Methyltrioctylammonium chloride 甲基三辛基氯化铵

CAS 5137-55-3 MFCD00011862

化学结构图

5137-55-3
SMILES: CCCCCCCC[N+](C)(CCCCCCCC)CCCCCCCC.[Cl-]

化学属性

Mol. FormulaC25H54ClN
Mol. Weight404.16
Density0.884
Refractive index1.4465
Flash Point132°C(lit.)
TSCAYes
Boiling Point240 °C at 760 mmHg
Melting Point-20 °C
Appearance 淡黄色粘稠液体或膏体，沸点 225℃，熔点 -20℃
Stability易吸潮
pH:A

别名和识别编码

Chemical NameMethyltrioctylammonium Chloride
MDL NumberMFCD00011862
CAS Number5137-55-3
EC Number264-120-7
Beilstein Registry Number4039255
Synonym Methyl trioctyl ammonium chloride {LY} Methyl trioctyl ammonium chloride TOMAC salt capriquat methyltricaprylylammonium methyltricaprylylammonium chloride methyltrioctylammonium chloride tricaprylylmethylammonium trioctylmethylammonium trioctylmethylammonium chloride trioctylmethylammonium iodide trioctylmethylammonium trifluoroacetate {} {LY} Methyl trioctyl ammonium chloride {} {} {LY} Methyl trioctyl ammonium chloride {} {} {} {LY} Methyl trioctyl ammonium chloride {} {} {} {} {LY} Methyl trioctyl ammonium chloride {} {} {} {} {} {LY} Methyl trioctyl ammonium chloride {} {} {} {} {} {} {LY} Methyl trioctyl ammonium chloride {} {} {} {} {} {} {} {LY} Methyl trioctyl ammonium chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Methyl trioctyl ammonium chloride {} {} {} {} {} {} {} {} {} {LY} Methyl trioctyl ammonium chloride
PubChem Substance ID21218
Reaxys-RN4039255
Chemical Name Translation甲基三辛基氯化铵
Wiswesser Line Notation8K8&8&1 &G
LabNetwork Molecule IDLN00197497
InChIInChI=1S/C25H54N.ClH/c1-5-8-11-14-17-20-23-26(4,24-21-18-15-12-9-6-2)25-22-19-16-13-10-7-3;/h5-25H2,1-4H3;1H/q+1;/p-1
Canonical SMILESCCCCCCCC[N+](CCCCCCCC)(CCCCCCCC)C.[Cl-]
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分类

  • {SNA} cationic
  • {SNA} Ammonium Salts, Chemical Synthesis, Phase Transfer Catalysts, Synthetic Reagents
  • {SNA} Ammonium Salts, Cationic Detergents, Chemical Synthesis, Detergents, Detergents A to M, Phase Transfer Catalysts,
  • {SNA} Ammonium Salts, Cationic Detergents, Chemical Synthesis, Detergents A to M, Phase Transfer Catalysts, Synthetic Reagents, 去垢剂, 生化试剂
  • {SNA} Ammonium Salts, Biochemicals and Reagents, Cationic Detergents, Chemical Synthesis, Detergents, Detergents A to M, Phase Transfer Catalysts, Synthetic Reagents

产品应用

  • 相转移试剂

相关文献及参考

  • Mixture of C8-C10; predominantly C8.
  • Widely used lipophilic phase-transfer catalyst. Catalyzes the synthesis of long-chain alkyl azides from the bromides in water or formamide: Tetrahedron Lett., 30, 1245 (1989), the formation and saponification of hindered esters with KOH in the absence of solvent: J. Org. Chem., 51, 740 (1986), the solvent-free SNAr reactions of halopyridines: Heterocycles, 32, 1947 (1991), and dehydrohalogenation of vic-dibromides to alkynes: Org. Prep. Proced. Int., 21, 232 (1989). Catalyzes the solvent-free liquid-liquid phase-transfer hydroboration of olefins, using aqueous NaBH4: Synlett, 997 (2000). See Appendix 2.
  • Aliquat is a registered trademark of Cognis Corporation.

安全信息

Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S39 Wear eye/face protection 戴眼睛/面孔保护装置；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R38 Irritating to skin 刺激皮肤
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R50/53
Precautionary statements
  • P203
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P310+P330
  • P301+P316
  • P301+P317
  • P301+P330+P331
  • P302+P352
  • P302+P361+P354
  • P304+P340
  • P305+P351+P338
  • P305+P354+P338
  • P316
  • P317
  • P318
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H301 Toxic if swallowed 吞食有毒
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H361 Suspected of damaging fertility or the unborn child 怀疑对生育能力或未出生婴儿造成伤害
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter dust mask type N95 (US), Eyeshields, Faceshields, Gloves
RTECSUZ2997500
Packing GroupIII
UN Number 2810 UN2810
Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen Hygroscopic {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, s
Hazard Codes 6.1 Xn,N Xn;N
Hazard Class6.1 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 6600 ug/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
REFERENCE :
   AEHA** U.S. Army, Environmental Hygiene Agency Reports.  (Edgewood Arsenal,
   MD 21010)  Volume(issue)/page/year: 33-3-68/1971

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 280 mg/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
REFERENCE :
   AEHA** U.S. Army, Environmental Hygiene Agency Reports.  (Edgewood Arsena

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 10 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AEHA** U.S. Army, Environmental Hygiene Agency Reports.  (Edgewood Arsenal,
   MD 21010)  Volume(issue)/page/year: 33-3-68/1971

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 3300 ug/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
REFERENCE :
   AEHA** U.S. Army, Environmental Hygiene Agency Reports.  (Edgewood Arsenal,
   MD 21010)  Volume(issue)/page/year: 33-3-68/1971

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 10 mg/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
REFERENCE :
   AEHA** U.S. Army, Environmental Hygiene Agency Reports.  (Edgewood Arsenal,
   MD 21010)  Volume(issue)/page/year: 33-3-68/1971

TYPE OF TEST            : LD50 - Lethal d

其他信息

  • MOL 文件:5137-55-3.mol
  • F:3-10
  • TCI Shanghai:三正辛基甲基氯化铵 Methyltri-n-octylammonium Chloride,>;95.0%(T)(5137-55-3)
  • 海关编码:29239000
  • C8 和 C10 链的混合物，其中以C8 为主。水中溶解度:10 g/L (20°C)，溶于苯、氯仿、异丙醇和乙醇。
  • Sigma Aldrich:5137-55-3(sigmaaldrich)
  • MSDS 信息:Aliquat 336(5137-55-3).msds
  • 下游产品:3-硝基苯基甲烷磺酰氯 --> 4-氯苯基甲磺酰氯 --> 1,3-二甲基-2-咪唑啉酮 --> 6-苄氧基嘌呤 --> (2-氯苯基)甲基磺酰氯
  • 敏感性:Hygroscopic
  • 甲基三辛基氯化铵价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 K6948501 甲基三辛基氯化铵;三辛基甲基氯化铵 10g 931元 2011/08/23 xw060002 三辛基甲基氯化铵 100g 180元 2011/04/16 T1365 甲基三正辛基氯化铵 Methyltri-n-octylammonium Chloride 500G 2620元
  • 检测方法:NMR
  • 用途一:相转移试剂

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Phase Transfer Catalysts 相转移催化剂
  4. Ammonium Salts - Phase Transfer Catalysts
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Amine Salts - Nitrogen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Quaternary Ammonium Compounds 季铵化合物
  1. Functional Group 官能团索引
  2. quaternary ammonium salt

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