1-methyl-2-nitrosobenzene 1-甲基-2-亚硝基苯

CAS 611-23-4 MFCD00002061

化学结构图

611-23-4
SMILES: Cc1ccccc1N=O

化学属性

Mol. FormulaCH3C6H4NO
Mol. Weight121.14
Melting Point72-75 °C(lit.)
Solubility易溶于氯仿、乙醇、乙醚。

别名和识别编码

Chemical Name1-methyl-2-nitrosobenzene
Synonym {uni_hamburg} o-methylnitrosobenzene 2-Nitrosotoluene o-Nitrosotoluene 2-Methylnitrosobenzol Nitrosotoluene, p- Toluene, o-nitroso- Toluene, o-nitroso- 2-nitrosotoluene 1-methyl-2-nitroso-benzen o-nitrosotoluene 2-nitroso-toluene 2-Nitrosotoluol Nitrosotoluene toluene, 2-nitroso- 邻亚硝基甲苯 1-methyl-2-nitrosobenzene 1-Methyl-2-nitrosobenzene ORTHO-NITROSOTOLUENE 2-亚硝基甲苯 2-methyl-1-nitrosobenzene 2-Methyl-1-nitrosobenzene 2-Methylnitrosobenzene benzene, 1-methyl-2-nitroso- toluene,2-nitroso- o-Methylnitrosobenzene benzene,1-methyl-2-nitroso- o-nitroso-toluen 2-Nitrosotoluene,97% 1-Nitroso-2-methylbenzene 鄰亞硝【草(之上)+叨】 2-Methyl-nitrosobenzol 1-甲基-2-亚硝基苯 2-methylnitrosobenzene 2-NITROSOTOLUENE O-NITROSOTOLUENE Benzene, 1-methyl-2-nitroso- 1-Methyl-2-nitroso-benzene
MDL NumberMFCD00002061
CAS Number611-23-4
PubChem Substance ID11909
EC Number210-261-4
Chemical Name Translation1-甲基-2-亚硝基苯
Wiswesser Line NotationONR B1
Beilstein Registry Number1927295
InChIInChI=1S/C7H7NO/c1-6-4-2-3-5-7(6)8-9/h2-5H,1H3
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Nitrogen Compounds, Nitroso Compounds, Organic Building Blocks
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment

相关文献及参考

  • Short: III/35E Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Oxygen-17 Author: Duddeck, H.; Toth, G.; Simon, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35E Year: 2002 Keyword: Alipathic and Aromatic hydrocarbons; Coupling constant j; Nuclear Magnetic Resonance; chemical shifts δ ISBN: 3-540-42501-2 ISBN: 978-3-540-42501-4 Internet Resource: DOI:10.1007/b92953 RefComment: VII, 230 pages. With CD-ROM., Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), carbon-13 (subvol. D), and oxygen-17 (subvol. E) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CD-ROM's.
  • Short: IV/8A Title: Enthalpies of Fusion and Transition of Organic Compounds Author: Zhang, Z.-Y.; Frenkel, M.; March, K.N.; Wilhoit, R.C. Editor: Marsh, K.N. Source: Landolt-Börnstein, New Series Volume: IV/8A Year: 1995 Keyword: organic compounds; enthaly of fusion; melting point; phase transition ISBN: 3-540-58854-X ISBN: 978-3-540-58854-2 Internet Resource: DOI:10.1007/b55145 RefComment: VIII, 588 pages.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
Signal word Warning
Hazard statements
  • H332 Harmful if inhaled 吸入有害
  • H315 Causes skin irritation 会刺激皮肤
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H319 Causes serious eye irritation 严重刺激眼睛
RTECSXT3400000
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Hazard Codes Xn
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
Storage condition 0-6°C 
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 103 gm/kg/73W-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Liver - tumors
   Kidney, Ureter, Bladder - tumors
REFERENCE :
   CALEDQ Cancer Letters (Shannon, Ireland).  (Elsevier Scientific Pub. Ireland
   Ltd., POB 85, Limerick, Ireland)  V.1-    1975- Volume(issue)/page/year:
   16,103,1982

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 1 umol/plate
REFERENCE :
   IJEBA6 Indian Journal of Experimental Biology.  (Publications & Information
   Directorate, CSIR, Hillside Rd., New Delhi 110 012, India)  V.1-    1963-
   Volume(issue)/page/year: 25,618,1987

其他信息

  • MOL 文件:611-23-4.mol
  • 稳定性:Stable. Incompatible with oxidizing agents.
  • RTECS号:XT3400000
  • 外观性质:针状或柱状结晶。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Nitroso Compounds - Nitrogen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Nitroso Compounds - Nitrogen Compounds

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