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  4. Alkenyl Grignard Reagents 烯烃格氏试剂
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Grignard Reagents 格氏试剂
  1. Functional Group 官能团索引
  2. organomagnesium compound

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