Isopropoxyboronic acid pinacol ester 异丙醇频哪醇硼酸酯

CAS 61676-62-8 MFCD00192241

化学结构图

61676-62-8
SMILES: CC(C)OB1OC(C)(C)C(C)(C)O1

化学属性

Mol. FormulaC9H19BO3
Mol. Weight186.06
Boiling Point150.3°C at 760 mmHg
Density0.912
Refractive index1.4070 to 1.4110
Flash Point37°C(lit.)
TSCANo
Stability对湿度敏感
pH:A

别名和识别编码

Chemical NameIsopropoxyboronic acid pinacol ester
CAS Number61676-62-8
Alfabeta NameISOPROPOXYTETRAMETHYLDIOXABOROLANE 24455132------,,,,,
MDL NumberMFCD00192241
Synonym 2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane {LY} 2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane {} {LY} 2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane {} {} {LY} 2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane {} {} {} {LY} 2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane {} {} {} {} {LY} 2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane {} {} {} {} {} {LY} 2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane {} {} {} {} {} {} {LY} 2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane {} {} {} {} {} {} {} {LY} 2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane {} {} {} {} {} {} {} {} {LY} 2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane {} {} {} {} {} {} {} {} {} {LY} 2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane {} {} {} {} {} {} {} {} {} {} {LY} 2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane {} {} {} {} {} {} {} {} {} {} {}
Beilstein Registry Number1906370
PubChem Substance ID5017741
EC Number250-023-7
Reaxys-RN1906370
Chemical Name Translation异丙醇频哪醇硼酸酯
LabNetwork Molecule IDLN00117874
InChIInChI=1S/C9H19BO3/c1-7(2)11-10-12-8(3,4)9(5,6)13-10/h7H,1-6H3
Canonical SMILESCC(C)OB1OC(C)(C)C(C)(C)O1
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分类

  • {SNA} Boronic Acids and Derivatives, Chemical Synthesis, Organoborates, Organometallic Reagents

相关文献及参考

  • Selective reagent for preparation of pinacol boronic esters, e.g. for preparation of allenyl or vinyl pinacol boronates from the Grignard or lithium reagents: Liebigs Ann. Chem., 881 (1987); Chem. Ber., 122, 1777 (1989); Tetrahedron Lett., 33, 6941 (1992).

安全信息

Warnings IRRITANT, MOISTURE SENSITIVE, FLAMMABLE
Packing GroupIII
UN Number 1993
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R10 Flammable 易燃
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Storage condition 2-8°C {LY} 2-8°C Moisture Sensitive {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P302+P352+P332+P313+P362+P364
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P370+P378
  • P305+P351+P338+P337+P313
  • P303+P361+P353
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P241+P242+P243
  • P403+P235
Signal word
Hazard Codes
Hazard Class3

其他信息

  • Sigma Aldrich:61676-62-8(sigmaaldrich)

系列性分类


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