Ammonium pyrrolidinedithiocarbamate 吡咯烷二硫代甲酸铵

CAS 5108-96-3 MFCD00012720

化学结构图

5108-96-3
SMILES: N.S=C(S)N1CCCC1

化学属性

Mol. FormulaC5H12N2S2
Mol. Weight164.29
Melting Point142-143 °C
TSCAYes
SolubilitySoluble in water (50 mg/ml), ethanol, chloroform, and DMSO (100 mM).
Density1.264
Stability对空气和热敏感

别名和识别编码

Chemical NameAmmonium pyrrolidinedithiocarbamate
Synonym Pyrrolidinedithiocarbamate (ammonium) {SNA} 1-吡咯烷二硫代羧酸 铵盐 1-吡咯烷二硫代羧酸铵盐 1-吡咯烷硫代氨基甲酸铵盐 1-吡咯烷硫代羧酸铵盐 AMMONIUM 1-PYRROLIDINEDITHIOCARBAMATE AMMONIUM PYRROLIDINE DITHIOFORMATE AMMONIUM PYRROLIDINEDITHIOCARBAMATE AMMONIUM SALT Ammonium pyrrolidinedithiocarbamate N,N-TETRAMETHYLENEDITHIOCARBAMIC ACID AMMONIUM SALT PDC {} {Chemblink} 1-Pyrrolidinecarbodithioic acid ammonium salt; APDC; APDTC; Ammonium tetramethylenedithiocarbamate {} {} {Chemicalbook} 1-PYRROLIDINECARBODITHIOIC ACID, AMMONIUM SALT {} {} {} {SNA} 吡咯烷二硫代氨基甲酸铵 吡咯烷二硫代甲酸铵 四亚甲基二硫代氨基甲酸铵 四亚甲基二硫代氨基甲酸铵, 1-吡咯烷二硫代羧酸铵盐,吡咯烷二硫代氨基甲酸铵 四亚甲基二硫代氨基甲酸铵;1-吡咯烷二硫代羧酸铵盐;吡咯烷二硫代氨基甲
CAS Number5108-96-3
PubChem Substance ID87574803
EC Number225-834-4
Beilstein Registry Number3730472
MDL NumberMFCD00012720
Reaxys-RN3730472
Chemical Name Translation吡咯烷二硫代甲酸铵
InChIKeyMDDIUTVUBYEEEM-UHFFFAOYSA-N
LabNetwork Molecule IDLN00195329
InChIInChI=1S/C5H9NS2.H3N/c7-5(8)6-3-1-2-4-6;/h1-4H2,(H,7,8);1H3
Canonical SMILESSC(N1CCCC1)=S.N
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分类

  • {SNA} A-AM, Analytical Reagents, Analytical/Chromatography, Bioactive Small Molecules, Cell Biology, Gravimetric Reagents
  • {SA} A-AM, Application Index, Bioactive Small Molecules, Biochemicals and Reagents, Cell Biology, Cell Signaling Enzymes, Cell Signaling and Neuroscience, Core Bioreagents, Enzyme Inhibitors,
  • {SNA} Application Index, Cell Signaling Enzymes, Core Bioreagents, Enzyme Inhibitors, Enzyme Inhibitors by Enzyme, L to O, NOS Regulators, Nitric Oxide Metabolism, Nitric Oxide Synthase, Nitric Oxide Synthase Regulators,

产品应用

  • 原子吸收分析用试剂。发射光谱测定三价铬。多种金属络合剂。测尿中痕量铅。微量测定镉、钴、铋和钼。从酸性溶液中沉淀砷、铋、镉、钴、铜、铁、锰、镍、铅、锑、锡、钒、锌。
  • 依托抑制NOS mRNA的翻译,从而防止一氧化氮合成酶(nitric oxide synthetase)的诱导;诱导大鼠血管平滑肌细胞凋亡和抑制白血病HL- 60细胞凋亡。99%规格适用于此类研究。

相关文献及参考

  • Chelating ligand useful for the extraction of many metals from aqueous solution.
  • Beilstein: 20,V,1,331
  • Beil. 20 ,V,1,331

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xn Xi Xi,Xn
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
Signal word
Storage condition 2-8°C, sealed storage, away from moisture {LY} 2-8°C, sealed storage, away from moisture <0°C <;0 Hygroscopic {} {LY} 2-8°C, sealed storage, away from moisture {} {} {Chemicalbook} 2-8°C 储存温度2-8°C，充氩保存 密封阴凉干燥保存。瓶内存放一小袋碳酸铵。 密封阴凉干燥保存。瓶内存放一小袋碳酸铵。储存温度2-8°C
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R22 Harmful if swallowed 吞咽有害

