1-Bromo-3,3,3-Trifluoroacetone 3-溴-1,1,1-三氟丙酮

CAS 431-35-6 MFCD00039237

化学结构图

431-35-6
SMILES: O=C(CBr)C(F)(F)F

化学属性

Mol. FormulaC3H2BrF3O
Mol. Weight190.95
Boiling Point87
Refractive index1.3730 to 1.3770
Density1.839
Flash Point5°C
TSCANo
Melting Point<-80 °C
Appearance colorless liq.

别名和识别编码

Chemical Name1-Bromo-3,3,3-Trifluoroacetone
CAS Number431-35-6
Alfabeta NameBROMOTRIFLUOROACETONE 3111---,,
MDL NumberMFCD00039237
PubChem Substance ID87564176
EC Number207-071-9
Beilstein Registry Number1703387
Synonym 3-Bromo-1,1,1-trifluoropropan-2-one {LY} 3-Bromo-1,1,1-trifluoropropan-2-one {} {LY} 3-Bromo-1,1,1-trifluoropropan-2-one {} {} {LY} 3-Bromo-1,1,1-trifluoropropan-2-one {} {} {} {LY} 3-Bromo-1,1,1-trifluoropropan-2-one {} {} {} {} {LY} 3-Bromo-1,1,1-trifluoropropan-2-one {} {} {} {} {} {LY} 3-Bromo-1,1,1-trifluoropropan-2-one {} {} {} {} {} {} {LY} 3-Bromo-1,1,1-trifluoropropan-2-one {} {} {} {} {} {} {} {LY} 3-Bromo-1,1,1-trifluoropropan-2-one {} {} {} {} {} {} {} {} {LY} 3-Bromo-1,1,1-trifluoropropan-2-one {} {} {} {} {} {} {} {} {} {LY} 3-Bromo-1,1,1-trifluoropropan-2-one {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromo-1,1,1-trifluoropropan-2-one {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromo-1,1,1-trifluoropropan-2-one {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromo-1,1,1-trifluoropropan-2-one {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromo-1,1,1-trifluoropropan-2-one {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromo-1,1
Chemical Name Translation3-溴-1,1,1-三氟丙酮
Reaxys-RN1703387
InChIKeyONZQYZKCUHFORE-UHFFFAOYSA-N
LabNetwork Molecule IDLN00116183
InChIInChI=1S/C3H2BrF3O/c4-1-2(8)3(5,6)7/h1H2
Canonical SMILESO=C(CBr)C(F)(F)F
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分类

  • {SNA} Building Blocks, C3 to C6, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks
  • Building Blocks, C3 to C6, Carbonyl Compounds, Chemical Synthesis, Ketones, Organic Building Blocks

相关文献及参考

  • Beil. 1 ,IV,3220
  • FT-NMR 1 (1), 652:B / RegBook 1 (1), 459:B / Structure Index 1 , 65:A:6
  • A novel reductive olefination reaction with aldehydes, mediated by Ti(O-i-Pr)4 and PPh3, provides a one-pot synthesis of trifluoromethylated trans-allylic alcohols: Chem. Commun., 2195 (1998):
  • The oxime is readily converted with base to the highly reactive species 1,1,1-trifluoro-2-nitroso-2-propene, which undergoes hetero-Diels-Alder reactions, e.g. with cyclopentadiene or indole to give fused oxazolines. The indole adduct rearomatizes to give 1-(3-indolyl)-3,3,3-trifluoroacetoxime: J. Org. Chem., 57, 339 (1992).

安全信息

Warnings LACHRYMATOR, FLAMMABLE, CORROSIVE
GHS Symbol
WGK Germany3
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes F,C
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
Packing GroupII
UN Number 2924 UN2924
Risk Statements
  • R11 Highly flammable 非常易燃
  • R37 Irritating to respiratory system 刺激呼吸道
  • R34 Causes burns 会导致灼伤
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
Hazard Class3/8
Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

其他信息

  • F:19
  • MSDS 信息:1-Bromo-3,3,3-trifluoroacetone(431-35-6).msds
  • Alfa Aesar:1-溴-3,3,3-三氟丙酮97% 1-Bromo-3,3,3-trifluoroacetone, 97%(431-35-6)
  • Acros Organics:3-溴-1,1,1-三氟丙酮 3-Bromo-1,1,1-trifluoroacetone, 97%(431-35-6)
  • 图谱信息:3-溴-1,1,1-三氟丙酮(431-35-6)核磁图( 1 HNMR) 3-溴-1,1,1-三氟丙酮(431-35-6)质谱(MS) 3-溴-1,1,1-三氟丙酮(431-35-6)核磁图( 13 CNMR) 3-溴-1,1,1-三氟丙酮(431-35-6)红外图谱(IR1)
  • TCI Shanghai:3-溴-1,1,1-三氟丙酮 3-Bromo-1,1,1-trifluoro-2-propanone,>;95.0%(GC)(431-35-6)
  • Sigma Aldrich:431-35-6(sigmaaldrich)
  • Hazard Note:Corrosive/Flammable/Lachrymatory
  • 3-溴-1,1,1-三氟丙酮价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B1240 1-溴-3,3,3-三氟丙酮 1-Bromo-3,3,3-trifluoroacetone 5G 429元 2014/06/02 B1240 1-溴-3,3,3-三氟丙酮 1-Bromo-3,3,3-trifluoroacetone 25G 1820元 2010/06/21 297440050 3-溴-1,1,1-三氟丙酮 3-Bromo-1,1,1-trifluoroacetone 97% 5 GR 400元
  • 敏感性:Lachrymatory
  • MOL 文件:431-35-6.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Ketones - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Ketones - Carbonyl Compounds
  6. C3 to C6 - Ketones
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Ketones 酮
  6. C15 to C38
  1. Organo Fluorine
  2. Fluorine

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