(1R,2R)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(4-BROMOBENZYL)ALLYLCHLOROSILANE] (R,R)-1,3-双[(4-溴苯基)甲基]-2-氯八氢-2-烯丙基-1H-1,3,2-苯并二氮杂噻咯

CAS 546084-25-7 MFCD10567380

化学结构图

546084-25-7
SMILES: C=CC[Si]1(Cl)N(CC2C=CC(Br)=CC=2)[C@@H]2CCCC[C@H]2N1CC1C=CC(Br)=CC=1

化学属性

Mol. FormulaC23H27Br2ClN2Si
Mol. Weight554.82
Melting Point95-100 °C
Appearance white solid
Stabilitymoisture sensitive, store cold

别名和识别编码

Chemical Name(R,R)-1,3-Bis[(4-bromophenyl)methyl]-2-chlorooctahydro-2-allyl-1H-1,3,2-benzodiazasilole
Synonym (3aR,7aR)-2-烯丙基-1,3-双(4-溴苄基)-2-氯八氢-1H-苯并[d][1,3,2]二氮杂噻咯 (R,R)-1,3-双[(4-溴苯基)甲基]-2-氯八氢-2-烯丙基-1H-1,3,2-苯并二氮杂噻咯
MDL NumberMFCD10567380
Chemical Name Translation(R,R)-1,3-双[(4-溴苯基)甲基]-2-氯八氢-2-烯丙基-1H-1,3,2-苯并二氮杂噻咯
PubChem Substance ID329762475
CAS Number546084-25-7
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分类

  • {SNA} Allylation, Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents

安全信息

GHS Symbol
WGK Germany1
Precautionary statements
  • P422 Store contents under… 存储目录在…之下。
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P231+P232
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
Signal word Danger
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
Hazard Codes F,C
Risk Statements
  • R15 Contact with water liberates extremely flammable gases 遇水会释放出极端易燃的气体
  • R34 Causes burns 会导致灼伤

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Allylation - Chiral Catalysts, Ligands, and Reagents
  1. Organocatalyst
  2. Silicon

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