4-Fluorobenzoyl Chloride 对氟苯甲酰氯

CAS 403-43-0 MFCD00000684

化学结构图

403-43-0
SMILES: O=C(Cl)c1ccc(F)cc1

化学属性

Mol. FormulaC7H4ClFO
Mol. Weight159
Boiling Point82
Melting Point10-12
TSCAT
Density1.342
Refractive index1.5290 to 1.5330
Flash Point82°C(lit.)
Stability对湿度敏感
Appearance D 1.5309，相对密度 1.342，f.p.180℉(82℃)，不溶于水，在水中分解，溶于醇、醚中，易吸潮。 本品为无色或淡黄色液体，m.p.9℃，b.p.82℃/2.67kPa，n 20

别名和识别编码

Chemical Name4-Fluorobenzoyl Chloride
CAS Number403-43-0
Alfabeta NameFLUOROBENZOYLCHLORIDE 4-
MDL NumberMFCD00000684
Synonym 4-氟苄氧基氯 4-Fluorobenzoylchloride,98% 对氟苯甲醛氟 4-Fluorbenzoesäurechlorid 4-Fluorobenzoyl Chloride p-Fluorobenzoyl Chloride para-Fluorobenzoyl chloride 4-Fluorobenozylchloride AKOS BBS-00003921 LABOTEST-BB LTBB000747 p-Fluorobenzoic acid chloride P-FLUO[A]RO BENZOYL CHLORIDE 4-Fluorobenzoic acid chloride Benzoyl chloride, p-fluoro- FLUOROBENZOYL(4-) CHLORIDE 4-Fluorbenzoylchlorid 4-FLUOROBENZOYL CHLORIDE 2,6-二溴-6-氟苯胺 4-Fluor-benzoylchlorid 4-氟苯(甲)酰氯,98% Benzoyl chloride, p-fluoro- p-Fluorobenzoyl P-FLUOROBENZOYL CHLORIDE 4-Fluoro-benzoyl chloride 4-fluoro-benzoylchlorid p-Fluorobenzoic acid chloride 4-Fluorobenzenecarbonyl chloride p-Fluorobenzoyl chloride 对氟苯甲酰氯 Benzoyl chloride, 4-fluoro- 4-Fluorobenzoyl chloride 4-氟苯甲酰氯
EC Number206-961-4
Beilstein Registry Number386215
PubChem Substance ID67879
Chemical Name Translation对氟苯甲酰氯
Reaxys-RN386215
InChIKeyCZKLEJHVLCMVQR-UHFFFAOYSA-N
LabNetwork Molecule IDLN00007667
InChIInChI=1S/C7H4ClFO/c8-7(10)5-1-3-6(9)4-2-5/h1-4H
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; carbonyl chloride; 1fragment
  • {SNA} Acid Halides, Aryl Fluorinated Building Blocks, Building Blocks, C7, Carbonyl Compounds, Chemical Synthesis, Fluorinated Building Blocks, Organic Building Blocks, Organic Fluorinated Building Blocks, Other Fluorinated Organic Building Blocks
  • {Chemicalbook} 农药中间体: 杀菌剂中间体: 吗啉类杀菌剂

相关文献及参考

  • Short: EINECS
  • Short: III/35E
  • Short: III/20b
  • Beilstein:9(1)137

安全信息

Warnings LACHRYMATOR, CORROSIVE
Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S20 When using do not eat or drink 使用时，不得进食，饮水；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
Risk Statements
  • R34 Causes burns 会导致灼伤
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P370+P378
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H227 Combustible liquid 可燃液体
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Packing GroupII
UN Number 3265 UN 3265 8/PG 2 UN3265
Storage condition Moisture Sensitive 对湿度敏感，密封保存。
Hazard Codes 8 C
Hazard Class8

其他信息

  • 海关编码:29163900
  • Acros Organics:4-氟苯甲酰氯 4-Fluorobenzoyl chloride, 98%(403-43-0)
  • MSDS 信息:4-Fluorobenozylchloride(403-43-0).msds
  • 用途一:用作染料、农药、医药中间体
  • TSCA:T
  • TCI Shanghai:4-氟苯甲酰氯 4-Fluorobenzoyl Chloride,>;97.0%(T)(403-43-0)
  • Sigma Aldrich:403-43-0(sigmaaldrich)
  • 对氟苯甲酰氯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010228 对氟苯甲酰氯 100g 750元 2011/04/16 F0213 4-氟苯甲酰氯 4-Fluorobenzoyl Chloride 500G 4320元 2011/04/16 F0213 4-氟苯甲酰氯 4-Fluorobenzoyl Chloride 25G 540元
  • F:10-19
  • 上游原料:氯 --> 对氟苯甲酸
  • 水中分解。
  • MOL 文件:403-43-0.mol
  • 用途三:医药、农药中间体。
  • 敏感性:Lachrymatory
  • 用途二:对氟苯甲酰氯是杀菌剂氟吗啉的中间体。
  • 图谱信息:对氟苯甲酰氯(403-43-0)质谱(MS) 对氟苯甲酰氯(403-43-0)Raman光谱 对氟苯甲酰氯(403-43-0)核磁图( 1 HNMR) 对氟苯甲酰氯(403-43-0)红外图谱(IR1) 对氟苯甲酰氯(403-43-0)核磁图( 13 CNMR)
  • Hazard Note:Corrosive/Lachrymatory
  • 方法一:其制备方法是将对氟苯甲酸与氯化亚砜反应，反应结束后蒸去氯化亚砜得产品。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Fluorinated Building Blocks 氟化物砌块
  4. Organic Fluorinated Building Blocks - Fluorinated Building Blocks
  5. Other Fluorinated Organic Building Blocks - Organic Fluorinated Building Blocks
  6. Aryl Fluorinated Building Blocks 芳基氟化物
  7. C7 - Aryl Fluorinated Building Blocks
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Acid Halides 酸性卤化物(酰氯等)
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Acyl halide
  2. acyl chloride

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