6,6'-Dimethyl-[1,1'-biphenyl]-2,2'-diamine (S)-(-)-6,6'-二甲基-2,2'-联苯二胺

CAS 3685-05-0 MFCD00114959

化学结构图

3685-05-0
SMILES: Cc1cccc(N)c1-c1c(C)cccc1N

化学属性

Mol. FormulaC14H16N2
Mol. Weight212.29
Melting Point156-160
Density1.106

别名和识别编码

Chemical Name(1S)-6,6'-Dimethyl[1,1'-biphenyl]-2,2'-diamine
Synonym (S)-2,2′-二氨基-6,6′-二甲基联苯 (S)-6,6′-二甲基-2,2′-二氨基联苯 (S)-6,6′-二甲基-1,1′-联苯-2,2′-二基二胺 (S)-6,6′-二甲基-1,1′-联苯-2,2′-二胺 (R)-2,2′-二氨基-6,6′-二甲基联苯 (R)-6,6′-二甲基-2,2′-二氨基联苯 (R)-6,6′-二甲基-1,1′-联苯-2,2′-二基二胺 (R)-6,6′-二甲基-1,1′-联苯-2,2′-二胺 2,2'-Diamino-6,6'-dimethylbiphenyl; 2,2'-Dimethyl-6,6'-diaminobiphenyl; 6,6'-Diamino-2,2'-dimethylbiphenyl; 6,6'-Dimethyl-1,1'-biphenyl-2,2'-diamine; 6,6'-Dimethyl-2,2'-biphenyldiamine; 6,6'-Dimethyl-2,2'-diaminobiphenyl (S)-(-)-6,6′-二甲基-2,2′-联苯二胺 (S)-2,2′-Diamino-6,6′-dimethylbiphenyl 6,6'-Diamino-2,2'-ditolyl
MDL NumberMFCD00114959
CAS Number20261-65-8
Beilstein Registry Number5741777
Chemical Name Translation(S)-(-)-6,6'-二甲基-2,2'-联苯二胺
PubChem Substance ID882241
InChIInChI=1S/C14H16N2/c1-9-5-3-7-11(15)13(9)14-10(2)6-4-8-12(14)16/h3-8H,15-16H2,1-2H3
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分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Other Chiral Ligands
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment

相关文献及参考

  • Short: IV/1a Title: Densities of Liquid Systems: Nonaqueous Systems and Ternary Aqueous Systems Author: Lacmann, R.; Synowietz, C. Editor: Schäfer, Kl. Source: Landolt-Börnstein, New Series Volume: IV/1a Year: 1974 ISBN: 3-540-06269-6 ISBN: 978-3-540-06269-1 Internet Resource: DOI:10.1007/b20003 RefComment: X, 716 pages. Hardcover Abstract: Volume IV/1 contains information on the densities of liquid systems. It may be considered as a supplement to volume II/1 of the 6th Edition, which contains only a few data on nonaqueous systems. Data are not listed for all systems but primarily for those of greater interest where data for a larger range of concentrations were available.

安全信息

GHS Symbol
WGK Germany3
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P317
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
Signal word
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R50 Very toxic to aquatic organisms 对水生生物极毒
  • R22 Harmful if swallowed 吞咽有害
Safety Statements
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Packing GroupIII
UN Number

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Other Chiral Ligands - Chiral Catalysts, Ligands, and Reagents

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