Methyl 2-(bromomethyl)acrylate methyl 2-(bromomethyl)acrylate

CAS 4224-69-5 MFCD00011697

化学结构图

4224-69-5
SMILES: C=C(CBr)C(=O)OC

化学属性

Mol. FormulaC5H7BrO2
Mol. Weight179.01
Refractive index1.4870 to 1.4910
Boiling Point187.1°C at 760 mmHg
Density1.489
Flash Point78°C
Melting PointN/A

别名和识别编码

Chemical Namemethyl 2-(bromomethyl)acrylate
CAS Number4224-69-5
PubChem Substance ID521093
Beilstein Registry Number1852481
MDL NumberMFCD00011697
EC Number250-023-7
Reaxys-RN1852481
Synonym Methyl 2-(bromomethyl)acrylate {LY} Methyl 2-(bromomethyl)acrylate {} {LY} Methyl 2-(bromomethyl)acrylate {} {} {LY} Methyl 2-(bromomethyl)acrylate {} {} {} {LY} Methyl 2-(bromomethyl)acrylate {} {} {} {} {LY} Methyl 2-(bromomethyl)acrylate {} {} {} {} {} {LY} Methyl 2-(bromomethyl)acrylate {} {} {} {} {} {} {LY} Methyl 2-(bromomethyl)acrylate {} {} {} {} {} {} {} {LY} Methyl 2-(bromomethyl)acrylate {} {} {} {} {} {} {} {} {LY} Methyl 2-(bromomethyl)acrylate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl 2-(bromomethyl)acrylate {} {} {} {} {} {} {} {} {} {} {LY} Methyl 2-(bromomethyl)acrylate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl 2-(bromomethyl)acrylate {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl 2-(bromomethyl)acrylate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl 2-(bromomethyl)acrylate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Chemical Name Translationmethyl 2-(bromomethyl)acrylate
InChIKeyCFTUQSLVERGMHL-UHFFFAOYSA-N
LabNetwork Molecule IDLN00110875
InChIInChI=1S/C5H7BrO2/c1-4(3-6)5(7)8-2/h1,3H2,2H3
Canonical SMILESC=C(C(OC)=O)CBr
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分类

  • {SNA} Acrylate, Acrylic Monomers, Building Blocks, C2 to C5, Carbonyl Compounds, Chemical Synthesis, Esters, Monomers, Organic Building Blocks, Polymer Science, 材料科学
  • {SNA} Acrylate, Acrylic Monomers, Building Blocks,

相关文献及参考

  • 1. Tetrahedron Asymmetry 17 , 516, (2006) 摘要
  • 2. J. Org. Chem. 72 , 398, (2007) 摘要
  • Corp MSDS 1 (2), 2305:B / FT-IR 2 (1), 1078:A / FT-NMR 1 (1), 1031:C / RegBook 1 (1), 745:J / Structure Index 1 , 115:A:4 / Vapor Phase 3 , 696:D

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H227 Combustible liquid 可燃液体
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 6.1 Xi
RTECSAS4900000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {}
UN Number 2810 UN 2810 6.1/PG 2
Packing GroupII

其他信息

  • MOL 文件:4224-69-5.mol
  • Sigma Aldrich:4224-69-5(sigmaaldrich)
  • 2-(溴甲基)丙烯酸甲酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M2067 2-(溴甲基)丙烯酸甲酯 Methyl 2-(Bromomethyl)acrylate 1G 981元 2014/06/02 M2067 2-(溴甲基)丙烯酸甲酯 Methyl 2-(Bromomethyl)acrylate 5G 3390元 2010/06/21 367630050 2-(溴甲基)丙烯酸甲酯 Methyl 2-(bromomethyl)acrylate 96% 5 GR 4770元
  • Acros Organics:2-(溴甲基)丙烯酸甲酯 Methyl 2-(bromomethyl)acrylate, 96%(4224-69-5)
  • F:8-10

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters - Carbonyl Compounds
  6. C2 to C5 - Esters
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. C - Alphabetic
  5. CI - CL - C
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters
  6. C12 to C63
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Monomers
  4. Acrylic Monomers 丙烯酸单体
  5. Acrylamide and Methacrylamide

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