Pararosaniline hydrochloride 碱性红 9

CAS 569-61-9 MFCD00001657

化学结构图

569-61-9
SMILES: Cl.N=C1C=CC(=C(c2ccc(N)cc2)c2ccc(N)cc2)C=C1

化学属性

Mol. FormulaC19H18ClN3
Mol. Weight323.82
Melting Point250 °C
TSCAYes
Solubility10 G/L (25 ºC)
Flash Point>;230 °F
Boiling Point479.57 °C at 760 mmHg
Refractive indexn20/D 1.334
Density0.999 g/mL at 20 °C
Appearance liquid

别名和识别编码

Chemical NameBasic Red 9
Synonym Pararosaniline (hydrochloride) {LY} Pararosaniline (hydrochloride) alpha-(4-aminophenyl)-alpha-(4-imino-2,5-cyclohexadien-1-ylidene)-4-toluidine monohydrochloride hexazonium pararosaniline pararosaniline pararosaniline monoacetate pararosaniline monohydrochloride pararosaniline monohydroiodide pararosaniline mononitrate pararosaniline monoperchlorate pararosaniline phosphate (3:1) pararosaniline sulfate (2:1) {} {LY} Pararosaniline (hydrochloride) {} {} {LY} Pararosaniline (hydrochloride) {} {} {} {LY} Pararosaniline (hydrochloride) {} {} {} {} {LY} Pararosaniline (hydrochloride) {} {} {} {} {} {LY} Pararosaniline (hydrochloride) {} {} {} {} {} {} {LY} Pararosaniline (hydrochloride) {} {} {} {} {} {} {} {LY} Pararosaniline (hydrochloride) {} {} {} {} {} {} {} {} {LY} Pararosaniline (hydrochloride) {} {} {} {} {} {} {} {} {} {LY} Pararosaniline (hydrochloride)
MDL NumberMFCD00001657
CAS Number569-61-9
Beilstein Registry Number4164603
PubChem Substance ID11292
EC Number209-321-2
Reaxys-RN4164603
Chemical Name Translation碱性红 9
Merck Number14,5652
Wiswesser Line NotationL6Y DHJ AUM DYR DZ&R DZ
LabNetwork Molecule IDLN00193561
InChIInChI=1S/C19H17N3.ClH/c20-16-7-1-13(2-8-16)19(14-3-9-17(21)10-4-14)15-5-11-18(22)12-6-15;/h1-12,20H,21-22H2;1H
Canonical SMILESN=C(C=C/1)C=CC1=C(C2=CC=C(N)C=C2)\C3=CC=C(N)C=C3.Cl
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
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分类

  • {SNA} P, Stains & Dyes, A to Z, Stains and Dyes, 细胞生物学, 血液学和组织学
  • {SNA} Additional Standards, All alphabetical sorted, Analytical Standards, Chromatography, Colorant Standards, Colors, Food and Cosmetic Component Standards, 分析/色谱
  • {SNA} Certified Stains & Dyes,

