N-[(tert-Butoxy)carbonyl]-D-tryptophan N-叔丁氧羰基-D-色氨酸

CAS 5241-64-5 MFCD00037944

化学结构图

5241-64-5
SMILES: CC(C)(C)OC(=O)N[C@H](Cc1c[nH]c2ccccc12)C(=O)O

化学属性

Mol. FormulaC16H20N2O4
Mol. Weight304.34
Density1.262
Melting Point131-136°C
TSCANo
Boiling Point535.7°C at 760 mmHg
Flash Point277.8°C

别名和识别编码

Chemical NameN-[(tert-Butoxy)carbonyl]-D-tryptophan
MDL NumberMFCD00037944
CAS Number5241-64-5
EC Number226-042-1
Beilstein Registry Number22(5)14,62
Synonym Boc-D-Tryptophan {LY} Boc-D-Tryptophan {} {LY} Boc-D-Tryptophan {} {} {LY} Boc-D-Tryptophan {} {} {} {LY} Boc-D-Tryptophan {} {} {} {} {LY} Boc-D-Tryptophan {} {} {} {} {} {LY} Boc-D-Tryptophan {} {} {} {} {} {} {LY} Boc-D-Tryptophan {} {} {} {} {} {} {} {LY} Boc-D-Tryptophan {} {} {} {} {} {} {} {} {LY} Boc-D-Tryptophan {} {} {} {} {} {} {} {} {} {LY} Boc-D-Tryptophan {} {} {} {} {} {} {} {} {} {} {LY} Boc-D-Tryptophan {} {} {} {} {} {} {} {} {} {} {} {LY} Boc-D-Tryptophan {} {} {} {} {} {} {} {} {} {} {} {} {LY} Boc-D-Tryptophan {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Boc-D-Tryptophan {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Boc-D-Tryptophan {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Boc-D-Tryptophan {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Boc-D-Tryptophan {} {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID111050
Reaxys-RN4237334
Chemical Name TranslationN-叔丁氧羰基-D-色氨酸
InChIKeyNFVNYBJCJGKVQK-CYBMUJFWSA-N
LabNetwork Molecule IDLN00237020
InChIInChI=1S/C16H20N2O4/c1-16(2,3)22-15(21)18-13(14(19)20)8-10-9-17-12-7-5-4-6-11(10)12/h4-7,9,13,17H,8H2,1-3H3,(H,18,21)(H,19,20)/t13-/m1/s1
Canonical SMILESO=C(O)[C@@H](CC1=CNC2=C1C=CC=C2)NC(OC(C)(C)C)=O
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分类

  • {SNA} Amino Acid Derivatives, Chemical Biology, Chemical Synthesis, Peptide Chemistry, Tryptophan
  • {SNA} Amino Acids & Derivatives, Chemical Biology, Chemical Synthesis, Peptide Chemistry, Tryptophan

相关文献及参考

  • Beilstein:22(5)14,62

安全信息

Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • Sigma Aldrich:5241-64-5(sigmaaldrich)
  • 比旋光度:19 ° (c=1, DMF)
  • TCI Shanghai:N-(叔丁氧羰基)-D-色氨酸 N-(tert-Butoxycarbonyl)-D-tryptophan,>;97.0%(T)(5241-64-5)
  • 下游产品:DL-色氨酸 --> 亮丙瑞林 --> 五肽胃泌素
  • Acros Organics:色氨酸 Nalpha-BOC-D-Tryptophane, 97%(5241-64-5)
  • MOL 文件:5241-64-5.mol
  • BOC-D-色氨酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B2259 N-(叔丁氧羰基)-D-色氨酸 N-(tert-Butoxycarbonyl)-D-tryptophan 5G 669元 2014/06/02 B2259 N-(叔丁氧羰基)-D-色氨酸 N-(tert-Butoxycarbonyl)-D-tryptophan 1G 195元 2010/06/21 275750025 BOC-D-色氨酸 Nalpha-BOC-D-Tryptophane 97% 2.5 GR 1263元
  • 外观性质:白色细粉末晶体。熔点:131-136°C
  • Alfa Aesar:N(α)-Boc-D-色氨酸,98% N(alpha)-Boc-D-tryptophan, 97%(5241-64-5)
  • 图谱信息:BOC-D-色氨酸(5241-64-5)红外图谱(IR1) BOC-D-色氨酸(5241-64-5)红外图谱(IR2) BOC-D-色氨酸(5241-64-5)质谱(MS)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Chemical Biology 生物化学
  3. Peptide Chemistry 多肽化学
  4. Amino Acid Derivatives 氨基酸及其衍生物
  5. Tryptophan - Amino Acid Derivatives
  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Amino Acids 氨基酸
  4. Modified Amino Acids - Amino Acids
  5. Boc-amino Acids
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Indoles
  1. Life Science 生命科学
  2. Biochemistry / Glyco-Chemistry
  3. Protected & Labeled Amino Acids

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