Ethion 乙硫磷

CAS 563-12-2 MFCD00036232

化学结构图

563-12-2
SMILES: CCOP(=S)(OCC)SCSP(=S)(OCC)OCC

化学属性

Mol. FormulaC9H22O4P2S4
Mol. Weight384.48
Solubility微溶于水，溶于氯仿、苯、二甲苯，易溶于丙酮、甲醇、乙醇。
Density0.7915
Refractive index1.5490
Stability对光敏感
Boiling Point164-165°C
Melting Point-13°C

别名和识别编码

Chemical NameEthion
MDL NumberMFCD00036232
PubChem Substance ID3286
Beilstein Registry Number1804530
CAS Number563-12-2
EC Number209-242-3
Synonym Ethion powder,wettable powder granules(content2%-25%) 1240蚜螨立死 { 爱杀松 Methylene-S,S'-bis(O,O-diaethyl-dithiophosphat) 益赛昂,S,S'-亚甲基-O,O,O',O'-四乙基双( O,O,O,O-Tetraethyl S,S-methylenedi(phosphorodithioate) S,S'-Methylen-bis(O,O-d ENT 24,105 Ethion Bis(S-(diethoxyphosphinothioyl)mercapto)methane NIA 1240 S,S'-METHYLENE BIS[O,O-DIETHYL PHOSPHORODITHIOATE] Nialate 双[S-(二乙氧基膦基硫)硫醇]甲烷 益赛昂 ETHION Et CETHION 乙硫磷;益赛昂;S,S'-亚甲基-O,O,O',O'-四乙基双(二硫代磷酸酯) Phosphorodithioic acid, O,O-diethyl ester, S,S-diester with Embathion 蚜螨 益赛昂,S,S'-亚甲基-O,O,O',O'-四乙基双(二硫代磷酸酯） NIAGARA 1240(R) S,S'-Methylene O,O,O',O'-tetraethyl phosphorodithioate NIALATE(R) CEKUETION 一二四零 Methyleen-S,S'-bis(O,O-diethyl-dithiofosfaat) Fosfono 50 'LGC' (1212) Diethion 乙赛昂 Hylemox 一二四0 亚甲基二磷酸二硫代四乙酯 蚜螨立死 ETHYL METHYLENE PHOSPHORODITHIOATE O,O`,O``,O```-四乙基-S,S`-亚甲基双(二硫代磷酸酯) Ethion emulsion(content0.5%-25%) Niagara 1240 灭蟑灵 乙硫磷粉剂、可湿性粉剂、颗粒剂[含量2%～25%] Fosfatox E CETHION(R) 昂杀拉 O,O,O',O'-TETRAETHYL S,S'-METHYLENE DI(PHOSPHORODITHIOATE) ETHIOL Etilon S,S’-亚甲基-O,O,O’,O’-四乙基双(二硫代磷酸酯) NIA 1240(R) O,O,O',O'-四乙基-S,S'-亚甲基双(二硫代磷酸酯) 乙硫磷乳剂[含量0.5%～25%] DHANUMIT 双(O,O-二乙基二硫代磷酸基)甲烷 Ethyl methylene phosphorodithioate
Chemical Name Translation乙硫磷
Merck Number13,3772
Wiswesser Line Notation2OPS&O2&S1SPS&O2&O2
InChIInChI=1S/C9H22O4P2S4/c1-5-10-14(16,11-6-2)18-9-19-15(17,12-7-3)13-8-4/h5-9H2,1-4H3
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分类

  • Acaricides, Alpha sort, Alphabetic, Analytical Standards, Analytical/Chromatography, Chromatography, E, E-G, EQ - EZ, Environmental Standards, Insecticides, Organophorous, Pesticides, Pesticides & Metabolites
  • {SNA} Acaricides, Alphabetic, Analytical Standards, Analytical/Chromatography, Chromatography, E, EQ - EZ, Environmental Standards, Insecticides, Organophorous, Pesticides & Metabolites, Pesticides Standards

产品应用

  • 主要用于防治棉花红蜘蛛的在、幼虫及卵，柑桔红蜘蛛、锈壁虱的成、幼虫及卵，棉花的棉叶蝉等。辄可用于防治棉花象鼻虫，果树、蔬菜、小麦、豆科、饲料作用等螨类害虫。对棉花蚜虫亦有效。
  • 校准仪器和装置；评价方法；工作标准；质量保证/质量控制；其他。

