4-Piperidinol 4-羟基哌啶

CAS 5382-16-1 MFCD00005999

化学结构图

5382-16-1
SMILES: Oc1ccncc1

化学属性

Mol. FormulaC5H11NO
Mol. Weight101.15
Density1.422
Boiling Point222°C at 760 mmHg
Melting Point86-90°C
Flash Point108°C
TSCANo
Solubility可溶
Stability易吸潮
Appearance 白色至类白色吸湿性物质,溶解于水。

别名和识别编码

Chemical Name4-Piperidinol
CAS Number5382-16-1
Alfabeta NameHYDROXYPIPERIDINE 4-
MDL NumberMFCD00005999
EC Number226-373-1
Beilstein Registry Number21(1)188
Synonym Piperidin-4-ol {LY} Piperidin-4-ol {} {LY} Piperidin-4-ol {} {} {LY} Piperidin-4-ol {} {} {} {LY} Piperidin-4-ol {} {} {} {} {LY} Piperidin-4-ol {} {} {} {} {} {LY} Piperidin-4-ol {} {} {} {} {} {} {LY} Piperidin-4-ol {} {} {} {} {} {} {} {LY} Piperidin-4-ol {} {} {} {} {} {} {} {} {LY} Piperidin-4-ol {} {} {} {} {} {} {} {} {} {LY} Piperidin-4-ol {} {} {} {} {} {} {} {} {} {} {LY} Piperidin-4-ol {} {} {} {} {} {} {} {} {} {} {} {LY} Piperidin-4-ol {} {} {} {} {} {} {} {} {} {} {} {} {LY} Piperidin-4-ol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Piperidin-4-ol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Piperidin-4-ol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Piperidin-4-ol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Piperidin-4-ol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Piperidin-4-ol {} {} {} {}
PubChem Substance ID79341
Reaxys-RN102738
Chemical Name Translation4-羟基哌啶
InChIKeyHDOWRFHMPULYOA-UHFFFAOYSA-N
LabNetwork Molecule IDLN00157751
InChIInChI=1S/C5H11NO/c7-5-1-3-6-4-2-5/h5-7H,1-4H2
Canonical SMILESOC1CCNCC1
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分类

  • {SNA} Building Blocks, C5 to C7, Chemical Synthesis, Heterocyclic Building Blocks, Piperidines

产品应用

  • 用在铜催化的N-对抗O-芳基化

相关文献及参考

  • Beilstein:21(1)188

安全信息

Warnings IRRITANT
Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R34 Causes burns 会导致灼伤
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P302+P352+P332+P313+P362+P364
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P337+P313
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Packing GroupIII
UN Number 2811 UN3263 3263
Storage condition RT, protect from light {LY} RT, protect from light {} {LY} RT, protect from light {} {} {LY} RT, protect from light {} {} {} {LY} RT, protect from light {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect
Hazard Codes Xi
Hazard Class8

其他信息

  • Alfa Aesar:4-羟基哌啶,97% 4-Hydroxypiperidine, 97%(5382-16-1)
  • 下游产品:2-(4-羟基哌啶-1-基)-6-三氟甲基嘧啶-4-甲酰胺 --> 1-(5-羟甲基嘧啶-2-基)哌啶-4-醇 --> 1-(4-羟甲基-6-三氟甲基嘧啶-2-基)哌啶-4-醇 --> 2-(4-羟基哌啶-1-基)嘧啶-5-甲酸乙酯 --> 2-(4-羟基哌啶-1-基)嘧啶-5-甲酸 --> 5-酰氨-2-(4-羟基哌啶-1-基)嘧啶 --> 洛哌丁胺 --> 2-(4-羟基哌啶-1-基)-6-三氟甲基嘧啶-4-甲酸乙酯 --> N-甲基-4-氯哌啶 --> 4-溴哌啶氢溴酸盐 --> 依巴斯汀
  • 检测方法:GC
  • 溶解于水。
  • MOL 文件:5382-16-1.mol
  • Hazard Note:Irritant
  • 4-羟基哌啶价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010128 4-羟基哌啶 10g 300元 2011/04/16 H0413 4-羟基哌啶 4-Hydroxypiperidine 25G 880元 2010/06/21 366511000 4-羟基哌啶 4-Hydroxypiperidine 99+% 100 GR 3204元
  • TCI Shanghai:4-羟基哌啶 4-Hydroxypiperidine,>;98.0%(GC)(T)(5382-16-1)
  • 敏感性:Hygroscopic
  • 海关编码:29333999
  • Acros Organics:4-羟基哌啶 4-Hydroxypiperidine, 99+%(5382-16-1)
  • Sigma Aldrich:5382-16-1(sigmaaldrich)
  • 用途一:用在铜催化的N-对抗O-芳基化
  • MSDS 信息:4-Hydroxypiperidine(5382-16-1).msds

系列性分类


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