(1-Bromoethyl)benzene (1-溴乙基)苯

CAS 585-71-7 MFCD00000139

化学结构图

585-71-7
SMILES: CC(Br)c1ccccc1

化学属性

Mol. FormulaC8H9Br
Mol. Weight185.06
Refractive index1.5580 to 1.5620
Boiling Point200°C(lit.)
Density1.356 g/mL at 25 °C(lit.)
Flash Point96°C(lit.)
TSCAYes
Melting Point-65°
Stability对热、光线和空气敏感

别名和识别编码

Chemical Name(1-Bromoethyl)benzene
Synonym alpha-Phenylethyl bromide (1-BROMOETHYL)BENZENE 1-phenethylbromide α-Methylbenzyl bromide 1-苯乙基溴 α-甲基溴苄 1-Bromo-1-phenylethane A-METHYLBENZYL BROMIDE Α-苯乙基溴 1-溴乙基苯;1-溴-1-苯基乙烷;1-苯乙基溴;α-甲基溴苄 α-甲基溴苄 ALPHA-METHYLBENZYL BROMIDE 1-溴-1-苯基乙烷 alpha-phenylethylbromide (1-溴乙基)苯 A-PHENYLETHYL BROMIDE (1-溴乙基)苯,97% AKOS BBS-00004012 A-溴乙基苯 1-Phenyl-1-bromoethane alpha-phenethylbromide a-溴乙基苯 (±)-1-bromo-1-phenyl-ethane alpha-Phenethyl bromide (1-bromoethyl)-benzen 1-溴乙基苯 ALPHA-BROMOETHYLBENZENE 1-PHENYLETHYL BROMIDE alpha-溴乙基苯 1-Phenethyl bromide alpha-Methylbenzyl bromide (1-Bromoethyl)benzene, 97% (alpha-Methybenzylbromide) (1-Bromoethyl)benzene,97% Α-甲基苄基溴
CAS Number585-71-7
PubChem Substance ID87563607
EC Number209-560-2
MDL NumberMFCD00000139
Beilstein Registry Number5,355
Chemical Name Translation(1-溴乙基)苯
Reaxys-RN507210
LabNetwork Molecule IDLN00334975
InChIInChI=1S/C8H9Br/c1-7(9)8-5-3-2-4-6-8/h2-7H,1H3
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分类

  • {SNA} Aryl, Building Blocks, C8, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
  • Aryl, Building Blocks, C8, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks

产品应用

  • A useful eight carbon intermediate.

相关文献及参考

  • Beilstein:5,355

安全信息

GHS Symbol
WGK Germany3
Hazard Codes Xi
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P302+P352+P332+P313+P362+P364
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P337+P313
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
  • S37 Wear suitable gloves 戴适当手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Moisture Sensitive 储存温度2-8℃,充氩保存 Refrigerator 0-10°C 0-10 避光保存

其他信息

  • TCI Shanghai:(1-溴乙基)苯 (1-Bromoethyl)benzene,>;95.0%(GC)(585-71-7)
  • 下游产品:1-(1-苯基乙基)哌嗪 --> Α-甲基苄基乙酸酯
  • Acros Organics:(1-溴乙基)苯 (1-Bromoethyl)benzene, 97%(585-71-7)
  • 图谱信息:(1-溴乙基)苯(585-71-7)质谱(MS) (1-溴乙基)苯(585-71-7)核磁图( 1 HNMR) (1-溴乙基)苯(585-71-7)核磁图( 13 CNMR) (1-溴乙基)苯(585-71-7)红外图谱(IR2) (1-溴乙基)苯(585-71-7)红外图谱(IR1)
  • Alfa Aesar:(1-溴乙基)苯,97% (1-Bromoethyl)benzene, 97%(585-71-7)
  • MOL 文件:585-71-7.mol
  • (1-Bromoethyl)benzene has been employed in controlled radical polymerization of styrene, in asymmetric esterification of benzoic acid in the presence of a chiral cyclic guanidine and as initiator in the synthesis of bromine terminated polyp-methoxystyrene and polystyrene via atom transfer radical polymerization.
  • (1-溴乙基)苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B0592 (1-溴乙基)苯 (1-Bromoethyl)benzene 500G 2420元 2014/06/02 B0592 (1-溴乙基)苯 (1-Bromoethyl)benzene 25G 288元 2010/06/21 218391000 (1-溴乙基)苯 (1-Bromoethyl)benzene 97% 100 GR 1001元
  • Sigma Aldrich:585-71-7(sigmaaldrich)
  • MSDS 信息:alpha-Methylbenzyl bromide(585-71-7).msds

系列性分类


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