Samarium(III) trifluoromethanesulfonate 三氟甲磺酸钐(III)
CAS 52093-28-4 MFCD00192431
化学结构图
SMILES: O=S(=O)([O-])C(F)(F)F.O=S(=O)([O-])C(F)(F)F.O=S(=O)([O-])C(F)(F)F.[Sm+3]
化学属性
| Mol. Formula | Sm(SO3CF3)3 |
|---|---|
| Mol. Weight | 597.57 |
| TSCA | No |
| Appearance | white to off-white pwdr. |
| Stability | hygroscopic |
别名和识别编码
| Chemical Name | Samarium(III) trifluoromethanesulfonate |
|---|---|
| Synonym | AgOTf cpd Al(OTf)3 As(otf)2 Cu(OTf)2 Eu(OTf)3 In(OTf)3 Samarium(III) triflate TFMSA cpd aluminum triflate cerium triflate cupric trifluoromethanesulfonate indium triflate mercury(II) trifluoromethanesulfonate samarium triflate silver triflate silver trifluoromethanesulfonate triflic acid trifluoromethanesulfonate trifluoromethanesulfonic acid trifluoromethanesulfonic acid, aluminum salt trifluoromethanesulfonic acid, barium salt trifluoromethanesulfonic acid, cerium (+3) salt trifluoromethanesulfonic acid, cupric salt trifluoromethanesulfonic acid, indium salt trifluoromethanesulfonic acid, lanthanum (+3) salt trifluoromethanesulfonic acid, lithium salt trifluoromethanesulfonic acid, samarium salt |
| MDL Number | MFCD00192431 |
| PubChem Substance ID | 10145316 |
| EC Number | 000-000-0 |
| CAS Number | 52093-28-4 |
| Chemical Name Translation | 三氟甲磺酸钐(III) |
| LabNetwork Molecule ID | LN00222204 |
| InChI | InChI=1S/3CHF3O3S.Sm/c3*2-1(3,4)8(5,6)7;/h3*(H,5,6,7);/q;;;+3/p-3 |
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分类
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Samarium
相关文献及参考
- Effective catalyst for the Baylis-Hillman reaction, using 1,4-Diazabicyclo[2.2.2]octane, A14003: J. Org. Chem., 63, 7183 (1998). The uses of rare-earth metal triflates in organic synthesis have been reviewed by S. Kobayashi: Synlett, 689 (1994); Chem. Rev., 102, 2227 (2002).
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352
- P304+P340
- P305+P351+P338
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
- P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
- P332+P313
- P337+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P403+P233
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
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