Methyl 2-(bromomethyl)acrylate methyl 2-(bromomethyl)acrylate

CAS 4224-69-5 MFCD00011697

化学结构图

4224-69-5
SMILES: C=C(CBr)C(=O)OC

化学属性

Mol. FormulaC5H7BrO2
Mol. Weight179.01
Refractive index1.4870 to 1.4910
Boiling Point187.1°C at 760 mmHg
Density1.489
Flash Point78°C

别名和识别编码

Chemical Namemethyl 2-(bromomethyl)acrylate
CAS Number4224-69-5
PubChem Substance ID521093
Beilstein Registry Number1852481
MDL NumberMFCD00011697
EC Number250-023-7
Reaxys-RN1852481
Synonym Methyl 2-(bromomethyl)acrylate {LY} Methyl 2-(bromomethyl)acrylate {} {LY} Methyl 2-(bromomethyl)acrylate {} {} {LY} Methyl 2-(bromomethyl)acrylate {} {} {} {LY} Methyl 2-(bromomethyl)acrylate {} {} {} {} {LY} Methyl 2-(bromomethyl)acrylate {} {} {} {} {} {LY} Methyl 2-(bromomethyl)acrylate {} {} {} {} {} {} {LY} Methyl 2-(bromomethyl)acrylate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl 2-(bromomethyl)acrylate {} {} {} {} {} {} {} {} {LY} Methyl 2-(bromomethyl)acrylate {} {} {} {} {} {} {} {} {} {LY} Methyl 2-(bromomethyl)acrylate {} {} {} {} {} {} {} {} {} {} {LY} Methyl 2-(bromomethyl)acrylate {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl 2-(bromomethyl)acrylate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl 2-(bromomethyl)acrylate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl 2-(bromomethyl)acrylate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Chemical Name Translationmethyl 2-(bromomethyl)acrylate
InChIKeyCFTUQSLVERGMHL-UHFFFAOYSA-N
LabNetwork Molecule IDLN00110875
InChIInChI=1S/C5H7BrO2/c1-4(3-6)5(7)8-2/h1,3H2,2H3
Canonical SMILESC=C(CBr)C(OC)=O
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分类

  • {SNA} Acrylate, Acrylic Monomers, Building Blocks, C2 to C5, Carbonyl Compounds, Chemical Synthesis, Esters, Monomers, Organic Building Blocks, Polymer Science, 材料科学
  • {SNA} Acrylate, Acrylic Monomers, Building Blocks,

相关文献及参考

  • 1. Tetrahedron Asymmetry 17 , 516, (2006) 摘要
  • 2. J. Org. Chem. 72 , 398, (2007) 摘要
  • Corp MSDS 1 (2), 2305:B / FT-IR 2 (1), 1078:A / FT-NMR 1 (1), 1031:C / RegBook 1 (1), 745:J / Structure Index 1 , 115:A:4 / Vapor Phase 3 , 696:D

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H227 Combustible liquid 可燃液体
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 6.1 Xi
RTECSAS4900000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P332+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {}
UN Number 2810 UN 2810 6.1/PG 2
Packing GroupII

其他信息

  • MOL 文件:4224-69-5.mol
  • Sigma Aldrich:4224-69-5(sigmaaldrich)
  • 2-(溴甲基)丙烯酸甲酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M2067 2-(溴甲基)丙烯酸甲酯 Methyl 2-(Bromomethyl)acrylate 1G 981元 2014/06/02 M2067 2-(溴甲基)丙烯酸甲酯 Methyl 2-(Bromomethyl)acrylate 5G 3390元 2010/06/21 367630050 2-(溴甲基)丙烯酸甲酯 Methyl 2-(bromomethyl)acrylate 96% 5 GR 4770元
  • Acros Organics:2-(溴甲基)丙烯酸甲酯 Methyl 2-(bromomethyl)acrylate, 96%(4224-69-5)
  • F:8-10

系列性分类


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