其他信息

  • Acros Organics:1-吡咯烷硫代氨基甲酸铵盐 1-Pyrrolidinecarbodithioic acid, ammonium salt, 98%(5108-96-3)
  • 外观性质:白色结晶性粉末。有氨气味。有吸湿性。在空气中不稳定，宜保存在氨气流中。溶于水，微溶于乙醇。熔点149-152℃。有刺激性。
  • F:3
  • MOL 文件:5108-96-3.mol
  • Alfa Aesar:1-吡咯烷羰基二硫酸铵盐,98% 1-Pyrrolidinecarbodithioic acid ammonium salt, 98%(5108-96-3)
  • 用途一:发射光谱测定三价铬。多种金属络合剂。测尿中痕量铅。微量测定镉、钴、铋和钼。从酸性溶液中沉淀砷、铋、镉、钴、铜、铁、锰、镍、铅、锑、锡、钒、锌。原子吸收分光光度分析的络合剂。原子吸收分析试剂
  • 吡咯烷二硫代甲酸铵盐价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30012160 吡咯烷二硫代甲酸铵盐 25g 55元 2011/08/23 30012114 吡咯烷二硫代甲酸铵盐 25g 68元 2011/04/16 P0644 1-吡咯烷二硫代甲酸铵[原子吸收分析用试剂] Ammonium 1-Pyrrolidinecarbodithioate [Reagent for Atomic Absorption Analysis] 250G 3050元
  • 图谱信息:吡咯烷二硫代甲酸铵盐(5108-96-3)核磁图( 1 HNMR) 吡咯烷二硫代甲酸铵盐(5108-96-3)红外图谱(IR1) 吡咯烷二硫代甲酸铵盐(5108-96-3)质谱(MS) 吡咯烷二硫代甲酸铵盐(5108-96-3)核磁图( 13 CNMR) 吡咯烷二硫代甲酸铵盐(5108-96-3)红外图谱(IR2)
  • TCI Shanghai:1-吡咯烷二硫代甲酸铵盐[原子吸收分析用试剂] Ammonium 1-Pyrrolidinecarbodithioate [Reagent for Atomic Absorption Analysis],>;95.0%(T)(5108-96-3)
  • 海关编码:29339990
  • 敏感性:Hygroscopic
  • Sigma Aldrich:5108-96-3(sigmaaldrich)
  • MSDS 信息:Ammonium 1-pyrrolidinedithiocarbamate(5108-96-3).msds
  • 有氨气味。有吸湿性。在空气中不稳定，宜保存在氨气流中。溶于水，微溶于乙醇。有刺激性。

系列性分类

  1. Life Science 生命科学
  2. Cell Biology 细胞生物学
  3. Bioactive Small Molecules - Cell Biology
  4. A-AM - Bioactive Small Molecules
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Pyrroles 吡咯
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Alkyl 烷基卤代烃
  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Enzymes, Inhibitors, and Substrates - Biochemicals and Reagents
  4. Application Index - Enzymes, Inhibitors, and Substrates
  5. Cell Signaling Enzymes - Application Index
  6. Nitric Oxide Metabolism - Cell Signaling Enzymes
  7. NOS Regulators - Nitric Oxide Metabolism
  1. Analytical & Chromatography 分析化学与色谱
  2. HPLC
  3. Analytical Reagents
  1. Analytical & Chromatography 分析化学与色谱
  2. Gas Chromatography (GC) 气相色谱
  3. Packed GC
  4. Packings, Uncoated
  5. Activated Carbon
  1. Functional Group 官能团索引
  2. thiocarbamic acid
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Dry Powder Media
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Cell Signaling and Neuroscience
  4. Nitric Oxide and Cell Stress
  5. Nitric Oxide Metabolism
  6. Nitric Oxide Scavengers
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Enzymes, Inhibitors, and Substrates
  4. Cell Signaling Enzymes
  5. Nitric Oxide Metabolism
  6. NOS Inhibitors
  1. Life Science 生命科学
  2. Biochemicals and Reagents
  3. Enzymes, Inhibitors, and Substrates
  4. Enzyme Inhibitors
  5. Enzyme Inhibitors by Enzyme
  6. NADH peroxidase