2,6-Dinitrophenol 2,6-二硝基苯酚(易制爆)

CAS 573-56-8 MFCD00024235

化学结构图

573-56-8
SMILES: O=[N+]([O-])c1cccc([N+](=O)[O-])c1O

化学属性

Mol. FormulaC6H4N2O5
Mol. Weight184.12
Melting Point61-63° (dry)
TSCANo
Vapor Density6.35 (vs air)
Appearance 淡黄色结晶。熔点63-64℃。溶于沸醇、醚和氯仿,微溶于热水及冷醇。

别名和识别编码

Chemical Name2,6-Dinitrophenol
Synonym β-二硝基苯酚 1-Hydroxy-2,6-dinitrobenzol 2 6-DINITROPHENOL OEKANAL & 2,5-dinitrophenol 2,6-DINITROPHENOL 2,6-DNP 2,6-Dinitrofenol 2,6-Dinitrophenol 2,6-Dinitrophenol (wetted with ca. 20% Water, containing 5g on a dry weight basis) 2,6-Dinitrophenol 10 µg/mL in Acetonitrile 2,6-dinitrophenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
MDL NumberMFCD00024235
EC Number209-357-9
CAS Number573-56-8
Merck Number14,3282
Beilstein Registry Number1913410
PubChem Substance ID11312
Chemical Name Translation2,6-二硝基苯酚(易制爆)
Wiswesser Line NotationWNR BQ CNW
InChIInChI=1S/C6H4N2O5/c9-6-4(7(10)11)2-1-3-5(6)8(12)13/h1-3,9H
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; alcohol; 1fragment
  • {SNA} Building Blocks, C6 to C8, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Phenols

相关文献及参考

  • Short: III/35D2 Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Carbon-13, Part 2: Aromatic Compounds Author: Mikhova, B. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35D2 Year: 2005 Keyword: aromatic compounds; carbon-13; chemical shift; coupling constant; molecular structure ISBN: 978-3-540-20189-2 ISBN: 3-540-20189-0 Internet Resource: DOI:10.1007/b83345 RefComment: VIII, 291 p., Hardcover RefComment: Written for Science and engineers in the fields of physics, chemistry and physical chemistry who inted to use NMR to study the structure and the binding of molecules Abstract: Nuclear Magnetic Resonance (NMR) is based on the fact that certain nuclei exhibit a magnetic moment, orient by a magnetic field, and absorb characteristic frequencies in the radiofrequency part of the spectrum. The spectral lines of the nuclei are highly influenced by the chemical environment i.e. the structure and interaction of the molecules. NMR is now the leading technique and a powerful tool for the investigation of the structure and interaction of molecules. The present Landolt-Börnstein volume III/35 Nuclear Magnetic Resonance (NMR) Data is therefore of major interest to all scientists and engineers who intend to use NMR to study the structure and the binding of molecules. Volume III/35 "NMR-Data" is divided into several subvolumes and parts. Subvolume III/35A contains the nuclei 11B and 31P, subvolume III/35B contains the nuclei 19F and 15N, subvolume III/35C contains the nucleus 1H, subvolume III/35D contains the nucleus 13C, subvolume III/35E contains the nucleus 17O, and subvolume III/35G contains the nucleus 77Se. More nuclei will be presented later.
  • Short: III/5a Title: Structure Data of Organic Crystals: C ... C 13 Author: Schudt, E.; Weitz, G. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/5a Year: 1971 ISBN: 3-540-05177-5 ISBN: 978-3-540-

