2,3,6,7-Tetrahydro-1H,5H-benzo[ij]quinolizine 2,3,6,7-四氢-1H,5H-苯并[i,j]喹嗪

CAS 479-59-4 MFCD00006917

化学结构图

479-59-4
SMILES: c1cc2c3c(c1)CCCN3CCC2

化学属性

Mol. FormulaC12H15N
Mol. Weight173.25
Flash Point>110°(230°F)
TSCAYes
Boiling Point170-173 °C at 31 mmHg
Melting Point34-36°C
Density1.422
Appearance 白色晶体。熔点34-36℃（97%商品）。其溴氢酸盐（[83647-41-7]）的熔点239-242℃。

别名和识别编码

Chemical Name2,3,6,7-Tetrahydro-1H,5H-benzo[ij]quinolizine
Synonym 2,3,6,7-Tetrahydro-1H,5H-pyrido[3,2,1-ij]quinoline {LY} 2,3,6,7-Tetrahydro-1H,5H-pyrido[3,2,1-ij]quinoline {} {LY} 2,3,6,7-Tetrahydro-1H,5H-pyrido[3,2,1-ij]quinoline {} {} {LY} 2,3,6,7-Tetrahydro-1H,5H-pyrido[3,2,1-ij]quinoline {} {} {} {LY} 2,3,6,7-Tetrahydro-1H,5H-pyrido[3,2,1-ij]quinoline {} {} {} {} {LY} 2,3,6,7-Tetrahydro-1H,5H-pyrido[3,2,1-ij]quinoline {} {} {} {} {} {LY} 2,3,6,7-Tetrahydro-1H,5H-pyrido[3,2,1-ij]quinoline {} {} {} {} {} {} {LY} 2,3,6,7-Tetrahydro-1H,5H-pyrido[3,2,1-ij]quinoline {} {} {} {} {} {} {} {LY} 2,3,6,7-Tetrahydro-1H,5H-pyrido[3,2,1-ij]quinoline {} {} {} {} {} {} {} {} {LY} 2,3,6,7-Tetrahydro-1H,5H-pyrido[3,2,1-ij]quinoline {} {} {} {} {} {} {} {} {} {LY} 2,3,6,7-Tetrahydro-1H,5H-pyrido[3,2,1-ij]quinoline {} {} {} {} {} {} {} {} {} {} {LY} 2,3,6,7-Tetrahydro-1H,5H-pyrido[3,2,1-ij]quinoline {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} 2,3,6,7-Tetrahydro-1H,5H-pyrido[3,2,1-ij]quinoline {} {} {} {} {} {} {} {}
MDL NumberMFCD00006917
CAS Number479-59-4
EC Number207-535-0
Beilstein Registry Number139925
PubChem Substance ID68069
Reaxys-RN139925
Chemical Name Translation2,3,6,7-四氢-1H,5H-苯并[i,j]喹嗪
InChIKeyDZFWNZJKBJOGFQ-UHFFFAOYSA-N
LabNetwork Molecule IDLN01249554
InChIInChI=1S/C12H15N/c1-4-10-6-2-8-13-9-3-7-11(5-1)12(10)13/h1,4-5H,2-3,6-9H2
Canonical SMILESC12=CC=CC3=C1N(CCC3)CCC2
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分类

  • {SNA} Charge Transport and Photosensitizing Materials, Light-Emitting Dopants and Fluorescent Dyes, Materials Science, OLED and PLED Materials, Organic and Printed Electronics, Photoluminescent Materials, Photonic and Optical Materials
  • {SNA} Charge Transport and Photosensitizing Materials, Light-Emitting Dopants and Fluorescent Dyes, OLED and PLED Materials, Organic and Printed Electronics,

相关文献及参考

  • Short: III/35D3 Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Carbon-13, Part 3: Heterocycles Author: Gupta, R.R.; Jain, M.; Lechner, M.D.; Mikhova, B.M. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35D3 Year: 2007 Keyword: C-13; NMR; carbon-13; chemical shifts; coupling constants; heterocycles; nuclear magnetic resonance ISBN: 978-3-540-29731-4 ISBN: 3-540-29731-6 Internet Resource: DOI: 10.1007/978-3-540-47067-0 RefComment: VIII, 342 p., 1 illus., Hardcover RefComment: Written for Science and engineers in the fields of physics, chemistry and physical chemistry who inted to use NMR to study the structure and the binding of molecules Abstract: Nuclear Magnetic Resonance (NMR) is based on the fact that certain nuclei exhibit a magnetic moment, orient by a magnetic field, and absorb characteristic frequencies in the radiofrequency part of the spectrum. NMR is now a leading technique and a powerful tool for the investigation of the structure and interaction of molecules. The present Landolt-Börnstein volume III/35 Nuclear Magnetic Resonance (NMR) Data is therefore of major interest to all scientists and engineers who use NMR to study the structure and the binding of molecules. Volume III/35 "NMR-Data" is divided into several subvolumes and parts. Subvolume III/35A contains the nuclei B-11 and P-31, subvolume III/35B contains the nuclei F-19 and N-15, subvolume III/35C contains the nucleus H-1, subvolume III/35D contains the nucleus C-13, subvolume III/35E contains the nucleus O-17, and subvolume III/35G contains the nucleus Se-77. More nuclei are planned for future volumes.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

Storage condition 2-8°C {LY} 2-8°C Air Sensitive {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
WGK Germany3
Safety Statements
Signal word Warning
GHS Symbol
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R52/53
Precautionary statements
  • P308+P313
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P405 Store locked up. 上锁保管。
Hazard statements
  • H341 Suspected of causing genetic defects 怀疑导致遗传性缺陷

其他信息

  • MSDS 信息:Julolidine(479-59-4).msds
  • 用途一:用于有机合成。
  • Acros Organics:久洛尼定 Julolidine, 98%(479-59-4)
  • TCI Shanghai:久洛尼定 Julolidine,>;97.0%(GC)(T)(479-59-4)
  • 方法一:66.5g（0.5mol）四氢喹啉和400g1-溴-3-氯丙烷在150-160℃油浴中加热20h，冷却后加入50ml浓盐酸和500ml水，进行水蒸气蒸馏，除去过量的1-溴-3-氯丙烷。用40%氢氧化钠将剩余物调至碱性，用乙醚提取。乙醚提取液用水洗涤，经粒状氢氧化钠干燥，蒸除乙醚，减压蒸馏，收集105-110℃（0.133kPa）馏分，得67-70g久洛尼定。
  • 久洛尼定价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 J0007 久洛尼定 Julolidine 5G 729元 2014/06/02 J0007 久洛尼定 Julolidine 25G 2530元 2010/06/21 122830250 久洛尼定 Julolidine 98% 25 GR 2550元
  • Alfa Aesar:多洛尼定,98+% Julolidine, 98%(479-59-4)
  • Sigma Aldrich:479-59-4(sigmaaldrich)
  • 图谱信息:久洛尼定(479-59-4)质谱(MS) 久洛尼定(479-59-4)红外图谱(IR1)
  • 上游原料:1-溴-3-氯丙烷 --> 四氢喹啉
  • MOL 文件:479-59-4.mol

系列性分类

  1. Materials Science 材料科学
  2. Products for Organic & Printed Electronics Research
  3. OLED and PLED Materials - Organic and Printed Electronics
  4. Charge Transport and Photosensitizing Materials - OLED and PLED Materials

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