Ethyl 2-Chloropropionate 2-氯丙酸乙酯

CAS 535-13-7 MFCD00000864

化学结构图

535-13-7
SMILES: CCOC(=O)C(C)Cl

化学属性

Mol. FormulaC5H9ClO2
Mol. Weight137
Refractive index1.4150 to 1.4190
Boiling Point147°C
Density1.072
Flash Point38°C(lit.)
TSCAYes
Solubility不溶于水，溶于乙醇、乙醚。
pH:A

别名和识别编码

Chemical NameEthyl 2-Chloropropionate
CAS Number535-13-7
PubChem Substance ID87565859
EC Number208-610-0
Beilstein Registry Number2,248
MDL NumberMFCD00000864
Reaxys-RN773906
Merck Number3785
Synonym Α-氯代丙酸乙酯 NSC 2-CHLOROPROPIONIC ACID ETHYL ESTER ethyl-2-chloropropionic acid 2-Chloropropionic acid ethyl ethyl (±)-2-chloropropionate (±)-Ethyl 2-chloropropionate 2-氯丙酸乙酯 {Chemi 2-Chlor-propansäureethylester propionicacid,2-chloro-,ethylester Ethyl-2-chloropropionate Ethyl-(±)-2-chlorpropionat (±)-2-Chlorpropionsäureethylester Α-氯丙酸乙酯 (±)-2-chloroproprionate (2RS)-2-Chloropropionic acid ethyl ester 2-Chlorpropionsäureethylester propanoic acid, 2-chloro-, ethyl ester 2-Chloropropionic acid ethyl ester propionic acid, 2-chloro-, ethyl ester 乙基-2-氯丙酸酯 Ethyl 2-chloropropanoate Ethyl 2-Chloropropionate 2- ETHYL 2-CHLOROPROPIONATE pract Propionic acid, 2-chloro-, ethyl ester Ethyl-(2-chlorpropionat) Ethyl α-chloropropionate 2-chloro-propanoicaciethylester ethyl2-chloropropanoate 2-chloropropanoicacid,ethylester 2-Chlorpropansäureethylester 2-Chloropropionic acid, ethyl ester Propanoic acid, 2-chloro-, ethyl ester ETHYL 2-CHLOROPROPIONATE 3-Nitrosalicyclic Acid ETHYL ALPHA-CHLOROPROPIONATE (±)-2-chloro-propionic acid ethyl ester 2-CHLORO-PROPIONIC ACID ETHYL ESTER ethyl 2-chloropropanoate 2-chloropropanoic acid, ethyl ester Ethyl 2-chloropropionate Propanoicacid,2-chloro-,ethylester 2-Chloropropion
Chemical Name Translation2-氯丙酸乙酯
LabNetwork Molecule IDLN00223431
InChIInChI=1S/C5H9ClO2/c1-3-8-5(7)4(2)6/h4H,3H2,1-2H3
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分类

  • Building Blocks, C2 to C5, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks
  • {uni_hamburg} no charge; ester; racemate; 1fragment
  • {SNA} Building Blocks, C2 to C5, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks
  • {Chemicalbook} 农药中间体: 除草剂中间体: 苯氧羧酸类和芳氧基苯氧基羧酸类除草剂

产品应用

  • 用作溶剂，用于有机合成。

相关文献及参考

  • Short: IV
  • Short: IV/20A
  • Merck:14,3785
  • Merck:14,3785 Beilstein:2,248
  • Short: IV/18B
  • Short: III/38B

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P303+P361+P353
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P370+P378
  • P403+P235
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R10 Flammable 易燃
UN Number 2935 UN2935
Packing GroupIII
Hazard Class3
Storage condition Flammables area
Warnings 危化品目录(2015)
Restrict 危险品

其他信息

  • 方法一:其制备方法与制备α-氯代丙酸甲酯类似，以乙醇代替甲醇，与α-氯代丙酸反应而得到产品。反应方程式：CH 3 CHClCOOH+C 2 H 5 OH→CH 3 CHClCOOC 2 H 5 +H 2 O
  • Alfa Aesar:2-氯丙酸乙酯,97% Ethyl 2-chloropropionate, 97%(535-13-7)
  • MOL 文件:535-13-7.mol
  • 图谱信息:2-氯丙酸乙酯(535-13-7)红外图谱(IR1) 2-氯丙酸乙酯(535-13-7)Raman光谱 2-氯丙酸乙酯(535-13-7)核磁图( 1 HNMR) 2-氯丙酸乙酯(535-13-7)红外图谱(IR2) 2-氯丙酸乙酯(535-13-7)质谱(MS)
  • 用途二:α-氯代丙酸乙酯是除草剂喹禾灵的中间体。
  • MSDS 信息:2-氯丙酸乙酯(535-13-7).msds
  • 外观性质:无色液体，有香味。
  • TCI Shanghai:2-氯丙酸乙酯 Ethyl 2-Chloropropionate,>;95.0%(GC)(535-13-7)
  • 下游产品:恶唑禾草灵 --> 2-甲基苯并呋喃
  • Acros Organics:2-氯丙酸乙酯 Ethyl 2-chloropropionate, 97%(535-13-7)
  • 2-氯丙酸乙酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C0790 2-氯丙酸乙酯 Ethyl 2-Chloropropionate 25ML 247元 2011/04/16 C0790 2-氯丙酸乙酯 Ethyl 2-Chloropropionate 500ML 2240元 2010/06/21 185230250 2-氯丙酸乙酯 Ethyl 2-chloropropionate 97% 25 ML 278元
  • 用途一:用作农药、医药、香料的中间体
  • 有香味，不溶于水，可混溶于乙醇、乙醚。
  • Sigma Aldrich:535-13-7(sigmaaldrich)
  • 上游原料:丙酸 --> 丙酸甲酯
  • 用途三:用作农药中间体。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Esters - Carbonyl Compounds
  6. C2 to C5 - Esters

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