2-(trifluoromethyl)pyridine 2-三氟甲基吡啶

CAS 368-48-9 MFCD02183562

化学结构图

368-48-9
SMILES: FC(F)(F)c1ccccn1

化学属性

Mol. FormulaC6H4F3N
Mol. Weight147.10
Boiling Point115.3°C at 760 mmHg
Density1.275 g/mL at 25 °C
Refractive index1.4170 to 1.4210
Flash Point42°C
TSCANo
Appearance 无色透明液体。

别名和识别编码

Chemical Name2-(trifluoromethyl)pyridine
CAS Number368-48-9
Alfabeta NameTRIFLUOROMETHYLPYRIDINE 2()-
MDL NumberMFCD02183562
Synonym 2-(Trifluoromethyl)pyridine {LY} 2-(Trifluoromethyl)pyridine {} {LY} 2-(Trifluoromethyl)pyridine {} {} {LY} 2-(Trifluoromethyl)pyridine {} {} {} {LY} 2-(Trifluoromethyl)pyridine {} {} {} {} {LY} 2-(Trifluoromethyl)pyridine {} {} {} {} {} {LY} 2-(Trifluoromethyl)pyridine {} {} {} {} {} {} {LY} 2-(Trifluoromethyl)pyridine {} {} {} {} {} {} {} {LY} 2-(Trifluoromethyl)pyridine {} {} {} {} {} {} {} {} {LY} 2-(Trifluoromethyl)pyridine {} {} {} {} {} {} {} {} {} {LY} 2-(Trifluoromethyl)pyridine {} {} {} {} {} {} {} {} {} {} {LY} 2-(Trifluoromethyl)pyridine {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Trifluoromethyl)pyridine {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Trifluoromethyl)pyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Trifluoromethyl)pyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Trifluoromethyl)pyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Trifluoromethyl)pyridine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Trif
PubChem Substance ID354334129
EC Number000-000-0
Beilstein Registry Number20(5)5,497
Chemical Name Translation2-三氟甲基吡啶
InChIKeyATRQECRSCHYSNP-UHFFFAOYSA-N
LabNetwork Molecule IDLN00009673
Reaxys-RN3112
InChIInChI=1S/C6H4F3N/c7-6(8,9)5-3-1-2-4-10-5/h1-4H
Canonical SMILESFC(C1=NC=CC=C1)(F)F
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分类

  • {SNA} Building Blocks, C6, Chemical Synthesis, Heterocyclic Building Blocks, Pyridines

相关文献及参考

  • Lithiation with n-BuLi/LiOCH2CH2NMe2 takes place at the 6-position, affording access to 6-substituted derivatives. With LiTMP (see 2,2,6,6-Tetramethyl­piperidine, A18712), 3-lithiation occurs: Eur. J. Org. Chem., 1569 (2003).

安全信息

Warnings IRRITANT, FLAMMABLE
WGK Germany3
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P403+P235
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Signal word Warning
GHS Symbol
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Packing GroupIII
UN Number 1993 UN 1993 3/PG 3 UN1993
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R10 Flammable 易燃
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S37 Wear suitable gloves 戴适当手套；
Hazard Codes Xi,F Xi
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Class3

其他信息

  • 下游产品:
  • Hazard Note:Flammable/Irritant
  • 检测方法:GC
  • Sigma Aldrich:368-48-9(sigmaaldrich)
  • MOL 文件:368-48-9.mol
  • Alfa Aesar:2-(三氟甲基)吡啶,99% 2-(Trifluoromethyl)pyridine, 99%(368-48-9)
  • 存储注意事项:热敏感;氮气保护
  • 2-三氟甲基吡啶价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/05/25 L19554 2-(三氟甲基)吡啶, 99% 2-(Trifluoromethyl)pyridine, 99% 250mg 420元 2010/05/25 L19554 2-(三氟甲基)吡啶, 99% 2-(Trifluoromethyl)pyridine, 99% 1g 1166元
  • MSDS 信息:2-(Trifluoromethyl)pyridine(368-48-9).msds

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Fluorinated Building Blocks 氟化物砌块
  4. Organic Fluorinated Building Blocks - Fluorinated Building Blocks
  5. Trifluoromethyl 三氟甲基
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. C6 - Pyridines
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Pyridines 吡啶

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