• 原料直供
• 试剂商城
• 直接询价

分类

• {SNA} Analytical Reagents, Analytical/Chromatography, Buffers & Reagents, Chromatography Reagents & Solvents, HPLC, HPLC Buffer - Solid, HPLC Buffers, Solid
• {SNA} Analytical Reagents, Analytical/Chromatography, Chromatography Reagents & Solvents,
• {SNA} Chromatography Reagents & Solvents, HybridSPE-Phospholipid Technology, LC-MS Mobile Phase Additives, LC-MS Solvents & Reagents (CHROMASOLV), Precipitation Solvents, Blends, Additives, Sample Preparation & Purification, Solid Phase Extraction (SPE), 分析/色谱, 分析试剂
• {SNA} Essential Chemicals, Inorganic Salts, Solutions and Reagents, Reagent Grade, Research Essentials
• {SNA} Chromatography Reagents & Solvents,

产品应用

• 分析试剂，从贵金属盐中沉淀碱金属。
• 缓冲液组分，用于在凝聚胺（polybrene）亲和层析从复杂系统中分离和纯化糖胺（glycosaminoglycans）

相关文献及参考

• Merck:14,523 Beilstein: 2,IV,18
• Reagent for N-formylation of secondary amines and anilines: Tetrahedron Lett., 41, 9149 (2000).
• Widely used as a hydrogen donor in catalytic hydrogen transfer reductions. Review: Synthesis, 91 (1988). See also Palladium, A12012, Cyclohexene, A11359, Hydrazine monohydrate, A14005, Formic acid, A13285 and Sodium hypophosphite monohydrate, A13385.
• Short: III/5a
• A simple microwave-assisted method for catalytic transfer hydrogenation in ethylene glycol or 1,3-propanediol has been reported: J. Org. Chem., 64, 5746 (1999).
• Examples include:
• Reduction of aryl nitro groups to amines: Tetrahedron Lett., 25, 3415 (1984). For reductive cyclization of an o-nitrobenzyl ketone to an indole, see: Org. Synth. Coll., 9, 601 (1998). Hydrogenolysis of N-benzyl groups: Synthesis, 53 (1987); Tetrahedron Lett., 28, 515 (1987). Reduction of aldehydes and ketones to methyl and methylene groups: Tetrahedron Lett., 29, 3741 (1988). The temperature- and solvent-dependencies of this type of reaction have been studied: Synth. Commun., 22, 2673, 2683 (1992). Selective reduction of the heterocyclic ring of quinolines and isoquinolines: Synth. Commun., 20, 2815 (1990). Reduction of pyridine N-oxides to piperidines: J. Org. Chem., 66, 5264 (2001). Regioselective reduction of epoxides: J. Org. Chem., 60, 4922 (1995). Ammonium formate was found to be a more active H donor than either sodium formate or formic acid in the catalytic hydrogenolysis of aryl chlorides. For a comparative mechanistic study of this reaction, see: J. Org. Chem., 60, 1347 (1995).
• Merck:14,523

安全信息

GHS Symbol

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2250 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ZERNAL Zeitschrift fuer Ernaehrungswissenschaft.  (Dr. Dietrich Steinkopff
   Verlag, Postfach 111008, D-6100 Darmstadt 11, Fed. Rep. Ger.)  V.1- 1960- 
   Volume(issue)/page/year: 9,332,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 410 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ZERNAL Zeitschrift fuer Ernaehrungswissenschaft.  (Dr. Dietrich Steinkopff
   Verlag, Postfach 111008, D-6100 Darmstadt 11, Fed. Rep. Ger.)  V.1- 1960- 
   Volume(issue)/page/year: 9,332,1969

其他信息

• 水中溶解度(g/100ml):不同温度(℃)时每100毫升水中的溶解克数: 102g/0℃;143g/20℃;204g/40℃;311g/60℃;533g/80℃
• 毒性分级:中毒
• 急性毒性:口服-小鼠LD50: 2250 毫克/公斤;静脉-小鼠LD50: 410 毫克/公斤
• Alfa Aesar:甲酸铵,99% Ammonium formate, 99%(540-69-2)
• 易潮解，易溶于水，能溶于醇、氨水
• 用途四:分析试剂，从贵金属盐中沉淀碱金属。
• 甲酸铵价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30011618 甲酸铵;蚁酸铵 500g 47元 2011/08/23 30011628 甲酸铵;蚁酸铵 500g 41元 2010/06/21 168615000 甲酸铵 Ammonium formate 97% 500 GR 730元
• 类别:有毒物品
• 用途一:用于电解、电容器行业
• 敏感性:Hygroscopic
• MOL 文件:540-69-2.mol
• 上游原料:氨 --> 甲酸 --> 4-氯苯甲醛
• 储运特性:库房通风低温干燥
• F:3-10
• 易潮解，易溶于水，能溶于醇、氨水。
• 可燃性危险特性:可燃; 高温产生有毒氮氧化物和氨烟雾
• 下游产品:2,5-二甲氧基苄胺 --> 三唑酮 --> (1-甲基-2-哌啶)甲胺 --> 5-氮杂吲哚 --> 1,2,4-三氮唑 --> 3-吖丁啶羧酸 --> 5-氨基-2-吲哚 羧酸 --> N-Boc-3-羟基氮杂环丁烷 --> 3-氨基-5-氟吡啶 --> 5-氟-2-吡啶羧酸 --> 4-三氟甲基烟酸 --> 5-氨基-1H-吲哚-2-羧酸乙酯 --> 4-氯-7-甲基噻吩并[3,2-D]嘧啶 --> S-烯丙醇酮 --> 3-氨基-4-甲氧基苯甲酸 --> 3-(4-吗啉基)苯胺 --> 3-氯苄胺 --> 5-氯-1H-吲唑-3-乙酸 --> α-氨基乙苯 --> 1,3,5-三甲基-吡唑-4-甲胺 --> 4-甲基-5-甲酸基-1,3-噁唑 --> 4-甲基恶唑-5-羰酰氯 --> 3,5-双(三氟甲基)苯甲胺 --> 4-氯-2-甲基苄胺 --> 2,3-二羟基苯并[B]呋喃-5-基甲胺 --> 替考拉宁 A2 --> alpha-甲基苄胺 --> (R)-2-氨基庚烷 --> 3,4,5-三甲氧基苄胺 --> 吲唑-3-乙酸 --> 柠嗪酸 --> 香兰素胺盐酸盐 --> 4-氨基四氢吡喃
• 图谱信息:甲酸铵(540-69-2)Raman光谱 甲酸铵(540-69-2)核磁图( 13 CNMR) 甲酸铵(540-69-2)红外图谱(IR1) 甲酸铵(540-69-2)红外图谱(IR2)
• Acros Organics:甲酸铵 Ammonium formate, 99%(540-69-2)
• Sigma Aldrich:540-69-2(sigmaaldrich)
• 方法一:由甲酸和氨中和而得。将甲酸及水冷冻，搅拌下通氨气使pH值为7-7.5，降温至-5℃，甩滤，得甲酸铵。
• 用途三:用于有机合成，作医药中间体、分析试剂。
• 用途二:用作分析试剂，也用于有机合成
• 灭火剂:干粉、泡沫、砂土、二氧化碳, 雾状水
• MSDS 信息:Ammonium formate(540-69-2).msds