Bis(Dimethylamino)Dimethylsilane 双(二甲氨基)二甲基硅烷

CAS 3768-58-9 MFCD00008296

化学结构图

3768-58-9
SMILES: CN(C)[Si](C)(C)N(C)C

化学属性

Mol. FormulaC6H18N2Si
Mol. Weight146.31
Refractive index1.4170 to 1.4190
Vapor Density>;1 (vs air)
Boiling Point128°C(lit.)
Vapor Pressure1 mmHg ( 20 °C)
Density0.809
Melting Point98
Flash Point-7°C(lit.)
TSCAYes
Stabilitymoisture sensitive
Appearance colorless liq.

别名和识别编码

Chemical NameBis(Dimethylamino)Dimethylsilane
Synonym 双(二甲氨基)二甲基硅烷 六甲基硅二胺 BIS(DIMETHYLAMINO)DIMETHYSILANE Dimethylbis[dimethylamino]silane Bis-(dimethylamino)-dimethylsilan Silanediamine,hexamethyl- 双(二甲基氨基)二甲基硅烷; 六甲基硅二胺 N,N,N',N'-Tetramethyldimethylsilanediamine bis(dimethylamino)dimethyl-silane hexamethyl-Silanediamine Dimethylsilylenebis(dimethylamine) N,N,N',N',α,α-Hexamethylsilanediamine 双(二甲基氨基)二甲基硅烷 bis-(n,n-diethylamino)-dimethylsilane bis(dimethylamino)dimethylsilane BIS(DIMETHYLAMINO)DIMETHYLSILANE 96% Bis(N,N-dimethylamino)dimethylsilane 双(二甲基氨)二甲基硅烷 Silanediamine, hexamethyl- BIS(DIMETHYLAMINO)DIMETHYLSILANE hexamethyl-silanediamin bis-dimethylamino-dimethyl-silane
MDL NumberMFCD00008296
CAS Number3768-58-9
PubChem Substance ID77384
EC Number223-200-1
Beilstein Registry Number4(4)4113
Chemical Name Translation双(二甲氨基)二甲基硅烷
Reaxys-RN1736095
InChIKeyQULMGWCCKILBTO-UHFFFAOYSA-N
LabNetwork Molecule IDLN01740677
InChIInChI=1S/C6H18N2Si/c1-7(2)9(5,6)8(3)4/h1-6H3
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分类

  • {SNA} Derivatization Reagents, Derivatization Reagents GC, Reagents for Silylation, Silylation Reagents, 分析/色谱, 分析试剂
  • {SNA} Analytical Reagents, Analytical/Chromatography, Derivatization Reagents, Derivatization Reagents GC, Reagents for Silylation, Silylation Reagents
  • {SNA} Chemical Synthesis, Organometallic Reagents, Organosilicon, Others
  • {uni_hamburg} no charge; 1fragment
  • {SA} Analytical Reagents, Analytical/Chromatography, Derivatization Reagents, Derivatization Reagents GC, Reagents for Silylation, Silylation Reagents
  • {SNA} Chemical Synthesis, Organometallic Reagents, Organosilicon, Other Organosilicon

相关文献及参考

  • Short: III/20a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cl Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20a Year: 1988 Keyword: NQR ISBN: 3-540-18161-X ISBN: 978-3-540-18161-3 Internet Resource: DOI:10.1007/b31153 RefComment: IX,677 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
  • Short: III/35F Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Silicon-29 Author: Marsmann, H.C.; Uhlig, F.; Gupta, R.R.; Lechner, M.D.; Mikhova, B.M. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35F Year: 2008 Keyword: NMR; Si-29; chemical shifts; coupling constants; nuclear magnetic resonance; silicon-29 ISBN: 978-3-540-45277-5 (print) ISBN: 978-3-540-45278-2 (electronic) Internet Resource: DOI: 10.1007/978-3-540-45278-2 RefComment: X, 463 p. 40 illus., Hardcover RefComment: Written for: Scientists and engineers in the fields of physics, chemistry, and physical chemistry who intend to use NMR to study the structure and the binding of molecules Abstract: Nuclear Magnetic Resonance (NMR) is based on the fact that certain nuclei exhibit a magnetic moment, oriented by a magnetic field, and absorb characteristic frequencies in the radiofrequency part of the spectrum. The spectral lines of the nuclei are highly influenced by the chemical environment, i.e. the structure and interaction of the molecules. NMR is now the leading technique and a powerful tool for the investigation of the structure
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安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P303+P361+P353+P310+P363
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P370+P378
  • P405 Store locked up. 上锁保管。
  • P303+P361+P353
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P304+P340+P310
  • P301+P330+P331+P310
  • P305+P351+P338+P310
  • P241+P242+P243
  • P403+P235
Signal word
Packing GroupII
UN Number UN2924 2924
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R11 Highly flammable 非常易燃
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
Storage condition Moisture Sensitive Flammables area
Hazard Codes F,C
Hazard Class3/8

其他信息

  • 蒸气压:1 mm Hg ( 20 °C)
  • 图谱信息:双(二甲基氨基)二甲基硅烷(3768-58-9)红外图谱(IR1) 双(二甲基氨基)二甲基硅烷(3768-58-9)质谱(MS)
  • 蒸气密度:>;1 (vs air)
  • F:10-21
  • MOL 文件:3768-58-9.mol
  • Sigma Aldrich:3768-58-9(sigmaaldrich)
  • Alfa Aesar:双(二甲基氨)二甲基硅烷,97% Bis(dimethylamino)dimethylsilane, 97%(3768-58-9)
  • 双(二甲基氨基)二甲基硅烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B2150 双(二甲氨基)二甲基硅烷 Bis(dimethylamino)dimethylsilane 25ML 539元 2014/06/02 B2150 双(二甲氨基)二甲基硅烷 Bis(dimethylamino)dimethylsilane 250ML 2780元 2010/05/25 B21119 双(二甲基氨)二甲基硅烷, 97% Bis(dimethylamino)dimethylsilane, 97% 25g 519元
  • TCI Shanghai:双(二甲氨基)二甲基硅烷 Bis(dimethylamino)dimethylsilane,>;97.0%(GC)(3768-58-9)
  • 敏感性:Moisture Sensitive
  • TSCA:Yes

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Derivatization Reagents 衍生分析试剂
  4. Derivatization Reagents GC - Derivatization Reagents
  5. Reagents for Silylation - Derivatization Reagents GC
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Derivatization Reagents 衍生分析试剂
  4. Fluka Reagents
  1. CVD & ALD Precursors
  1. CVD & ALD Precursors
  2. Silicon
  1. Silanes & Silanols for CVD & ALD
  2. Silicon

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