Benzyltrimethylammonium chloride 苄基三甲基氯化铵

CAS 56-93-9 MFCD00011782

化学结构图

56-93-9
SMILES:

化学属性

Mol. FormulaC10H16ClN
Mol. Weight185.69
Density1.072 g/mL at 20 °C
Refractive indexn20/D 1.470
TSCAYes
Melting Point239 °C
Solubility800 G/L
Stability易吸潮
Appearance 无色结晶，135℃以上分解为氯化苄和三甲胺，易溶于水、乙醇和丁醇，不溶于醚。易潮解，一般商品为60%溶液，相对密度1.07（20/20℃）。 本品为白色固体。熔点155℃（分解）。
Flash Point>100°C
Boiling Point305.52 °C at 760 mmHg

别名和识别编码

Chemical NameBenzyltrimethylammonium chloride
Synonym Benzyltrimethylammonium (chloride) {LY} Benzyltrimethylammonium (chloride) {} {LY} Benzyltrimethylammonium (chloride) {} {} {LY} Benzyltrimethylammonium (chloride) {} {} {} {LY} Benzyltrimethylammonium (chloride) {} {} {} {} {LY} Benzyltrimethylammonium (chloride) {} {} {} {} {} {LY} Benzyltrimethylammonium (chloride) {} {} {} {} {} {} {LY} Benzyltrimethylammonium (chloride) {} {} {} {} {} {} {} {LY} Benzyltrimethylammonium (chloride) {} {} {} {} {} {} {} {} {LY} Benzyltrimethylammonium (chloride) {} {} {} {} {} {} {} {} {} {LY} Benzyltrimethylammonium (chloride) {} {} {} {} {} {} {} {} {} {} {LY} Benzyltrimethylammonium (chloride) {} {} {} {} {} {} {} {} {} {} {} {LY} Benzyltrimethylammonium (chloride) {} {} {} {} {} {} {} {} {} {} {} {} {LY} Benzyltrimethylammonium (chloride) {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Benzyltrimethylammonium (chloride) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Benzyltrimethylammon
MDL NumberMFCD00011782
CAS Number56-93-9
EC Number200-300-3
Beilstein Registry Number3917255
PubChem Substance ID87563484
Alfabeta NameBENZYLTRIMETHYLAMMONIUMCHLORIDE
Reaxys-RN3917255
Chemical Name Translation苄基三甲基氯化铵
Wiswesser Line Notation1K1&1&1R &G
LabNetwork Molecule IDLN00183078
Canonical SMILESC[N+](C)(C)CC1=CC=CC=C1.[Cl-]
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分类

  • {SNA} Ammonium Salts, Chemical Synthesis, Phase Transfer Catalysts, Synthetic Reagents
  • {Chemicalbook} 化工助剂: 工业表面活性剂: 阳离子表面活性剂

产品应用

  • 测定铂、钯、汞和金。有机合成。纤维素。溶剂。乳化剂。阻聚剂。

相关文献及参考

  • Beilstein:12,1020

安全信息

Signal word Danger
GHS Symbol
WGK Germany2
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P310+P330
  • P302+P350
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
RTECSBO8400000
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard statements
  • H301 Toxic if swallowed 吞食有毒
  • H315 Causes skin irritation 会刺激皮肤
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Hazard Codes 6.1 Xn Xn,Xi
Warnings IRRITANT
UN Number 2811 UN 2811 6.1/PG 3
Packing GroupIII
Hazard Class6.1 
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 250 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NCNSA6 National Academy of Sciences, National Research Council,
   Chemical-Biological Coordination Center, Review.  (Washington, DC)
   Volume(issue)/page/year: 5,39,1953

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1600 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPMSAE Journal of Pharmaceutical Sciences.  (American Pharmaceutical Assoc.,
   2215 Constitution Ave., NW, Washington, DC 20037)  V.50-    1961-
   Volume(issue)/page/year: 69,327,1980

