Cyclopenta-2,4-dien-1-yltrimethylsilane 环戊二烯基-5-三甲基硅烷

CAS 3559-74-8 MFCD00010666

化学结构图

3559-74-8
SMILES: C[Si](C)(C)C1C=CC=C1

化学属性

Mol. FormulaC8H14Si
Mol. Weight138.28
Density0.833 g/mL at 25 °C(lit.)
Flash Point29°(84°F)
TSCANo
Boiling Point138-140 °C(lit.)
Refractive indexn20/D 1.471(lit.)
Melting Point-19 °C
Appearance colorless liq.
Stabilitymoisture sensitive, store cold

别名和识别编码

Chemical NameCyclopenta-2,4-dien-1-yltrimethylsilane
MDL NumberMFCD00010666
CAS Number3559-74-8
Synonym Cyclopenta-2,4-dien-1-yltrimethylsilane {LY} Cyclopenta-2,4-dien-1-yltrimethylsilane {} {LY} Cyclopenta-2,4-dien-1-yltrimethylsilane {} {} {LY} Cyclopenta-2,4-dien-1-yltrimethylsilane {} {} {} {LY} Cyclopenta-2,4-dien-1-yltrimethylsilane {} {} {} {} {LY} Cyclopenta-2,4-dien-1-yltrimethylsilane {} {} {} {} {} {LY} Cyclopenta-2,4-dien-1-yltrimethylsilane {} {} {} {} {} {} {LY} Cyclopenta-2,4-dien-1-yltrimethylsilane {} {} {} {} {} {} {} {LY} Cyclopenta-2,4-dien-1-yltrimethylsilane {} {} {} {} {} {} {} {} {LY} Cyclopenta-2,4-dien-1-yltrimethylsilane {} {} {} {} {} {} {} {} {} {LY} Cyclopenta-2,4-dien-1-yltrimethylsilane {} {} {} {} {} {} {} {} {} {} {LY} Cyclopenta-2,4-dien-1-yltrimethylsilane {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclopenta-2,4-dien-1-yltrimethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclopenta-2,4-dien-1-yltrimethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclopenta-2,4-dien-1-yltrimethylsilane {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID91288
Reaxys-RN1924523
Beilstein Registry Number16(4)1360
Chemical Name Translation环戊二烯基-5-三甲基硅烷
InChIKeyVMFHCJPMKUTMMQ-UHFFFAOYSA-N
LabNetwork Molecule IDLN01744274
InChIInChI=1S/C8H14Si/c1-9(2,3)8-6-4-5-7-8/h4-8H,1-3H3
Canonical SMILESC[Si](C)(C)C1C=CC=C1
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分类

  • {SNA} Alkenes, Building Blocks, Chemical Synthesis, Cyclic, Organic Building Blocks

安全信息

Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
Packing GroupIII
UN Number 1993 UN 1993 3/PG 3 UN1993
Risk Statements
  • R10 Flammable 易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition -20°C 0-10 0-10°C Moisture Sensitive
WGK Germany3
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Signal word Warning
GHS Symbol
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes Xi
Hazard Class3

其他信息

  • MOL 文件:3559-74-8.mol
  • 环戊二炔三甲基硅烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T2284 5-(三甲基硅基)-1,3-环戊二烯 5-(Trimethylsilyl)-1,3-cyclopentadiene 5G 1350元 2014/06/02 T2284 5-(三甲基硅基)-1,3-环戊二烯 5-(Trimethylsilyl)-1,3-cyclopentadiene 1G 452元 2010/06/21 387160050 环戊二炔三甲基硅烷 Cyclopentadienyltrimethylsilane 5 GR 1821元
  • Alfa Aesar:三甲硅烷基环戊二烯,97%(异构体的混合物) Trimethylsilylcyclopentadiene, mixture of isomers, tech. 90%(3559-74-8)
  • Sigma Aldrich:3559-74-8(sigmaaldrich)
  • Acros Organics:1-(Trimethylsilyl)cyclopentadiene(3559-74-8)
  • F:10
  • TCI Shanghai:5-(三甲基硅基)-1,3-环戊二烯 5-(Trimethylsilyl)-1,3-cyclopentadiene,>;97.0%(GC)(3559-74-8)
  • 敏感性:Moisture Sensitive

系列性分类

  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Organosilicon 有机硅
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Alkenes 烯烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Alkenes 烯烃
  5. Cyclic - Alkenes
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Silicon Compounds for Organic Synthesis 硅化合物
  1. Ligands
  2. Silicon
  1. Metallocenes, Derivatives & Cp Precursors
  2. Silicon

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