5-Norbornene-2,3-dicarbonyl chloride, trans- 反式-3,6-桥-亚甲基-1,2,3,6-四氢邻苯二甲酰氯

CAS 4582-21-2 MFCD00167567

化学结构图

4582-21-2
SMILES: O=C(Cl)[C@H]1[C@@H]2C=C[C@@H](C2)[C@@H]1C(=O)Cl

化学属性

Mol. FormulaC9H8Cl2O2
Mol. Weight219.06
Refractive indexn20/D 1.517(lit.)
Boiling Point114-118 °C/11 mmHg(lit.)
Density1.349 g/mL at 25 °C(lit.)

别名和识别编码

Chemical NameBicyclo[2.2.1]-5-heptene-2,3-dicarbonyl chloride
MDL NumberMFCD00167567
CAS Number4582-21-2
Synonym trans-Bicyclo(2.2.1)hept-5-enyl-2,3-dicarbonylchloride 反-3,6-内亚甲基-1,2,3,6-四氢邻苯二甲酰氯 反式-3,6-桥-亚甲基-1,2,3,6-四氢邻苯二甲酰氯
PubChem Substance ID98325
EC Number224-967-5
Chemical Name Translation反式-3,6-桥-亚甲基-1,2,3,6-四氢邻苯二甲酰氯
InChIKeyKANQIAARVSWKKG-UHFFFAOYSA-N
Wiswesser Line NotationL55 A CUTJ FVG GVG -T
Beilstein Registry Number3134243
InChIInChI=1S/C9H8Cl2O2/c10-8(12)6-4-1-2-5(3-4)7(6)9(11)13/h1-2,4-7H,3H2
LabNetwork Molecule IDLN04671919
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分类

  • {SNA} Acid Halides, Building Blocks, Carbonyl Compounds, Chemical Synthesis, Materials Science, Monomers, Norbornene Monomers, Organic Building Blocks, Polymer Science
  • {SNA} Acid Halides, Building Blocks, Carbonyl Compounds, Chemical Synthesis, Monomers, Norbornene Monomers, Organic Building Blocks, Polymer Science, 材料科学
  • {SNA} Acid Halides, Building Blocks, Carbonyl Compounds, Chemical Synthesis, Organic Building Blocks

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H332 Harmful if inhaled 吸入有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H312+H332
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSRB8225000
Precautionary statements
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
Signal word Danger
Hazard Codes C
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R34 Causes burns 会导致灼伤
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1830 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   28,313,1974

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 1 mL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   28,313,1974

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Acid Halides 酸性卤化物(酰氯等)
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Acid Halides 酸性卤化物(酰氯等)

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