其他信息

  • {Chemical
  • TCI Shanghai:苄基三甲基氯化铵 Benzyltrimethylammonium Chloride,>;99.0%(T)(56-93-9)
  • MOL 文件:56-93-9.mol
  • 苄基三乙基氯化铵价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30195826 苄基三乙基氯化铵;氯化苄基三乙铵;三乙基苄基氯化铵 100g 58.5元 2011/04/16 B0444 苄基三乙基氯化铵 Benzyltriethylammonium Chloride 25G 177元 2011/04/16 B0444 苄基三乙基氯化铵 Benzyltriethylammonium Chloride 500G 997元
  • 下游产品:4-(4-氨基苯基)吗啡啉-3-酮 --> 4-溴甲基四氢吡喃 --> 2,5-二氨基-4,6-二氯嘧啶 --> 毒死蜱 --> 2-乙氧基苯甲酸 --> 2-氨基-4-戊炔腈 --> 1-氨基环丙基甲腈 --> 6-溴-2H-1,4-苯并噁嗪-3(4H)-酮 --> 6,6'-二甲基-2,2'-联吡啶 --> 2,2-二氯-1-甲基环丙胺 --> 氯氰菊酯 --> 1-(3-三氟甲基苯基)哌嗪 --> 松脂醇 --> 甲基毒死蜱 --> 二碘甲烷 --> 4-溴-3-甲基乙酰苯胺 --> N,N-二甲基丙烯基脲 --> 毒鼠磷 --> 氯辛硫磷 --> 1-(2-甲氧苯基)哌嗪 --> 异氰酸叔丁酯 --> 分散紫 26 --> 2-氨基-2,3-二甲基丁腈 --> O,O-(二-对氯苯基)硫代磷酰氯
  • 可燃性
  • 苄基三甲基氯化铵价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw060015 苄基三甲基氯化铵;三甲基苄基氯化铵 100g 85元 2011/08/23 xw060019 苄基三甲基氯化铵;三甲基苄基氯化铵 500g 300元 2011/04/16 B0447 苄基三甲基氯化铵 Benzyltrimethylammonium Chloride 25G 187元
  • {Ch
  • 灭火剂:干粉,泡沫,沙土,二氧化碳, 雾状水
  • 上游原料:苄基氯 --> 三甲胺
  • 图谱信息:苄基三乙基氯化铵(56-37-1)核磁图( 1 HNMR) 苄基三乙基氯化铵(56-37-1)红外图谱(IR1) 苄基三乙基氯化铵(5
  • 用途一:用作医药中间体及相转移催化剂
  • 方法一:将氯化苄、三甲胺和甲醇的混合物回流反应4h，蒸除甲醇得到粗品，经乙醇重结晶得苄基三甲基氯化铵成品，产率88%。
  • MSDS 信息:BTM(56-93-9).msds
  • F:3
  • 方法二:将氯化苄、三乙胺、丙酮加入反应锅，在63-64℃回流8小时。缓缓降至15℃，过滤，滤饼用丙酮
  • 用途三:烷基化反应催化剂。有机合成相转移催化剂。通过相转移催化迈克尔加成反应(Mechael addition)合成多取代环丙烷。
  • 有吸湿性。低于135℃时稳定，135℃以上分解为氯化苄和三甲胺。易溶于水、乙醇、热苯和丁醇，微溶于苯二甲酸二丁酯和磷酸三丁酯，不溶于乙醚。有刺激性。
  • 图谱信息:苄基三甲基氯化铵(56-93-9)红外图谱(IR1) 苄基三甲基氯化铵(56-93-9)红外图谱(IR2) 苄基三甲基氯化铵(56-93-9)核磁图( 13 CNMR) 苄基三甲基氯化铵(56-93-9)Raman光谱 苄基三甲基氯化铵(56-93-9)质谱(MS)
  • 敏感性:Hygroscopic
  • Sigma Aldri
  • 用途一:用于测定铂、钯、汞和金，用作乳化剂和阻聚剂。
  • 类别:有毒物品
  • 类别:农药
  • 用途二:用作医药中间体及相转移催化剂
  • 用途四:测定铂、钯、汞和金。有机合成。纤维素。溶剂。乳化剂。阻聚剂。
  • 储运特性:低温通风干燥; 与库房食品原料分开存放

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Phase Transfer Catalysts 相转移催化剂
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Phase Transfer Catalysts 相转移催化剂
  4. Ammonium Salts - Phase Transfer Catalysts
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Phase Transfer Catalysts 相转移催化剂
  4. Ammonium Salts - Phase Transfer Catalysts
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Amine Salts - Nitrogen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Quaternary Ammonium Compounds 季铵化合物
  1. Functional Group 官能团索引
  2. quaternary ammonium salt