Bromocyclopropane 溴代环丙烷

CAS 4333-56-6 MFCD00001271

化学结构图

4333-56-6
SMILES: BrC1CC1

化学属性

Mol. FormulaC3H5Br
Mol. Weight120.98
Boiling Point69°C at 760 mmHg
TSCAT
Density1.51
Refractive index1.4570 to 1.4610
Flash Point-6.67°C
Appearance 浅黄色至无色透明液体，沸点67-69℃，折光率(nD20) 1.4605，密度(d420) 1.5120， 闪点-6℃。
Solubilityimmiscible

别名和识别编码

Chemical NameBromocyclopropane
CAS Number4333-56-6
Alfabeta NameCYCLOPROPYLBROMIDE
MDL NumberMFCD00001271
EC Number224-375-7
Beilstein Registry Number1900287
Synonym Bromocyclopropane {LY} Bromocyclopropane {} {LY} Bromocyclopropane {} {} {LY} Bromocyclopropane {} {} {} {LY} Bromocyclopropane {} {} {} {} {LY} Bromocyclopropane {} {} {} {} {} {LY} Bromocyclopropane {} {} {} {} {} {} {LY} Bromocyclopropane {} {} {} {} {} {} {} {LY} Bromocyclopropane {} {} {} {} {} {} {} {} {LY} Bromocyclopropane {} {} {} {} {} {} {} {} {} {LY} Bromocyclopropane {} {} {} {} {} {} {} {} {} {} {LY} Bromocyclopropane {} {} {} {} {} {} {} {} {} {} {} {LY} Bromocyclopropane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bromocyclopropane {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bromocyclopropane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bromocyclopropane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bromocyclopropane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bromocyclopropane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bromocyclop
PubChem Substance ID78037
Chemical Name Translation溴代环丙烷
Reaxys-RN1900287
InChIKeyLKXYJYDRLBPHRS-UHFFFAOYSA-N
LabNetwork Molecule IDLN00008749
InChIInChI=1S/C3H5Br/c4-3-1-2-3/h3H,1-2H2
Canonical SMILESBrC1CC1
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分类

  • {SNA} Alkyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks

产品应用

  • 本品是重要的药物合成中间体，可用于合成环丙沙星、恩罗沙星和斯帕沙星等多种含环丙基的药物及氟喹诺酮类抗菌药物。

相关文献及参考

  • Beilstein: 5,IV,6
  • The Grignard reagent functions as an allyl anion equivalent in the reaction with thioacetals catalyzed by Dichlorobis(triphenyl­phosphine)­nickel(II)­, 13930: J. Am. Chem. Soc., 111, 9119 (1989):
  • The lithio-derivative reacts with Bis(cyclopentadienyl)­titanium dichloride, A11456, to give bis(cyclopropyl)titanocene, which reacts with carbonyl compounds to give alkylidenecyclopropane derivatives: Tetrahedron Lett., 34, 943 (1993). Similarly, esters and lactones give enol ethers and acetylenes give vinylcyclopropanes.

安全信息

Warnings LACHRYMATOR, FLAMMABLE
Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S29 Do not empty into drains 不要排入下水道；
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S37 Wear suitable gloves 戴适当手套；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
Risk Statements
  • R11 Highly flammable 非常易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Packing GroupII
UN Number 1993 UN 1993 3/PG 2
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 3 F,Xi
Storage condition -20°C {LY} -20°C 2-8°C {} {LY} -20°C {} {} {LY} -20°C {} {} {} {LY} -20°C {} {} {} {} {LY} -20°C {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Hazard Class3

其他信息

  • Acros Organics:溴环丙烷 Cyclopropyl bromide, 99%(4333-56-6)
  • 用途一:医药中间体。
  • TCI Shanghai:溴化环丙烷 Bromocyclopropane,>;95.0%(GC)(4333-56-6)
  • MOL 文件:4333-56-6.mol
  • Sigma Aldrich:4333-56-6(sigmaaldrich)
  • 图谱信息:溴代环丙烷(4333-56-6)红外图谱(IR1) 溴代环丙烷(4333-56-6)质谱(MS) 溴代环丙烷(4333-56-6)核磁图( 13 CNMR) 溴代环丙烷(4333-56-6)核磁图( 1 HNMR)
  • F:8-19
  • Hazard Note:Irritant
  • 用途二:本品是重要的药物合成中间体，可用于合成环丙沙星、恩罗沙星和斯帕沙星等多种含环丙基的药物及氟喹诺酮类抗菌药物。
  • Alfa Aesar:溴环丙烷,99% Bromocyclopropane, 99%(4333-56-6)
  • 溴代环丙烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C1067 溴化环丙烷 Bromocyclopropane 25G 895元 2014/06/02 C1067 溴化环丙烷 Bromocyclopropane 250G 5330元 2014/06/02 C1067 溴化环丙烷 Bromocyclopropane 5G 308元
  • 溴代环丙烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 C1067 溴化环丙烷 Bromocyclopropane 25G 1450元 2011/04/16 C1067 溴化环丙烷 Bromocyclopropane 250G 8670元 2011/04/16 C1067 溴化环丙烷 Bromocyclopropane 5G 503元
  • 和水混溶。
  • 海关编码:29035990
  • 下游产品:环丙甲醛 --> 环戊乙酸
  • TSCA:T
  • MSDS 信息:Bromocyclopropane(4333-56-6).msds

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Alkyl 烷基卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Alkyl 烷基卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Alkenyl
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Simple 3-Membered Ring Compounds 简单三元环化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Cyclopropy 环丙基化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Cyclopropy 环丙基化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Cyclopropy 环丙基化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Cyclopropy 环丙基化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Cyclopropy 环丙基化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Cyclopropy 环丙基化合物

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