产品应用

  • 生物染色

相关文献及参考

  • Short: III/20a
  • Short: EINECS
  • Beilstein: 13,IV,2283

安全信息

Hazard statements
  • H303 May be harmfully swallowed 吞食可能有害
  • H350 May cause cancer 可能致癌
RTECSCX9850100
GHS Symbol
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P203
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P301+P317
  • P308+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P318
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
WGK Germany3
Personal Protective Equipment Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Signal word
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S53 Avoid exposure - obtain special instructions before use 避免接触,使用前获得特别指示说明;
Risk Statements
  • R11 Highly flammable 非常易燃
  • R45 May cause cancer 可能致癌
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Hazard Codes T F,T,Xn Xn,Xi F,Xn
Storage condition RT, sealed storage, away from moisture and light {LY} RT, sealed storage, away from moisture and light Store at RT. {} {LY} RT, sealed storage, away from moisture and light {} {} {LY} RT, sealed storage, away from moisture and light {} {} {} {LY} RT, sealed storage, away from moisture and light {} {} {} {} {LY} RT, sealed storage, away from moisture and light {} {} {} {} {} {LY} RT, sealed storage, away from moisture and light {} {} {} {} {} {} {LY} RT, sealed storage, away from moisture and light {} {} {} {} {} {} {} {LY} RT, sealed storage, away from moisture and light {} {} {} {} {} {} {} {} {LY} RT, sealed storage, away from moisture and light {} {} {} {} {} {} {} {} {} {LY} RT, sealed storage, away from moisture and light {} {} {} {} {} {} {} {} {} {} {LY} RT, sealed storage, away from moisture and light {} {} {} {} {} {} {} {} {} {} {} {LY} RT, sealed storage, away from moisture and light {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, sealed stor
UN Number UN 2924 3/PG 2
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 728 mg/kg/2Y-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Liver - tumors
   Endocrine - thyroid tumors
REFERENCE :
   NTPTR* National Toxicology Program Technical Report Series.  (Research
   Triangle Park, NC 27709) No.206-  Volume(issue)/page/year: NTP-TR-285,1986

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1714 mg/kg/43W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Tumorigenic - tumors at site of application
REFERENCE :
   NATWAY Naturwissenschaften.  (Springer-Verlag, Heidelberger Platz 3, D-1000
   Berlin 33, Fed. Rep. Ger.)  V.1-    1913-  Volume(issue)/page/year:
   43,543,1956

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 364 mg/kg/2Y-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Liver - tumors
   Endocrine - adrenal cortex tumors
REFERENCE :
   NTPTR* National Toxicology Program Technical Report Series.  (Research
   Triangle Park, NC 27709) No.206-  Volume(issue)/page/year: NTP-TR-285,1986

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 5 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FAZMAE Fortschritte der Arzneimittelforschung.  Progress in Drug Research.
   (Birkhauser Boston, Inc., c/o Springer-Verlag New York, 44 Hartz Way,
   Secaucus, NJ 07094)  V.1-    1959-  Volume(issue)/page/year: 17,108,1973

TYPE OF TEST            : Body fluid assay
TEST SYSTEM             : Rodent - rat Bacteria - Salmonella typhimurium
DOSE/DURATION           : 1680 mg/kg/2W (Continuous)
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 9,69,1987

TYPE OF TEST            : DNA adduct
TEST SYSTEM             : Mammal - species unspecified Lymphocyte
DOSE/DURATION           : 10 pph
REFERENCE :
   BIPMAA Biopolymers.  (John Wiley & Sons, Inc., 605 Third Ave., New York, NY
   10158)  V.1-    1963-  Volume(issue)/page/year: 11,2537,1972

TYPE OF TEST            : DNA inhibition
TEST SYSTEM             : Human HeLa cell
DOSE/DURATION           : 300 umol/L
REFERENCE :
   CRNGDP Carcinogenesis (London). (Oxford Univ. Press, Pinkhill House,
   Southfield Road, Eynsham, Oxford OX8 1JJ, UK)  V.1-    1980-
   Volume(issue)/page/year: 13,2389,1992

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Rodent - mouse Lymphocyte
DOSE/DURATION           : 41 mg/L
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/

TYPE OF TEST            : Morphological transformation
TEST SYSTEM             : Rodent - rat Embryo
DOSE/DURATION           : 1400 ug/L
REFERENCE :
   JJIND8 JNCI, Journal of the National Cancer Institute.  (Washington, DC)
   V.61-79, 1978-87. For publisher information, see JNCIEQ.
   Volume(issue)/page/year: 67,1303,1981

TYPE OF TEST            : Morphological transformation
TEST SYSTEM             : Rodent - mouse Fibroblast
DOSE/DURATION           : 8 ug/L
REFERENCE :
   JJIND8 JNCI, Journal of the National Cancer Institute.  (Washington, DC)
   V.61-79, 1978-87. For publisher information, see JNCIEQ.
   Volume(issue)/page/year: 67,1303,1981

