2,6-Diethylaniline 2,6-二乙基苯胺

CAS 579-66-8 MFCD00007753

化学结构图

579-66-8
SMILES: CCc1cccc(CC)c1N

化学属性

Mol. FormulaC10H15N
Mol. Weight149.24
Refractive index1.5450 to 1.5480
Boiling Point243°C at 760 mmHg
Density0.906
Vapor Pressure0.02 mmHg ( 20 °C)
Flash Point115°C
TSCAYes
Melting Point3-4°C
Stability对光敏感

别名和识别编码

Chemical Name2,6-Diethylaniline
Synonym 2,6-Diethylaniline {LY} 2,6-Diethylaniline {} {LY} 2,6-Diethylaniline {} {} {LY} 2,6-Diethylaniline {} {} {} {LY} 2,6-Diethylaniline {} {} {} {} {LY} 2,6-Diethylaniline {} {} {} {} {} {LY} 2,6-Diethylaniline {} {} {} {} {} {} {LY} 2,6-Diethylaniline {} {} {} {} {} {} {} {LY} 2,6-Diethylaniline {} {} {} {} {} {} {} {} {LY} 2,6-Diethylaniline {} {} {} {} {} {} {} {} {} {LY} 2,6-Diethylaniline {} {} {} {} {} {} {} {} {} {} {LY} 2,6-Diethylaniline {} {} {} {} {} {} {} {} {} {} {} {LY} 2,6-Diethylaniline {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,6-Diethylaniline {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,6-Diethylaniline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,6-Diethylaniline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,6-Diethylaniline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,6-Diethylaniline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
CAS Number579-66-8
PubChem Substance ID87567148
EC Number209-445-7
Beilstein Registry Number1423626
MDL NumberMFCD00007753
Reaxys-RN1423626
Chemical Name Translation2,6-二乙基苯胺
Wiswesser Line NotationZR B2 F2
LabNetwork Molecule IDLN00223447
InChIInChI=1S/C10H15N/c1-3-8-6-5-7-9(4-2)10(8)11/h5-7H,3-4,11H2,1-2H3
Canonical SMILESNC1=C(CC)C=CC=C1CC
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分类

  • {Chemicalbook} 农药中间体: 除草剂中间体: 酰胺类除草剂
  • {SNA} Alphabetical Index of Analytical Standards, Amines, Analytical Standards, Analytical/Chromatography, Aromatics, Chemical Class, Chromatography, D, DID - DIN, Environmental Standards, 农残和代谢标准品, 按照字母排序
  • {SNA} Alphabetical Index of Analytical Standards, Amines, Analytical Standards, Aromatics, Chemical Class, Chromatography, D, DID - DIN, Environmental Standards, 农残和代谢标准品, 分析/色谱, 按照字母排序
  • {SNA} Amines, B

产品应用

  • 2,6-二乙基苯胺是生产除草剂甲草胺、丙草胺和丁草胺的关键原料，也可用于合成染料、抗氧剂、环氧树脂固化剂等。

相关文献及参考

  • Short: IV/18B
  • Short: EINECS
  • Beilstein:12,164
  • Short: III/38B

安全信息

GHS Symbol
WGK Germany2
Hazard statements
  • H302 Harmful if swallowed 吞食有害
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes Xn
RTECSBX3500000
Signal word
Safety Statements
  • S24 Avoid contact with skin 避免皮肤接触；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
Precautionary statements
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P332+P313
  • P301+P312+P330
  • P302+P350
  • P337+P313
  • P308+P313
  • P302+P352+P332+P313+P362+P364
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P305+P351+P338+P337+P313
  • P405 Store locked up. 上锁保管。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {}
Packing GroupIII
Hazard Class6.1(b)
UN Number 2810 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1800 mg/kg
TOXIC EFFECTS :
   Liver - other changes
   Blood - changes in bone marrow (not otherwise specified)
   Blood - changes in spleen
REFERENCE :
   FAATDF Fundamental and Applied Toxicology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1981-  Volume(issue)/page/year:
   3,285,1983

