9,10-Dibromoanthracene 9,10-二溴蒽
CAS 523-27-3 MFCD00001244
化学结构图
SMILES: Brc1c2ccccc2c(Br)c2ccccc12
化学属性
| Mol. Formula | C14H8Br2 |
|---|---|
| Mol. Weight | 336.03 |
| Melting Point | 220-225 |
| Density | 1.7651 |
| TSCA | Yes |
| Appearance | 黄色针状结晶，熔点226℃。能升华，氧化后生成蒽醌。溶于热苯和热甲苯，微溶于醇、醚和冷苯，不溶于水。 |
别名和识别编码
| Chemical Name | 9,10-Dibromoanthracene |
|---|---|
| CAS Number | 523-27-3 |
| Synonym | 9,10-Dibromanthracen 9,10-DIBROMOANTHRACENE 9,10-Dibromoanthracene 9,10-DIBROMO ANTHRACENEN 9,10-dibromoananthracene 9,10-二溴蒽 NSC 6263 二溴并三苯 Anthracene,9,10-dibromo- ms-Dibromoanthracene 9,1O-dibromoanthracene 9,I O-Dibromanthracen 9,10-DIRBOMOANTHRACENE Anthracene, 9,10-dibromo- 9,10-dibromo-anthracen 9,10-dibromo-anthracene 9,10-Dibromoanthracene99% |
| MDL Number | MFCD00001244 |
| PubChem Substance ID | 68226 |
| EC Number | 208-342-4 |
| Beilstein Registry Number | 1912109 |
| Reaxys-RN | 1912109 |
| Merck Number | 3018 |
| Chemical Name Translation | 9,10-二溴蒽 |
| LabNetwork Molecule ID | LN00190016 |
| InChI | InChI=1S/C14H8Br2/c15-13-9-5-1-2-6-10(9)14(16)12-8-4-3-7-11(12)13/h1-8H |
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分类
- {SNA} Aryl, Building Blocks, C13 to C37+, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
- {uni_hamburg} no charge; carbocycle; aromatic; large ring; fused rings; 6ring; 10ring; 14ring; 1fragment
- Aryl, Building Blocks, C13 to C37+, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
产品应用
- 9,10-Dibromoanthracene is a dibrominated polycyclic aromatic hydrocarbon (PAH). 9,10-Dibromoanthracene is often used as an energy acceptor and activator in reactions that produce chemiluminescence.
相关文献及参考
- Blakey, I. et al.: Macromolecules, 34, 9130 (2001); Faven, C. et al.: Anal. Sci., 9, 371 (1993);
- Merck 14 ,3018
- Beil. 5 ,665
- FT-IR 1 (1), 1032:B / FT-IR 2 (2), 1771:A / IR-Spectra (3), 621:B / IR-Spectra (2), 553:C / RegBook 1 (1), 1223:M / Structure Index 1 , 187:D:4
- Short: II/3 Title: Luminescence of Organic Substances Author: Schmillen, A.; Legler, R. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/3 Year: 1967 ISBN: 3-540-03895-7 ISBN: 978-3-540-03895-5 Internet Resource: DOI:10.1007/b86158 RefComment: 270 figs., VIII, 416 pages. Hardcover Abstract: For more than 1000 luminescent organic substances the most important data are represented as wave numbers of absorption and emission bands, decay times and quantum efficiencies. Additional tables contain further information for restricted groups of substances (figures on typical spectra, wave numbers of sharp single bands, influence of surrounding molecules, etc.).
- Short: III/20b Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei Cl ... Rb Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20b Year: 1988 Keyword: NQR ISBN: 3-540-18483-X ISBN: 978-3-540-18483-6 Internet Resource: DOI:10.1007/b86664 RefComment: IX,717 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
- Short: III/35D2 Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Carbon-13, Part 2: Aromatic Compounds A
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P273 Avoid release to the environment. 避免释放到环境中。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352
- P304+P340
- P305+P351+P338
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
- P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
- P332+P313
- P337+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
- P403+P233
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H315 Causes skin irritation 会刺激皮肤
- H316 Causes mild skin irritation 会轻微的刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
- H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R50/53
其他信息
- 下游产品:9,10-蒽二羧醛
- 上游原料:四氯化碳 --> 蒽
- TCI Shanghai:9,10-二溴蒽 9,10-Dibromoanthracene,>;98.0%(GC)(523-27-3)
- 用途一:有机合成中间体。
- 9,10-二溴蒽价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D0166 9,10-二溴蒽 9,10-Dibromoanthracene 500G 8040元 2014/06/02 D0166 9,10-二溴蒽 9,10-Dibromoanthracene 25G 950元 2010/06/21 112710500 9,10-二溴蒽 9,10-Dibromoanthracene 96% 50 GR 1668元
- Alfa Aesar:9,10-二溴蒽,98% 9,10-Dibromoanthracene, 98%(523-27-3)
- Sigma Aldrich:523-27-3(sigmaaldrich)
- MSDS 信息:9,10-Dibromoanthracene(523-27-3).msds
- 方法一:由蒽溴化而得。溴化反应在室温进行，以四氯化碳作溶剂。采用80-85%蒽为原料，加溴反应半小时，产率83-88%。
- MOL 文件:523-27-3.mol
- 图谱信息:9,10-二溴蒽(523-27-3)核磁图( 1 HNMR) 9,10-二溴蒽(523-27-3)红外图谱(IR1) 9,10-二溴蒽(523-27-3)红外图谱(IR2) 9,10-二溴蒽(523-27-3)质谱(MS) 9,10-二溴蒽(523-27-3)红外图谱(IR3) 9,10-二溴蒽(523-27-3)核磁图( 13 CNMR)
- Acros Organics:9,10-二溴蒽 9,10-Dibromoanthracene, 96%(523-27-3)
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