其他信息

  • 用途三:香料。主要用于配制水果型香精。增塑剂(用于包装材料)。
  • Acros Organic
  • 可燃性危险特性:遇明火、高温、强氧化剂可燃;燃烧产生刺激烟雾
  • 人工染料:即苯胺染料或煤焦油染料
  • 毒性分级:低毒
  • 碱性红 9价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 71031160 盐酸付玫瑰苯胺(副品红) 25g 58元 2011/08/23 71031144 盐酸付玫瑰苯胺 25g 58元 2011/08/23 71031183 盐酸付玫瑰苯胺 10g 199元
  • MOL 文件:569-61-9.mol
  • 职业标准:STEL 10 毫克/ 立方米
  • 用途一:用作合成橡胶的耐寒增塑剂
  • {Chemi
  • 易溶于乙醇呈绯红色,热水呈红色,微溶于冷水,不溶于乙醚。在浓硫酸中呈黄光棕色,稀释后呈紫红色。曾有实验动物致癌试验阳性的报道。Colour Index Number 42500
  • TCI Shanghai:癸二酸
  • 图谱信息:癸二酸二丁酯(109-43-3)Raman光谱 癸二酸二丁酯(109-43-3)红外图谱(IR2) 癸二酸二丁酯(109-43-3)质谱(MS) 癸二酸二丁酯(109-43-3)核磁图( 13 CNMR) 癸二酸二丁酯(109-43-3)红外图谱(IR1) 癸二酸二
  • 色指数:42500
  • 碱性品红价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 71019644 碱性品红;盐基品红;碱性新品红;玫瑰苯胺盐酸盐 25g 21元 2011/08/23 71019644 碱性品红;盐基品红;碱性新品红;玫瑰苯胺盐酸盐 25g 21元 2010/06/21 401695000 碱性品红 Basic Fuchsin , pure, certified 500 GR 5262元
  • {Chemicalb
  • 癸二酸二丁酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30055228 癸二酸二丁酯 500ml 55.5元 2011/08/23 40012961 癸二酸二丁酯 25ml 36元 2011/04/16 S0023 癸二酸二丁酯 Dibutyl Sebacate 25ML 124元
  • 图谱信息:碱性红 9(569-61-9)红外图谱(IR1)
  • 上游原料:叔丁醇 --> 浓盐酸 --> 蓖麻油 --> 皮脂酸 --> 癸二酰氯
  • 稳定性:Stable. Incompatible with strong oxidizing agents.
  • 海关编码:29171390
  • 类别:易燃液体
  • 储运特性:包装完整、轻装轻放; 库房通风、远离明火、高温、与氧化剂分开存放
  • 用途:主要用于棉、腈纶、蚕丝、皮革等的染色,也可用于纸张、羽毛、麦杆、木等的着色,还可用于制造色淀
  • 方法二:由癸二酸与丁醇在硫酸催化下酯化而得。催化剂的用量为0.3%,温度为130-140℃,常压下酯化约4-6h,酯化时加入0.1-0.3%活性炭。所得粗酯经中和、脱醇、压滤即得成品。原料癸二酸由蓖麻油制得。原料消耗(kg/t)癸二酸 665丁醇 525
  • 外观性质:无色或淡黄色透明液体。
  • Sigma Aldrich:109-43-3(sigmaaldrich)
  • EPA化学物质信息:Benzenamine, 4-[(4-aminophenyl)(4-imino- 2,5
  • 图谱信息:碱性品红(632-99-5)红外图谱(IR2) 碱性品红(632-99-5)红外图谱(IR1)
  • Alfa Aesar:癸二酸二正丁酯,94% Di-n-butyl sebacate, 94%(109-43-3)

系列性分类


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