3-(Trifluoromethyl)Phenylhydrazine 3-三氟甲基苯肼

CAS 368-78-5 MFCD00025093

化学结构图

368-78-5
SMILES: NNc1cccc(C(F)(F)F)c1

化学属性

Mol. FormulaC7H7F3N2
Mol. Weight176.14
Boiling Point204.6 °C at 760 mmHg
Refractive index1.5040 to 1.5080
Density1.348 g/mL at 25 °C(lit.)
Flash Point107°(224°F)
TSCANo

别名和识别编码

Chemical Name3-(Trifluoromethyl)Phenylhydrazine
CAS Number368-78-5
Alfabeta NameTRIFLUOROMETHYLPHENYLHYDRAZINE 3()-
MDL NumberMFCD00025093
PubChem Substance ID98650
EC Number206-713-5
Reaxys-RN640075
Beilstein Registry Number15(4)1224
Synonym 3-(Trifluoromethyl)phenylhydrazine {LY} 3-(Trifluoromethyl)phenylhydrazine {} {LY} 3-(Trifluoromethyl)phenylhydrazine {} {} {LY} 3-(Trifluoromethyl)phenylhydrazine {} {} {} {LY} 3-(Trifluoromethyl)phenylhydrazine {} {} {} {} {LY} 3-(Trifluoromethyl)phenylhydrazine {} {} {} {} {} {LY} 3-(Trifluoromethyl)phenylhydrazine {} {} {} {} {} {} {LY} 3-(Trifluoromethyl)phenylhydrazine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-(Trifluoromethyl)phenylhydrazine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-(Trifluoromethyl)phenylhydrazine {} {} {} {} {} {} {} {} {} {LY} 3-(Trifluoromethyl)phenylhydrazine {} {} {} {} {} {} {} {} {} {} {LY} 3-(Trifluoromethyl)phenylhydrazine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-(Trifluoromethyl)phenylhydrazine {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-(Trifluoromethyl)phenylhydrazine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-(Trifluoromethyl)phenylhydrazine {} {} {} {} {} {} {} {} {} {}
Chemical Name Translation3-三氟甲基苯肼
InChIKeyRSESUCWJKLHXEZ-UHFFFAOYSA-N
LabNetwork Molecule IDLN00116911
InChIInChI=1S/C7H7F3N2/c8-7(9,10)5-2-1-3-6(4-5)12-11/h1-4,12H,11H2
Canonical SMILESFC(F)(F)C1=CC(NN)=CC=C1
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分类

  • Building Blocks, Chemical Synthesis, Hydrazines, Nitrogen Compounds, Organic Building Blocks
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SA} Building Blocks, Chemical Synthesis, Hydrazines, Nitrogen Compounds, Organic Building Blocks

相关文献及参考

  • Beil. 15 ,IV,1224
  • FT-IR 2 (2), 2133:D / FT-NMR 1 (2), 556:A / RegBook 1 (1), 1455:D / Structure Index 1 , 227:C:3
  • Short: III/35B Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Fluorine-19 and Nitrogen-15 Author: Balasubramanian, M.; Gupta, R.R.; Jain, M.; Perumal, S. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35B Year: 1998 ISBN: 3-540-63275-1 ISBN: 978-3-540-63275-7 Internet Resource: DOI:10.1007/b55685 RefComment: VII, 242 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CO-ROM's.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

Warnings IRRITANT, IRRITANT-HARMFUL
GHS Symbol
WGK Germany3
Hazard Codes Xn Xn,Xi
Hazard statements
  • H332 Harmful if inhaled 吸入有害
  • H315 Causes skin irritation 会刺激皮肤
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H302+H312+H332
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P332+P313
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P301+P312+P330
  • P302+P350
  • P337+P313
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P302+P352+P312+P362+P364
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
Signal word Warning
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
Safety Statements
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
Storage condition -20°C, stored under nitrogen {LY} -20°C, stored under nitrogen 0-10 0-10°C 2-8°C {} {LY} -20°C, stored under nitrogen {} {} {LY} -20°C, stored under nitrogen {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen
UN Number 2810

其他信息

  • TCI Shanghai:3-三氟甲基苯肼 3-(Trifluoromethyl)phenylhydrazine,>;97.0%(GC)(T)(368-78-5)
  • Alfa Aesar:3-(三氟甲基)苯肼,95% 3-(Trifluoromethyl)phenylhydrazine, 95%(368-78-5)
  • Acros Organics:3-(Trifluoromethyl)phenylhydrazine, 97%(368-78-5)
  • MOL 文件:368-78-5.mol
  • Sigma Aldrich:368-78-5(sigmaaldrich)
  • 3-三氟甲基苯肼价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T2411 3-(三氟甲基)苯肼 3-(Trifluoromethyl)phenylhydrazine 1G 410元 2010/06/21 333100050 3-三氟甲基苯肼 3-(Trifluoromethyl)phenylhydrazine 90%, tech., 5 GR 1847元 2010/06/21 333100010 3-三氟甲基苯肼 3-(Trifluoromethyl)phenylhydrazine 90%, tech., 1 GR 467元
  • Hazard Note:Irritant

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Hydrazines - Nitrogen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Hydrazines - Nitrogen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Guanidines

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