Phenacyltriphenylphosphonium Bromide (苯甲酰基甲基)三苯基溴化鏻

CAS 6048-29-9 MFCD00011920

化学结构图

6048-29-9
SMILES: O=C(C[P+](c1ccccc1)(c1ccccc1)c1ccccc1)c1ccccc1.[Br-]

化学属性

Mol. FormulaC26H22BrOP
Mol. Weight461.34
Melting Point265-268°C
TSCANo
Stability易吸湿

别名和识别编码

Chemical NamePhenacyltriphenylphosphonium Bromide
Synonym (2-Oxo-2-phenylethyl)triphenylphosphonium bromide {LY} (2-Oxo-2-phenylethyl)triphenylphosphonium bromide {} {LY} (2-Oxo-2-phenylethyl)triphenylphosphonium bromide {} {} {LY} (2-Oxo-2-phenylethyl)triphenylphosphonium bromide {} {} {} {LY} (2-Oxo-2-phenylethyl)triphenylphosphonium bromide {} {} {} {} {LY} (2-Oxo-2-phenylethyl)triphenylphosphonium bromide {} {} {} {} {} {LY} (2-Oxo-2-phenylethyl)triphenylphosphonium bromide {} {} {} {} {} {} {LY} (2-Oxo-2-phenylethyl)triphenylphosphonium bromide {} {} {} {} {} {} {} {LY} (2-Oxo-2-phenylethyl)triphenylphosphonium bromide {} {} {} {} {} {} {} {} {LY} (2-Oxo-2-phenylethyl)triphenylphosphonium bromide {} {} {} {} {} {} {} {} {} {LY} (2-Oxo-2-phenylethyl)triphenylphosphonium bromide {} {} {} {} {} {} {} {} {} {} {LY} (2-Oxo-2-phenylethyl)triphenylphosphonium bromide {} {} {} {} {} {} {} {} {} {} {} {LY} (2-Oxo-2-phenylethyl)triphenylphosphonium bromide {} {} {} {} {} {} {} {} {} {} {} {} {LY} (2-Oxo-2-phenylethyl)triphenylp
MDL NumberMFCD00011920
PubChem Substance ID87575282
CAS Number6048-29-9
EC Number227-945-3
Reaxys-RN3642554
Beilstein Registry Number3642554
Chemical Name Translation(苯甲酰基甲基)三苯基溴化鏻
InChIKeyAEHDSYHVTDJGDN-UHFFFAOYSA-M
Wiswesser Line NotationRV1PR&R&R &E
LabNetwork Molecule IDLN04553301
Canonical SMILESO=C(C1=CC=CC=C1)C[P+](C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4.[Br-]
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分类

  • {SA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents

相关文献及参考

  • 1. Y.-S. Hon, et al., Tetrahedron 57 , 5991-6001, (2001)
  • 2. R. F. Al-Bashir, et al., J. Phys. Org. Chem. 24 , 311-319, (2011)
  • 3. K. Matoba, et al., Angew. Chem. Int. Ed. Engl. 49 , 5762-5766, (2010)
  • 4. C. L. Oswald, et al., Org. Lett. 11 , 4504-4507, (2009)
  • 5. R. Bera, et al., Tetrahedron 65 , 1300-1305, (2009)
  • 6. N. R. Mohamed, et al., Phosphorus, Sulfur Silicon Relat. Elem. 182 , 551-562, (2007)
  • Aldrich MSDS 1 , 1446:C / Corp MSDS 1 (2), 2737:A / FT-IR 1 (2), 549:B / FT-IR 2 (2), 3340:A / IR-Spectra (3), 1186:B / IR-Spectra (2), 1033:A / NMR-Reference 2 (2), 372:C / RegBook 1 (2), 2279:G / Structure Index 1 , 357:B:2

安全信息

GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P302+P352+P332+P313+P362+P364
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P337+P313
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
WGK Germany3
RTECSTA2400000
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Warning
Safety Statements
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 56 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#01534

其他信息

  • MOL 文件:6048-29-9.mol
  • Sigma Aldrich:6048-29-9(sigmaaldrich)
  • Acros Organics:Phenacyltriphenylphosphonium bromide, 96%(6048-29-9)
  • TCI Shanghai:溴化苯甲酰甲基三苯基膦 Phenacyltriphenylphosphonium Bromide,>;97.0%(LC)(T)(6048-29-9)
  • (苯甲酰基甲基)三苯基溴化膦价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P1182 苯甲酰甲基三苯基溴化膦 Phenacyltriphenylphosphonium Bromide 25G 637元 2010/06/21 165940250 (苯甲酰基甲基)三苯基溴化膦 Phenacyltriphenylphosphonium bromide 96% 25 GR 863元 2010/06/21 165941000 (苯甲酰基甲基)三苯基溴化膦 Phenacyltriphenylphosphonium bromide 96% 100 GR 2181元
  • 敏感性:Hygroscopic
  • Alfa Aesar:（苯甲酰基甲基）三苯基溴化膦,98+% (Benzoylmethyl)triphenylphosphonium bromide, 98+%(6048-29-9)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Wittig Reagents - Olefination
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. C-C Bond Formation - Synthetic Reagents
  4. Olefination - C-C Bond Formation
  5. Wittig Reagents - Olefination
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Phosphonium Compounds

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