5-Nitroacenaphthene (Contains 3-Nitroacenaphthene)

CAS 602-87-9 MFCD00014277

化学结构图

602-87-9
SMILES: O=[N+]([O-])c1ccc2c3c(cccc13)CC2

化学属性

Mol. FormulaC₁₂H₉NO₂
Mol. Weight199.21
Melting Point98-103°C
TSCAYes
Boiling Point-
Flash Point-
Solubility溶于醇、醚、油类、热水。

别名和识别编码

Chemical Name5-Nitroacenaphthene
Synonym 1,2-Dihydro-5-nitro-acenaphthylene 1,2-Dihydro-5-nitroacenaphthylene 1,2-dihydro-5-nitro-acenaphthylen 1,2-dihydro-5-nitroacenaphthylene 1,2-二氢-5-硝基苊 1,2-二氢-5-硝基苊,5-硝基苊 5-NITROACENAPHTHENE 5-Nan 5-Nitro-1,2-dihydroacenaphthylene 5-Nitroacenaphthene {} {} {} {} {} {Chemicalbook} Nitroacenaphthene {} {} {} {} {} {} {} {} {} {} {} {} {uni_hamburg} NCI-C01967 {} {} {} {} {} {} {} {uni_hamburg} Acenaphthylene, 1,2-dihydro-5-nitro- {} {} {} {} {} {} {} {} {uni_hamburg} Acenaphthene, 5-nitro- {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} 5-硝基苊 {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} 5-硝基二氢苊 {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} 5-nitronaphthaleneethylene {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {PubChem} 5-nitroacenaphthene
MDL Number-
CAS Number602-87-9
EC Number210-025-0
Beilstein Registry Number5(4)1840
PubChem Substance ID11769
Reaxys-RN1876864
Chemical Name Translation(Contains 3-Nitroacenaphthene)
Wiswesser Line NotationL566 1A LT&&J HNW
LabNetwork Molecule IDLN00248377
InChIInChI=1S/C12H9NO2/c14-13(15)11-7-6-9-5-4-8-2-1-3-10(11)12(8)9/h1-3,6-7H,4-5H2
Canonical SMILES-
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; alicycle; large ring; fused rings; 5ring; 6ring; 9ring; 10ring; 11ring; 1fragment
  • {SNA} Hematology and Histology, N, Stains & Dyes, A to Z, Stains and Dyes

产品应用

  • 该品是染料酸性高黄 FF；分散荧光黄等的中间体。也用作光刻胶增感剂。

相关文献及参考

  • Short: II/27B
  • Beilstein:5(4)1840
  • Short: III/35D2

安全信息

RTECSAB1060000
Safety Statements
Risk Statements
  • R45 May cause cancer 可能致癌
WGK Germany3
GHS Symbol
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P308+P313
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P501a
Hazard statements
  • H350 May cause cancer 可能致癌
  • H351 Suspected of causing cancer 怀疑致癌
Signal word
Personal Protective Equipment Eyeshields, Gloves, type P2 (EN 143) respirator cartridges
Hazard Codes T T,Xi
UN Number 2811
Packing GroupIII
Hazard Class6.1
Warnings 危化品目录(2015) 危险化学品 
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 3744 mg/kg/78W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Blood - leukemia
   Blood - lymphoma, including Hodg

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 120 gm/kg/17W-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Gastrointestinal - tumors
   Skin and Appendages - tumors
REFERENCE :
   TJIDAH Tokyo Jikeikai Ika Daigaku Zasshi.  Tokyo Jikeikai Medical Journal.
   (3-25-8, Nishi Shinbashi, Minato-ku, Tokyo 105, Japan)  V.66-    1951-
   Volume(issue)/page/year: 89,475,1974

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 60 gm/kg/70W-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Sense Organs and Special Senses (Ear) - effect, not otherwise specified
   Lungs, Thorax, or Respiration - tumors
REFERENCE :
   NCITR* National Cancer Institute Carcinogenesis Technical Report Series.
   (Bethesda, MD)  No.0-205. For publisher information, see NTPTR*.
   Volume(issue)/page/year: NCI-TR-118,1978

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 80 gm/kg/78W-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
   Reproductive - Tumorigenic effects - ovarian tumors
REFERENCE :
   NCITR* National Cancer Institute Carcinogenesis Technical Report Series.
   (Bethesda, MD)  No.0-205. For publisher information, see NTPTR*.
   Volume(issue)/

TY

TYPE OF TEST            : Unscheduled DNA synthesis
TEST SYSTEM             : Rodent - mouse Liver
DOSE/DURATION           : 200 mg/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 190,159,1987

TYPE OF TEST            : Unscheduled DNA synthesis
TEST SYSTEM             : Rodent - rat Liver
DOSE/DURATION           : 20 mg/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 190,159,1987

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 30 ng/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 7(Suppl
   5),1,1985

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 300 ug/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 272,91,1992

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 10 ug/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 7(Suppl
   5),1,1985

Storage condition -20°C

其他信息

  • TCI Shanghai:5-硝基苊(含3-硝基苊) 5-Nitroacenaphthene (contains 3-Nitroacenaphthene),>;80.0%(GC)(602-87-9)
  • 下游产品:
  • Hazard Note:Irritant
  • 方法一:由苊硝化而得。在干燥的搪玻璃反应锅中加入冰醋酸，在搅拌下加入工业苊（熔点92-94℃）。加热至70℃搅拌10min，冷却至23℃。控制温度23-26℃之间并慢慢滴加65%硝酸。加毕，在23-26℃下搅拌1h即生成5-硝基苊。
  • MSDS 信息:硝基苊(602-87-9).msds
  • 上游原料:搪玻璃反应锅 --> 苊
  • 用途三:该品是染料酸性高黄 FF；分散荧光黄等的中间体。也用作光刻胶增感剂。
  • Sigma Aldrich:602-87-9(sigmaaldrich)
  • Alfa Aesar:5-硝基苊,98% 5-Nitroacenaphthene, 98%(602-87-9)
  • 外观性质:黄色针状结晶。
  • 用途二:该品是染料酸性高黄 FF、分散荧光黄等的中间体。也用作光刻胶增感剂。
  • 溶于热水、乙醇、乙醚和石油醚。遇浓硫酸呈蓝紫色。
  • 用途一:用作化学试剂
  • MOL 文件:602-87-9.mol
  • 图谱信息:1,2-二氢-5-硝基苊 (602-87-9)红外图谱(IR1) 1,2-二氢-5-硝基苊 (602-87-9)红外图谱(IR2) 1,2-二氢-5-硝基苊 (602-87-9)质谱(MS)

系列性分类

  1. Life Science 生命科学
  2. Hematology and Histology 血液学和组织学
  3. Stains and Dyes - Hematology and Histology
  4. Stains & Dyes, A to Z - Stains and Dyes
  5. N - Stains & Dyes, A to Z

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