(R)-(-)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamine (R)-(-)-N,N-二甲基-1-[(S)-2-(二苯基膦基)二茂铁基]乙胺

CAS 55700-44-2 MFCD00075286

化学结构图

55700-44-2
SMILES: C[C@H]([C]1[CH][CH][CH][C]1P(c1ccccc1)c1ccccc1)N(C)C.[CH]1[CH][CH][CH][CH]1.[Fe]

化学属性

Mol. FormulaC26H28FeNP
Mol. Weight441.34
Melting Point141-143
TSCANo
Danger-Level-
pH-:-
Redox-

别名和识别编码

Chemical NameFerrocene, 1-​[(1R)​-​1-​(dimethylamino)​ethyl]​-​2-​(diphenylphosphino)​-​, (2R)​-
MDL NumberMFCD00075286
PubChem Substance ID87568958
CAS Number55700-44-2
Synonym (R)-(-)-N,N-二甲基-1-[(S)-2-(二苯基膦基)二茂铁基]乙胺
Chemical Name Translation(R)-(-)-N,N-二甲基-1-[(S)-2-(二苯基膦基)二茂铁基]乙胺
LabNetwork Molecule IDLN01745846
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分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Other Chiral Ligands
  • {SNA} Asymmetric Synthesis, Basic Phosphine Ligands, Catalysis and Inorganic Chemistry, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Cross-Coupling, Other Chiral Ligands, Phosphine Compounds, Phosphine Ligands

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P332+P313
  • P301+P312+P330
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P302+P350
  • P337+P313
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H332 Harmful if inhaled 吸入有害
  • H315 Causes skin irritation 会刺激皮肤
  • H312 Harmful in contact with skin 皮肤接触有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H319 Causes serious eye irritation 严重刺激眼睛
Signal word
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R22 Harmful if swallowed 吞咽有害
Storage condition Air Sensitive
Hazard Codes Xn
Restrict -

系列性分类


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