相关文献及参考

  • Merck:13,3772

安全信息

RTECSTE4550000
GHS Symbol
Precautionary statements
  • P301+P310
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P301+P310+P330
  • P302+P352+P312
Hazard statements
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H312 Harmful in contact with skin 皮肤接触有害
  • H301 Toxic if swallowed 吞食有毒
Hazard Codes T,N T;N
WGK Germany3
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Signal word Danger
Safety Statements
  • S25 Avoid contact with eyes 避免眼睛接触；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Risk Statements
  • R25 Toxic if swallowed 吞咽有毒
  • R21 Harmful in contact with skin 与皮肤接触有害
  • R50/53
UN Number 2810 3018
Storage condition 玻璃安瓿瓶包装，冷藏和避光条件下保存。 0-6°C 储存温度2-8℃
Restrict 剧毒化学品
Warnings 危化品目录(2015) 危险化学品 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 26 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PSEBAA Proceedings of the Society for Experimental Biology and Medicine.
   (Academic Press, Inc., 1 E. First St., Duluth, MN 55802)  V.1-    1903/04-
   Volume(issue)/page/year: 129,699,1968

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 40 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85DPAN "Wirksubstanzen der Pflanzenschutz und Schadlingsbekampfungsmittel,"
   Perkow, W., Berlin, Verlag Paul Parey, 1971-1976  Volume(issue)/page/year:
   -,-,1971/1976

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 13 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PHJOAV Pharmaceutical Journal.  (Pharmaceutical Soc. of Great Britain, 1
   Lambeth High St., London, SE1 7JN, UK)  V.131-    1933-
   Volume(issue)/page/year: 185,361,1960

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 915 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85DPAN "Wirksubstanzen der Pflanzenschutz und Schadlingsbekampfungsmittel,"
   Perkow, W., Berlin, Verlag Paul Parey, 1971-1976  Volume(issue)/page/year:
   -,-,1971/1976

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROU

其他信息

  • MOL 文件:563-12-2.mol
  • 外观性质:纯品为白色至琥珀色油状液体, 工业品为油状液体, 有恶臭。
  • 用途:主要用于防治棉花红蜘蛛的在、幼虫及卵，柑桔红蜘蛛、锈壁虱的成、幼虫及卵，棉花的棉叶蝉等。辄可用于防治棉花象鼻虫，果树、蔬菜、小麦、豆科、饲料作用等螨类害虫。对棉花蚜虫亦有效。
  • 图谱信息:乙硫磷(563-12-2)红外图谱(IR1) 乙硫磷(563-12-2)核磁图( 1 HNMR) 乙硫磷(563-12-2)核磁图( 13 CNMR) 乙硫磷(563-12-2)质谱(MS)
  • 杀虫剂单一组分标准液
  • HazardClass:6.1(a)
  • 生产方法:由O，O-二乙基二硫代磷酸酯用碳酸氢钠转变为钠盐后，与二氯甲烷反应制得乙硫磷。将钠盐、碳酸氢钠、氢氧化钠投入反应锅，加料量一般为每500g 60%的钠盐加碳酸氢钠5g，氢氧化钠的用量使料液的pH值调节到7为限。再按钠盐：二氯甲烷=1：0.7（摩尔比）投入二氯甲烷。向反应锅充入氮气，使锅内保持0.2-0.4MPa压力。升温至100-110℃，反应5-8h，反应压力为1-1.5MPa。反应完成后，冷却至35℃。将合成的原油滤去少量滤渣后，静置分层，取油层用水洗涤三次。减压脱水可得90%左右的乙硫磷原油。收率70%以上。
  • PackingGroup:II
  • RTECS号:TE4550000
  • 有恶臭。微溶于水，溶于二甲苯、氯仿、苯，易溶于丙酮、甲醇、乙醇。

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Environmental Standards - Chromatography
  5. Pesticides & Metabolites - Environmental Standards
  6. Pesticides - Pesticides & Metabolites
  7. Acaricides - Pesticides
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Environmental Standards - Chromatography
  5. Pesticides & Metabolites - Environmental Standards
  6. Pesticides - Pesticides & Metabolites
  7. Insecticides - Pesticides
  8. Organophorous - Insecticides
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Environmental Standards - Chromatography
  5. Pesticides & Metabolites - Environmental Standards
  6. Alpha sort - Pesticides & Metabolites
  7. E-G - Alpha sort

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