安全信息

RTECSSL2975000
Safety Statements
  • S37 Wear suitable gloves 戴适当手套;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
Packing GroupⅠ
UN Number 1320 UN 1320 4.1/PG 1 UN1320
Risk Statements
  • R33 Danger of cumulative effects 有累积作用的危险
  • R51/53
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
  • R50/53
Hazard Codes T,N T;N
GHS Symbol
WGK Germany3
Hazard statements
  • H228 Flammable solid 易燃固体
  • H301 Toxic if swallowed 吞食有毒
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H330 Fatal if inhaled 吸入致命
  • H331 Toxic if inhaled 吸入中毒
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P230 Keep wetted with … 保持湿润
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P250 Do not subject to grinding/shock/…/friction. 不要受研磨/冲击/....../摩擦。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛,皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P310
  • P301+P316
  • P302+P352
  • P304+P340
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医,如果你觉得不舒服
  • P316
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P361+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P380
  • P372 Explosion risk in case of fire. 在火中有灾爆炸的危险。
  • P373 DO NOT fight fire when fire reaches explosives. 火烧到爆炸物时,切勿救火。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P401 Store… 存储
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Hazard Class4.1
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 38 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPPMAB Journal of Pharmacy and Pharmacology.  (Pharmaceutical Soc. of Great
   Britain, 1 Lambeth High St., London SEI 7JN, UK)  V.1-    1949-
   Volume(issue)/page/year: 11,462,1959

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intramuscular
SPECIES OBSERVED        : Bird - pigeon
DOSE/DURATION           : 40 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/year: 49,187,1933

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 45 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPPMAB Journal of Pharmacy and Pharmacology.  (Pharmaceutical Soc. of Great
   Britain, 1 Lambeth High St., London SEI 7JN, UK)  V.1-    1949-
   Volume(issue)/page/year: 11,462,1959

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Mammal - dog
DOSE/DURATION           : 50 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPPMAB Journal of Pharmacy and Pharmacology.  (Pharmaceutical Soc. of Great
   Britain, 1 Lambeth High St., London SEI 7JN, UK)  V.1-    1949-
   Volume(issue)/page/year: 11,462,1959

Restrict 易制爆

其他信息

  • 蒸气密度:6.35 (vs air)
  • 方法一:由邻硝基苯酚经硝化而得。将邻硝基苯酚、冰醋酸、浓硫酸和硝酸配成的反应混合物在55-60℃搅拌反应半小时。反应毕,将硝化物倒入冰水中析出结晶,过滤、干燥即得粗制品。将粗品溶于氢氧化钠溶液中,加热至80℃,加入氯化钡溶液。冷至35℃,过滤,用水洗涤黄色的钡盐结晶。将钡盐加入碳酸钠溶液中,热至80℃再加入氯化钡溶液,冷至35℃,滤出第二次钡盐。将其又一次加入碳酸钠溶液中,加热至70-80℃,过滤,滤液用18%盐酸酸化至pH为1,即得到2,6-二硝基苯酚。
  • 上游原料:氯化钡 --> 2-硝基苯酚 --> 硝化物
  • 用途一:用于有机合成,用作酸碱指示剂的变色范围是pH为2.4(无色)-4.0(黄色)。
  • TCI Shanghai:2,6-二硝基苯酚(加约20%水湿润,本品干重约为5g) 2,6-Dinitrophenol (wetted with ca. 20% Water, containing 5g on a dry weight basis),>;98.0%(LC)(573-56-8)
  • 2,6-二硝基苯酚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D0842 2,6-二硝基苯酚(加约20%水湿润,本品干重约为5g) 2,6-Dinitrophenol (wetted with ca. 20% Water, containing 5g on a dry weight basis) 5G 1650元 2010/05/25 A19664 2,6-二硝基苯酚, 97%, stab. with ca 20% water 2,6-Dinitrophenol, 97%, stab. with ca 20% water 5g 1414元 2010/05/25 A19664 2,6-二硝基苯酚, 97%, stab. with ca 20% water 2,6-Dinitrophenol, 97%, stab. with ca 20% water 25g 5614元
  • Sigma Aldrich:573-56-8(sigmaaldrich)
  • MOL 文件:573-56-8.mol
  • 图谱信息:2,6-二硝基苯酚(573-56-8)质谱(MS) 2,6-二硝基苯酚(573-56-8)核磁图( 13 CNMR) 2,6-二硝基苯酚(573-56-8)核磁图( 1 HNMR) 2,6-二硝基苯酚(573-56-8)红外图谱(IR2) 2,6-二硝基苯酚(573-56-8)Raman光谱 2,6-二硝基苯酚(573-56-8)红外图谱(IR1)
  • Alfa Aesar:2,6-二硝基苯酚,97%,stab.withca20%water 2,6-Dinitrophenol, 97%, stab. with ca 20% water(573-56-8)

系列性分类


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