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 250 ng/plate
REFERENCE :
   BECTA6 Bulletin of Environmental Contamination and Toxicology.
   (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ
   07094)  V.1-    1966-  Volume(issue)/page/year: 35,696,1985

其他信息

  • 用途二:2，6-二乙基苯胺是除草剂甲草胺、丁草胺和丙草胺的中间体。
  • MOL 文件:579-66-8.mol
  • TCI Shanghai:2,6-二乙基苯胺 2,6-Diethylaniline,>;98.0%(GC)(T)(579-66-8)
  • F:8-9-23
  • Acros Organics:2,6-二乙基苯胺 2,6-Diethylaniline, 99.5%(579-66-8)
  • 2,6-二乙基苯胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D0476 2,6-二乙基苯胺 2,6-Diethylaniline 500ML 759元 2014/06/02 D0476 2,6-二乙基苯胺 2,6-Diethylaniline 25ML 143元 2010/06/21 165220010 2,6-二乙基苯胺 2,6-Diethylaniline 98% 1 LT 1327元
  • Sigma Aldrich:579-66-8(sigmaaldrich)
  • 方法一:其制备方法是以苯胺为原料，与乙烯在催化剂存在下高压反应。
  • 下游产品:乙草胺 --> 甲草胺 --> 丁草胺 --> 乙草胺乳油 --> 异丙甲草胺 --> 丙草胺 --> 2,6-二甲基氯代乙酰苯胺
  • 用途四:2,6-二乙基苯胺是生产除草剂甲草胺、丙草胺和丁草胺的关键原料，也可用于合成染料、抗氧剂、环氧树脂固化剂等。
  • MSDS 信息:2-Amino-1,3-diethylbenzene(579-66-8).msds
  • Alfa Aesar:2,6-二乙基苯胺,98% 2,6-Diethylaniline, 98%(579-66-8)
  • 方法二:由苯胺和乙烯在催化剂作用下经烷基化反应制得。生产流程有连续和间断两种。催化剂主要有三乙基铝、二乙基氯化铝、三氯化铝加铝粉和铝屑等。原料消耗定额：苯胺（≥99.6%）695kg/t、乙烯（≥99.9%）470kg/t、铝粉（≥99.7%）14.5kg/t、三氯化铝（≥99%）44kg/t、氢氧化钠溶液（42%）91kg/t、硫酸（93%）60kg/t。
  • 蒸气压:0.02 mm Hg ( 20 °C)
  • 上游原料:氨基苯 --> 铝 --> 氯化二乙基铝 --> 三乙基铝 --> 氯化铝(三氯化铝)
  • 图谱信息:2,6-二乙基苯胺(579-66-8)质谱(MS) 2,6-二乙基苯胺(579-66-8)红外图谱(IR1) 2,6-二乙基苯胺(579-66-8)核磁图( 13 CNMR) 2,6-二乙基苯胺(579-66-8)核磁图( 1 HNMR)
  • 用途一:是重要的农药、染料及医药中间体，是酰胺类除草剂甲草胺和丁草胺的原料
  • 用途三:该品是重要的有机合成中间体，用于制造染料、医药、香料和农药，其本身可代替四乙基铅作汽油抗爆剂。以2,6-二乙基苯胺为原料生产的除草剂甲草胺主要用于玉米、大豆和花生等作物防除杂草；也用来生产除草剂丁草胺，主要用于水稻田除草。这两种除草剂每公顷用量1-4kg，除草效果好，持效期长，是目前国际上性能较好，产量较大的新型除草剂。也可用于生产丙草胺，以及用于橡胶助剂及石油化工领域。
  • 敏感性:Air Sensitive

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. D - Alphabetic
  5. DID - DIN - D
  1. C10 - Amines
  1. C13 - Amines
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Amines 胺
  6. C8

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